scispace - formally typeset
Journal ArticleDOI

Hygromorphic behaviour of cellular material: hysteretic swelling and shrinkage of wood probed by phase contrast X-ray tomography

TLDR
In this article, the authors quantify the affine strains during swelling and shrinkage using high resolution images obtained by phase contrast synchrotron X-ray tomography of wood samples of different porosities.
Abstract
Wood is a hygromorphic material, meaning it responds to changes in environmental humidity by changing its geometry. Its cellular biological structure swells during wetting and shrinks during drying. The origin of the moisture-induced deformation lies at the sub-cellular scale. The cell wall can be considered a composite material with stiff cellulose fibrils acting as reinforcement embedded in a hemicellulose/lignin matrix. The bulk of the cellulose fibrils, forming 50% of the cell wall, are oriented longitudinally, forming long-pitched helices. Both components of cell wall matrix are displaying swelling. Moisture sorption and, to a lesser degree, swelling/shrinkage are known to be hysteretic. We quantify the affine strains during the swelling and shrinkage using high resolution images obtained by phase contrast synchrotron X-ray tomography of wood samples of different porosities. The reversibility of the swelling/shrinkage is found for samples with controlled moisture sorption history. The deformation is ...

read more

Citations
More filters
Journal ArticleDOI

Advanced computational modelling for drying processes – A review

TL;DR: In this paper, the authors deal with rapidly emerging advanced computational methods for modeling dehydration of porous materials, particularly for foods, and they show promising perspectives to aid developing next-generation sustainable and green drying technology, tailored to the new requirements for the future society, and are expected to play an increasingly important role in drying technology research.
Journal ArticleDOI

A comparative molecular dynamics study of crystalline, paracrystalline and amorphous states of cellulose

TL;DR: In this article, the authors apply united-atom molecular dynamics simulations to quantify changes in different morphologies of cellulose and reveal that the paracrystalline phase may be an intermediate, kinetically arrested phase formed upon amorphisation of crystalline cellulose.
Journal ArticleDOI

Role of hydrogen bonding in hysteresis observed in sorption-induced swelling of soft nanoporous polymers.

TL;DR: At atom-scale simulations are used to identify a molecular mechanism which is responsible for hysteresis in sorption-induced swelling in natural polymers, supported by mechanical testing and cellulose textural assessment upon sorption, to shed light on experimental observations for wood and other related materials.
Journal ArticleDOI

Water Adsorption in Wood Microfibril-Hemicellulose System: Role of the Crystalline-Amorphous Interface.

TL;DR: A two-phase model of a wood microfibril consisting of crystalline cellulose and amorphous hemicellulose is investigated with molecular dynamics in full range of sorption to understand the molecular origin of swelling and weakening of wood.
Journal ArticleDOI

Hygroscopic swelling and shrinkage of latewood cell wall micropillars reveal ultrastructural anisotropy.

TL;DR: It is found that the swelling/shrinkage strains are highly anisotropic in the transverse plane of the cell wall, larger in the normal than in the direction parallel to thecell wall's thickness.
References
More filters
Journal ArticleDOI

Holotomography: Quantitative phase tomography with micrometer resolution using hard synchrotron radiation x rays.

TL;DR: In this article, a holographic reconstruction procedure combining images taken at different distances from the specimen was developed, which results in quantitative phase mapping and, through association with threedimensional reconstruction, in holotomography, the complete three-dimensional mapping of the density in a sample.
Journal ArticleDOI

Water-driven programmable polyurethane shape memory polymer: Demonstration and mechanism

TL;DR: In this article, the authors demonstrate the new features of a polyurethane shape memory polymer: water-driven actuation and recovery in sequence (i.e., programmable).
Journal ArticleDOI

Observation of microstructure and damage in materials by phase sensitive radiography and tomography

TL;DR: In this paper, phase jumps related to the interface between the matrix and the reinforcing phases of the composites are detected even when these phases show very similar x-ray attenuation, illustrating the potential of the technique for assessing damage in materials with improved resolution and sensitivity.
Journal ArticleDOI

Hygromorphs: from pine cones to biomimetic bilayers

TL;DR: It is shown how simple bilayer hygromorphs of paper and polymer show similar behaviour that can be quantified via a theory which couples fluid transport in a porous medium and evaporative flux to mechanics and geometry.
Related Papers (5)