Journal ArticleDOI
Hygromorphic behaviour of cellular material: hysteretic swelling and shrinkage of wood probed by phase contrast X-ray tomography
TLDR
In this article, the authors quantify the affine strains during swelling and shrinkage using high resolution images obtained by phase contrast synchrotron X-ray tomography of wood samples of different porosities.Abstract:
Wood is a hygromorphic material, meaning it responds to changes in environmental humidity by changing its geometry. Its cellular biological structure swells during wetting and shrinks during drying. The origin of the moisture-induced deformation lies at the sub-cellular scale. The cell wall can be considered a composite material with stiff cellulose fibrils acting as reinforcement embedded in a hemicellulose/lignin matrix. The bulk of the cellulose fibrils, forming 50% of the cell wall, are oriented longitudinally, forming long-pitched helices. Both components of cell wall matrix are displaying swelling. Moisture sorption and, to a lesser degree, swelling/shrinkage are known to be hysteretic. We quantify the affine strains during the swelling and shrinkage using high resolution images obtained by phase contrast synchrotron X-ray tomography of wood samples of different porosities. The reversibility of the swelling/shrinkage is found for samples with controlled moisture sorption history. The deformation is ...read more
Citations
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Advanced computational modelling for drying processes – A review
TL;DR: In this paper, the authors deal with rapidly emerging advanced computational methods for modeling dehydration of porous materials, particularly for foods, and they show promising perspectives to aid developing next-generation sustainable and green drying technology, tailored to the new requirements for the future society, and are expected to play an increasingly important role in drying technology research.
Journal ArticleDOI
A comparative molecular dynamics study of crystalline, paracrystalline and amorphous states of cellulose
Karol Kulasinski,Karol Kulasinski,Sinan Keten,Sergey V. Churakov,Dominique Derome,Jan Carmeliet,Jan Carmeliet +6 more
TL;DR: In this article, the authors apply united-atom molecular dynamics simulations to quantify changes in different morphologies of cellulose and reveal that the paracrystalline phase may be an intermediate, kinetically arrested phase formed upon amorphisation of crystalline cellulose.
Journal ArticleDOI
Role of hydrogen bonding in hysteresis observed in sorption-induced swelling of soft nanoporous polymers.
TL;DR: At atom-scale simulations are used to identify a molecular mechanism which is responsible for hysteresis in sorption-induced swelling in natural polymers, supported by mechanical testing and cellulose textural assessment upon sorption, to shed light on experimental observations for wood and other related materials.
Journal ArticleDOI
Water Adsorption in Wood Microfibril-Hemicellulose System: Role of the Crystalline-Amorphous Interface.
TL;DR: A two-phase model of a wood microfibril consisting of crystalline cellulose and amorphous hemicellulose is investigated with molecular dynamics in full range of sorption to understand the molecular origin of swelling and weakening of wood.
Journal ArticleDOI
Hygroscopic swelling and shrinkage of latewood cell wall micropillars reveal ultrastructural anisotropy.
Ahmad Rafsanjani,Michael Stiefel,Konstantins Jefimovs,Rajmund Mokso,Dominique Derome,Jan Carmeliet,Jan Carmeliet +6 more
TL;DR: It is found that the swelling/shrinkage strains are highly anisotropic in the transverse plane of the cell wall, larger in the normal than in the direction parallel to thecell wall's thickness.
References
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Journal ArticleDOI
Holotomography: Quantitative phase tomography with micrometer resolution using hard synchrotron radiation x rays.
Peter Cloetens,Wolfgang Ludwig,José Baruchel,D. Van Dyck,J. Van Landuyt,J.P. Guigay,Michel Schlenker +6 more
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Water-driven programmable polyurethane shape memory polymer: Demonstration and mechanism
TL;DR: In this article, the authors demonstrate the new features of a polyurethane shape memory polymer: water-driven actuation and recovery in sequence (i.e., programmable).
Journal ArticleDOI
Observation of microstructure and damage in materials by phase sensitive radiography and tomography
Peter Cloetens,Murielle Pateyron-Salome,Jean-Yves Buffiere,Gilles Peix,José Baruchel,Françoise Peyrin,Michel Schlenker +6 more
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Journal ArticleDOI
Cell-wall recovery after irreversible deformation of wood
Jozef Keckes,Ingo Burgert,Klaus Frühmann,Martin Müller,Klaas Kölln,Myles Hamilton,Manfred Burghammer,Stephan V. Roth,Stefanie E. Stanzl-Tschegg,Peter Fratzl +9 more
TL;DR: It is suggested that the molecular recovery mechanism in the cell matrix is a universal phenomenon dominating the tensile deformation of different wood tissue types.
Journal ArticleDOI
Hygromorphs: from pine cones to biomimetic bilayers
TL;DR: It is shown how simple bilayer hygromorphs of paper and polymer show similar behaviour that can be quantified via a theory which couples fluid transport in a porous medium and evaporative flux to mechanics and geometry.