Journal ArticleDOI
Helical microtubules of graphitic carbon
TLDR
Iijima et al. as mentioned in this paper reported the preparation of a new type of finite carbon structure consisting of needle-like tubes, which were produced using an arc-discharge evaporation method similar to that used for fullerene synthesis.Abstract:
THE synthesis of molecular carbon structures in the form of C60 and other fullerenes1 has stimulated intense interest in the structures accessible to graphitic carbon sheets. Here I report the preparation of a new type of finite carbon structure consisting of needle-like tubes. Produced using an arc-discharge evaporation method similar to that used for fullerene synthesis, the needles grow at the negative end of the electrode used for the arc discharge. Electron microscopy reveals that each needle comprises coaxial tubes of graphitic sheets, ranging in number from 2 up to about 50. On each tube the carbon-atom hexagons are arranged in a helical fashion about the needle axis. The helical pitch varies from needle to needle and from tube to tube within a single needle. It appears that this helical structure may aid the growth process. The formation of these needles, ranging from a few to a few tens of nanometres in diameter, suggests that engineering of carbon structures should be possible on scales considerably greater than those relevant to the fullerenes. On 7 November 1991, Sumio Iijima announced in Nature the preparation of nanometre-size, needle-like tubes of carbon — now familiar as 'nanotubes'. Used in microelectronic circuitry and microscopy, and as a tool to test quantum mechanics and model biological systems, nanotubes seem to have unlimited potential.read more
Citations
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Journal ArticleDOI
Electronic structure of chiral graphene tubules
TL;DR: In this paper, the electronic structure for graphenemonolayer tubules is predicted as a function of the diameter and helicity of the constituent graphene tubules, and it is shown that approximately 1/3 of these tubules are a one-dimensional metal which is stable against a Peierls distortion, and the other 2/3 are onedimensional semiconductors.
Journal ArticleDOI
Graphene oxide, highly reduced graphene oxide, and graphene: versatile building blocks for carbon-based materials.
TL;DR: Techniques for preparing such advanced materials via stable graphene oxide, highly reduced grapheneoxide, and graphene dispersions in aqueous and organic media are summarized with a forward outlook on their applications.
Journal ArticleDOI
Formation of titanium oxide nanotube
TL;DR: In this article, a new route for the synthesis of a nanotube made of titanium oxide is presented, where needle-shaped TiO2 crystals (anatase phase) with a diameter of 8 nm and a length of 100 nm were obtained when sol−gel-derived fine TiO 2-based powders were treated chemically with a 5−10 M NaOH aqueous solution.
Journal ArticleDOI
Spatially Resolved Raman Spectroscopy of Single- and Few-Layer Graphene
D. Graf,F. Molitor,Klaus Ensslin,Christoph Stampfer,A. Jungen,Christofer Hierold,Ludger Wirtz +6 more
TL;DR: In this article, the authors used a scanning confocal approach to collect spectral data with spatial resolution, which allows them to directly compare Raman images with scanning force micrographs.
Journal ArticleDOI
Water‐Soluble Fluorescent Carbon Quantum Dots and Photocatalyst Design
Haitao Li,Xiaodie He,Zhenhui Kang,Zhenhui Kang,Hui Huang,Yang Liu,Yang Liu,Jinglin Liu,Suoyuan Lian,Chi Him A. Tsang,Xiao-Bao Yang,Shuit-Tong Lee +11 more
TL;DR: The facile one-step alkali-assisted electrochemical fabrication of CQDs with sizes of 1.2– 3.8 nm which possess size-dependent photoluminescence (PL) and excellent upconversion luminescence properties are reported and the design of photocatalysts is demonstrated to harness the use of the full spectrum of sunlight.
References
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Journal ArticleDOI
C 60 : Buckminsterfullerene
Harold W. Kroto,Harold W. Kroto,James R. Heath,Sean C. O'Brien,Robert F. Curl,Richard E. Smalley +5 more
TL;DR: In this article, the authors proposed a truncated icosahedron, a polygon with 60 vertices and 32 faces, 12 of which are pentagonal and 20 hexagonal.
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Solid C60: a new form of carbon
TL;DR: In this article, a new form of pure, solid carbon has been synthesized consisting of a somewhat disordered hexagonal close packing of soccer-ball-shaped C60 molecules.
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Filamentous growth of carbon through benzene decomposition
TL;DR: Carbon fibres have been prepared by pyrolysing a mixture of benzene and hydrogen at about 1100°C and have been studied by high resolution electron microscopy.
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Cohesive mechanism and energy bands of solid C60.
Susumu Saito,Atsushi Oshiyama +1 more
TL;DR: In this paper, the authors present microscopic total energy calculations which provide a cohesive property and electronic structures of a new form of solid carbon, the face-centered-cubic crystal (fcc ${\mathrm{C}}_{60}$).
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Growth, Structure, and Properties of Graphite Whiskers
TL;DR: Graphite whiskers have been grown in a dc arc under a pressure of 92 atmospheres of argon and at 3900°K as discussed by the authors, with recoverable lengths up to 3 cm. They are embedded in a solid matrix of graphite which builds up by diffusion of carbon vapor from the positive to the negative electrode.