Journal ArticleDOI
Oxygen vacancy-rich 2D/2D BiOCl-g-C3N4 ultrathin heterostructure nanosheets for enhanced visible-light-driven photocatalytic activity in environmental remediation
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TLDR
In this paper, a novel oxygen vacancy-rich two-dimensional/two-dimensional (2D/2D) BiOCl-g-C3N4 ultrathin heterostructure nanosheet (CN-BC) was successfully prepared by a facile solvothermal method for degradation of non-dye organic contaminants.Abstract:
Photocatalytic degradation has been unearthed as a promising strategy for environmental remediation, and the calling is endless for more efficient photocatalytic system. In this study, a novel oxygen vacancy-rich two-dimensional/two-dimensional (2D/2D) BiOCl-g-C3N4 ultrathin heterostructure nanosheet (CN-BC) is successfully prepared by a facile solvothermal method for degradation of non-dye organic contaminants. HRTEM observes the formation of heterojunction, while ESR and XPS unveil the distinct oxygen vacancy concentrations. Density functional calculations reveal that the introduction of oxygen vacancies (OVs) brings a new defect level, resulting in the increased photoabsorption. Under visible light irradiation, the OVs-rich optimum ratio of CN-BC (50CN-50BC) Exhibits 95% removal efficiency of 4-chlorophenol within 2 h, which is about 12.5, 5.3 and 3.4 times as that of pure BiOCl, g-C3N4 and OVs-poor heterostructure, respectively. The photocatalytic mechanism of OVs-rich 50CN-50BC is also revealed, suggesting that the synergistic effect between 2D/2D heterojunction and oxygen vacancies greatly promotes visible-light photoabsorption and photoinduced carrier separation efficiency with a prolonged lifetime, which is confirmed by multiple optical and electrochemical analyses, including DRS, steady-state photoluminescence spectra, electrochemical impedance spectroscopy, photocurrent response and time-resolved fluorescence spectra. This study could bring new opportunities for the rational design of highly efficient photocatalysts by combining 2D/2D heterojunctions with oxygen vacancies in environmental remediation.read more
Citations
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Formation of Z‐scheme g‐C 3 N 5 ‐BiOCl to enhance photocatalytic activity under visible light
Yujiang Jiao,Yuan-Ting Zhang,Guyu Zhang,Min Tian,Jianbo Zhao,Tianyi Cui,Yumin Yan,Jianhui Jiang +7 more
TL;DR: In this article , the surface of g-C3N5 was subjected to inorganic acid modification and combined with BiOCl to form a heterojunction, effectively improving the photocatalytic activity of the material.
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p-n Heterostructured BiVO4/g-C3N4 Photoanode: Construction and Its Photoelectrochemical Water Splitting Performance
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Efficient Removal of Ciprofloxacin from Contaminated Water via Polystyrene Anion Exchange Resin with Nanoconfined Zero-Valent Iron
TL;DR: In this article , a nanocomposite material nZVI/PA was synthesized by impregnating nanoscale zero-valent iron (nZVI) inside a millimeter-sized porous host (polystyrene-based anion exchange resin (PA)) for CIP removal.
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Comprehensive Insights into the Family of Atomically Thin 2D-Materials for Diverse Photocatalytic Applications.
Y. N. Teja,Mohan Sakar +1 more
TL;DR: In this paper , a review spotlights the family of various 2D materials, their properties and their 2D structure-induced photocatalytic mechanisms while giving an overview on their synthesis methods along with a detailed discussion on their diverse photocatalysis applications.
References
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Journal ArticleDOI
A metal-free polymeric photocatalyst for hydrogen production from water under visible light
Xinchen Wang,Kazuhiko Maeda,Arne Thomas,Kazuhiro Takanabe,Gang Xin,Johan M. Carlsson,Kazunari Domen,Markus Antonietti +7 more
TL;DR: It is shown that an abundant material, polymeric carbon nitride, can produce hydrogen from water under visible-light irradiation in the presence of a sacrificial donor.
Journal ArticleDOI
Graphitic Carbon Nitride (g-C3N4)-Based Photocatalysts for Artificial Photosynthesis and Environmental Remediation: Are We a Step Closer To Achieving Sustainability?
TL;DR: It is anticipated that this review can stimulate a new research doorway to facilitate the next generation of g-C3N4-based photocatalysts with ameliorated performances by harnessing the outstanding structural, electronic, and optical properties for the development of a sustainable future without environmental detriment.
Journal ArticleDOI
Recent Advances in Ultrathin Two-Dimensional Nanomaterials
Chaoliang Tan,Xiehong Cao,Xiehong Cao,Xue-Jun Wu,Qiyuan He,Jian Yang,Xiao Zhang,Junze Chen,Wei Zhao,Shikui Han,Gwang-Hyeon Nam,Melinda Sindoro,Hua Zhang +12 more
TL;DR: The unique advances on ultrathin 2D nanomaterials are introduced, followed by the description of their composition and crystal structures, and the assortments of their synthetic methods are summarized.
Journal ArticleDOI
Semiconductor heterojunction photocatalysts: design, construction, and photocatalytic performances
Huanli Wang,Lisha Zhang,Zhigang Chen,Junqing Hu,Shijie Li,Zhaohui Wang,Jianshe Liu,Xinchen Wang +7 more
TL;DR: This review attempts to summarize the recent progress in the rational design and fabrication ofheterojunction photocatalysts, such as the semiconductor-semiconductor heterojunction, the semiconductors-metal heterojunctions, the silicon-carbon heteroj junction and the multicomponent heteroj conjunction.
Journal ArticleDOI
Graphene-Like Carbon Nitride Nanosheets for Improved Photocatalytic Activities
TL;DR: In this article, a top-down thermal oxidation etching of bulk g-C3N4 in air has been shown to improve the photocatalytic activities of the material in terms of OH radical generation and hydrogen evolution.