scispace - formally typeset
Open AccessJournal ArticleDOI

Influence of pH on hydrothermal treatment of swine manure: Impact on extraction of nitrogen and phosphorus in process water.

TLDR
The results indicate that operating hydrothermal treatment in the presence of acidic additives has benefits in terms of improving the extraction of phosphorus and nitrogen.
About
This article is published in Bioresource Technology.The article was published on 2016-08-01 and is currently open access. It has received 155 citations till now. The article focuses on the topics: Hydrothermal circulation.

read more

Citations
More filters
Journal ArticleDOI

Valorization of hydrothermal liquefaction aqueous phase: pathways towards commercial viability

TL;DR: In this paper, the impact of HTL conditions and feedstock composition on the energy and elemental distribution of process outputs with specific emphasis on the hydrothermal liquefaction aqueous phase (HTL-AP) is discussed.
Journal ArticleDOI

Biochars and hydrochars prepared by pyrolysis and hydrothermal carbonisation of pig manure

TL;DR: Characterization of biochar and hydrochar samples showed that pyrolysis led to chars with more aromatic structures and high thermal stability while HTC process originated char with more aliphatic structures, suggesting that HTC could be an interesting method to obtain soil growing media or green roof materials with adequate hydrophysical properties.
Journal ArticleDOI

The transformation pathways of nitrogen in sewage sludge during hydrothermal treatment.

TL;DR: Results found that only 20% of N remained in hydrochar, whereas the rest of N (nearly 80%) was transformed into other phase, and the comprehensive pathway of N transformation during hydrothermal process was speculated.
Journal ArticleDOI

Characterization and utilization of aqueous products from hydrothermal conversion of biomass for bio-oil and hydro-char production: a review

TL;DR: In this paper, the main reactions occurring in HTC, characterization of HTC-AP, and factors affecting the compositions of HTH-AP are summarized, and the main challenges for future research on HTHAP have been identified and possible solutions are given.
Journal ArticleDOI

Transformation of Phosphorus during (Hydro)thermal Treatments of Solid Biowastes: Reaction Mechanisms and Implications for P Reclamation and Recycling

TL;DR: This study reviews the applications of (hydro)thermal techniques for the treatment of solid biowastes, which can greatly facilitate P recovery in addition to waste volume reduction, decontamination, and energy recovery, and provides a foundation for future research efforts targeting at sustainable management of nutrient-rich biowastses.
References
More filters
Journal ArticleDOI

Thermochemical biofuel production in hydrothermal media: A review of sub- and supercritical water technologies

TL;DR: Several biomass hydrothermal conversion processes are in development or demonstration as mentioned in this paper, which are generally lower temperature (200-400 °C) reactions which produce liquid products, often called bio-oil or bio-crude.
Journal ArticleDOI

Hydrothermal processing of microalgae using alkali and organic acids

TL;DR: In this paper, the conditions for producing high quality, low molecular weight bio-crude from microalgae and cyanobacteria containing low lipid contents including Chlorella vulgaris and Spirulina were investigated.
Journal ArticleDOI

Hydrothermal Carbonization (HTC) of Lignocellulosic Biomass

TL;DR: In this article, a 2 L Parr stirred pressure vessel was used to apply the hydrothermal carbonization (HTC) process to a mixed wood feedstock, and the effects of the reaction conditions on product compositions and yields were examined by varying temperature over the range of 215−295 °C and varying reaction hold time over a range of 5−60 min.
Journal ArticleDOI

Chemical properties of biocrude oil from the hydrothermal liquefaction of Spirulina algae, swine manure, and digested anaerobic sludge.

TL;DR: Findings show the importance of HTL feedstock composition and highlight the need for better understanding of biocrude chemistries when considering bio-oil uses and upgrading requirements.
Journal ArticleDOI

A review of ammonia emission mitigation techniques for concentrated animal feeding operations

TL;DR: Several approaches have been suggested and evaluated for reducing ammonia emissions from excreted animal manure: reducing nitrogen excretion through dietary manipulation, reducing volatile ammonia in the manure to stop ammonia loss, and segregating urine from faeces to reduce contact between urease and urine.
Related Papers (5)
Frequently Asked Questions (12)
Q1. What are the contributions mentioned in the paper "This is a repository copy of influence of ph on hydrothermal treatment of swine manure: impact on extraction of nitrogen and phosphorus in process water" ?

This study investigates the influence of pH on extraction of nitrogen and phosphorus from swine manure following hydrothermal treatment. A significant level of organic-N is extracted into the process waters following hydrothermal treatment. 

The presence of sulphuric acid can increase the extraction of cations and form soluble sulphates from K and Na and Mg. Sulphuric acid can also catalyse the conversion of organic acids by esterification and promote decomposition reactions involving hydration and decarbonylation. 

Following thermal hydrolysis at 170°C, the extraction of phosphorus in water alone reduces to 13% while extraction of phosphorus using formic acid and acetic acid reduces to 21% and 22% respectively. 

The analysis for total phosphorus requires a pre-digestion step using the persulphate digestion method before the colorimetric analysis. 

At 120oC, more phosphorus remained in the hydrochar (63 - 84%) than the aqueous phase for all additives (11 - 30%) except the H2SO4. 

Storing excess manure is a huge challenge to farmers due to odour issues, the high solubility of phosphorus and high degradation rate releasing ammonia (Vadas and Powell, 2013). 

The extraction of phosphorus increases by adding mineral and organic acids and the type of acid was shown to influence phosphorus extraction. 

For instance, strategies for ammonia reduction includes renovation of barns, change in animal nutrition, regular cleaning of exhaust air from farm structures and proper manure treatment (Ndegwa et al., 2008). 

Despite the keen interest in manure management over the past decades, development of sustainable management/treatment technologies on farm or nearby is still necessary to reduce these environmental concerns, improve agricultural benefits and reduce greenhouse gas emissions (Karakashev et al., 2008). 

Therefore livestock producers are concerned about developing new methods and technologies to meet regulatory requirements and maintain good environmental standards. 

Analysis of the metal content in the hydrochars (not shown) indicates that treatment in H2SO4 reduces the levels of Ca, Mg and Fe in the hydrochar compared with the other reagents. 

The nitrogen levels in manure are typically high, reflecting the high levels of crude protein and range from 3-5 % (Heilmann et al., 2014).