Journal ArticleDOI
Helical microtubules of graphitic carbon
TLDR
Iijima et al. as mentioned in this paper reported the preparation of a new type of finite carbon structure consisting of needle-like tubes, which were produced using an arc-discharge evaporation method similar to that used for fullerene synthesis.Abstract:
THE synthesis of molecular carbon structures in the form of C60 and other fullerenes1 has stimulated intense interest in the structures accessible to graphitic carbon sheets. Here I report the preparation of a new type of finite carbon structure consisting of needle-like tubes. Produced using an arc-discharge evaporation method similar to that used for fullerene synthesis, the needles grow at the negative end of the electrode used for the arc discharge. Electron microscopy reveals that each needle comprises coaxial tubes of graphitic sheets, ranging in number from 2 up to about 50. On each tube the carbon-atom hexagons are arranged in a helical fashion about the needle axis. The helical pitch varies from needle to needle and from tube to tube within a single needle. It appears that this helical structure may aid the growth process. The formation of these needles, ranging from a few to a few tens of nanometres in diameter, suggests that engineering of carbon structures should be possible on scales considerably greater than those relevant to the fullerenes. On 7 November 1991, Sumio Iijima announced in Nature the preparation of nanometre-size, needle-like tubes of carbon — now familiar as 'nanotubes'. Used in microelectronic circuitry and microscopy, and as a tool to test quantum mechanics and model biological systems, nanotubes seem to have unlimited potential.read more
Citations
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Journal ArticleDOI
Superhydrophobic Carbon Nanotube Forests
Kenneth K. S. Lau,José Bico,Kenneth B. K. Teo,Manish Chhowalla,Gehan A. J. Amaratunga,William I. Milne,Gareth H. McKinley,Karen K. Gleason +7 more
TL;DR: In this paper, the creation of a stable, superhydrophobic surface using the nanoscale roughness inherent in a vertically aligned carbon nanotube forest together with a thin conformal hydrophobic poly(tetrafluoroethylene) (PTFE) coating on the surface of the nanotubes was demonstrated.
Journal ArticleDOI
MoS2 and WS2 Analogues of Graphene
H. S. S. Ramakrishna Matte,A. Gomathi,Arun K. Manna,Dattatray J. Late,Ranjan Datta,Swapan K. Pati,C. N. R. Rao +6 more
TL;DR: This work aims to prepare graphene-like MoS2 and WS2, which are quasi-two-dimensional compounds in which the atoms within the layer are held together by strong covalent forces while van der Waals interaction enables stacking of the layers.
Journal ArticleDOI
Carbon Nanotubes in Biology and Medicine: In vitro and in vivo Detection, Imaging and Drug Delivery
TL;DR: Carbon nanotubes exhibit many unique intrinsic physical and chemical properties and have been intensively explored for biological and biomedical applications in the past few years as mentioned in this paper, and a comprehensive review of the main results from our and other groups in this field can be found in this paper.
Journal ArticleDOI
Aligned Carbon Nanotube Arrays Formed by Cutting a Polymer Resin—Nanotube Composite
TL;DR: The results demonstrate the nature of rheology, on nanometer scales, in composite media and flow-induced anisotropy produced by the cutting process and suggest that nanotubes have excellent mechanical properties.
Journal ArticleDOI
Self-assembling organic nanotubes based on a cyclic peptide architecture
TL;DR: The design, synthesis and characterization of a new class of organic nanotubes based on rationally designed cyclic polypeptides are reported, which may have possible applications in inclusion chemistry, catalysis, molecular electronics and molecular separation technology.
References
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Journal ArticleDOI
C 60 : Buckminsterfullerene
Harold W. Kroto,Harold W. Kroto,James R. Heath,Sean C. O'Brien,Robert F. Curl,Richard E. Smalley +5 more
TL;DR: In this article, the authors proposed a truncated icosahedron, a polygon with 60 vertices and 32 faces, 12 of which are pentagonal and 20 hexagonal.
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Solid C60: a new form of carbon
TL;DR: In this article, a new form of pure, solid carbon has been synthesized consisting of a somewhat disordered hexagonal close packing of soccer-ball-shaped C60 molecules.
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Filamentous growth of carbon through benzene decomposition
TL;DR: Carbon fibres have been prepared by pyrolysing a mixture of benzene and hydrogen at about 1100°C and have been studied by high resolution electron microscopy.
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Cohesive mechanism and energy bands of solid C60.
Susumu Saito,Atsushi Oshiyama +1 more
TL;DR: In this paper, the authors present microscopic total energy calculations which provide a cohesive property and electronic structures of a new form of solid carbon, the face-centered-cubic crystal (fcc ${\mathrm{C}}_{60}$).
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Growth, Structure, and Properties of Graphite Whiskers
TL;DR: Graphite whiskers have been grown in a dc arc under a pressure of 92 atmospheres of argon and at 3900°K as discussed by the authors, with recoverable lengths up to 3 cm. They are embedded in a solid matrix of graphite which builds up by diffusion of carbon vapor from the positive to the negative electrode.