Planar Double-Epsilon-Near-Zero Cavities for Spontaneous Emission and Purcell Effect Enhancement.
Vincenzo Caligiuri,Milan Palei,Milan Palei,Muhammad Imran,Muhammad Imran,Liberato Manna,Roman Krahne +6 more
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TLDR
This work designs metal/dielectric nanocavities to be resonant with the absorption and emission bands of the employed fluorophores, and discusses the possibility of tailoring the two ENZ wavelengths within the visible spectrum simply by finely designing the thickness of the two dielectric layers, which enables resonance matching with a broad variety of dyes.Abstract:
The enhancement of the photophysical response of fluorophores is a crucial factor for photonic and optoelectronic technologies that involve fluorophores as gain media. Recent advances in the development of an extreme light propagation regime, called epsilon-near-zero (ENZ), provide a promising approach in this respect. In this work, we design metal/dielectric nanocavities to be resonant with the absorption and emission bands of the employed fluorophores. Using CsPbBr3 perovskite nanocrystal films as light emitters, we study the spontaneous emission and decay rate enhancement induced by a specifically tailored double-epsilon-near-zero (double ENZ) structure. We experimentally demonstrate the existence of two ENZ wavelengths, by directly measuring their dielectric permittivity via ellipsometric analysis. The double ENZ nature of this plasmonic nanocavity has been exploited to achieve both surface plasmon enhanced absorption (SPEA) and surface plasmon coupled emission (SPCE), inducing a significant enhanceme...read more
Citations
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Zn-Alloyed CsPbI3 Nanocrystals for Highly Efficient Perovskite Light-Emitting Devices
Xinyu Shen,Yu Zhang,Stephen V. Kershaw,Tianshu Li,Congcong Wang,Xiaoyu Zhang,Wenyan Wang,Daguang Li,Yinghui Wang,Min Lu,Lijun Zhang,Chun Sun,Dan Zhao,Guanshi Qin,Xue Bai,William W. Yu,Andrey L. Rogach,Andrey L. Rogach +17 more
TL;DR: The hole injection barrier of electroluminescent LEDs was effectively eliminated by using alloyed CsPb0.64Zn0.36I3 nanocrystals, and a high peak external quantum efficiency of 15.1% has been achieved.
Journal ArticleDOI
Nonlinear optical effects in epsilon-near-zero media
TL;DR: Recently, a new class of materials with a vanishing permittivity, known as epsilon-near-zero (ENZ) materials, has been reported to exhibit unprecedented ultrafast nonlinear efficiencies within sub-wavelength propagation lengths as discussed by the authors.
Journal ArticleDOI
Hyperbolic metamaterials: From dispersion manipulation to applications
TL;DR: Hyperbolic metamaterials (HMMs) as mentioned in this paper are an important class of artificial anisotropic materials with hyperbolic IFCs, which have been intensively investigated.
Journal ArticleDOI
Hyperbolic Metamaterials: From Dispersion Manipulation to Application
TL;DR: In this article, the basic physical properties of hyperbolic metamaterials (HMMs) are introduced and some potential applications associated with Hyperbolic dispersion are also introduced.
References
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Journal ArticleDOI
Nanocrystals of Cesium Lead Halide Perovskites (CsPbX3, X = Cl, Br, and I): Novel Optoelectronic Materials Showing Bright Emission with Wide Color Gamut
Loredana Protesescu,Loredana Protesescu,Sergii Yakunin,Sergii Yakunin,Maryna I. Bodnarchuk,Maryna I. Bodnarchuk,Franziska Krieg,Franziska Krieg,Riccarda Caputo,Christopher H. Hendon,Ruo Xi Yang,Aron Walsh,Maksym V. Kovalenko,Maksym V. Kovalenko +13 more
TL;DR: The compelling combination of enhanced optical properties and chemical robustness makes CsPbX3 nanocrystals appealing for optoelectronic applications, particularly for blue and green spectral regions (410–530 nm), where typical metal chalcogenide-based quantum dots suffer from photodegradation.
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Nanostructures in Biodiagnostics
Nathaniel L. Rosi,Chad A. Mirkin +1 more
TL;DR: Nathaniel L. Rosi focuses on the rational assembly of DNA-modified nanostructures into larger-scale materials and their roles in biodiagnostic screening for nucleic acids.
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A hybridization model for the plasmon response of complex nanostructures.
TL;DR: A simple and intuitive picture that describes the plasmon response of complex nanostructures of arbitrary shape is presented, an electromagnetic analog of molecular orbital theory, that can be understood as the interaction or "hybridization" of elementary plasmons supported by nanostructure of elementary geometries.
Journal ArticleDOI
Demonstration of a spaser-based nanolaser
Mikhail A. Noginov,Guohua Zhu,A. M. Belgrave,Reuben M. Bakker,Vladimir M. Shalaev,Evgenii E. Narimanov,S Stout,S Stout,Erik Herz,Teeraporn Suteewong,Ulrich Wiesner +10 more
TL;DR: It is shown that 44-nm-diameter nanoparticles with a gold core and dye-doped silica shell allow us to completely overcome the loss of localized surface plasmons by gain and realize a spaser, and that outcoupling of surface plasmon oscillations to photonic modes at a wavelength of 531 nm makes this system the smallest nanolaser reported to date—and to the authors' knowledge the first operating at visible wavelengths.
Journal ArticleDOI
Tuning the Optical Properties of Cesium Lead Halide Perovskite Nanocrystals by Anion Exchange Reactions
Quinten A. Akkerman,Valerio D’Innocenzo,Sara Accornero,Alice Scarpellini,Annamaria Petrozza,Mirko Prato,Liberato Manna +6 more
TL;DR: It is demonstrated that, via controlled anion exchange reactions using a range of different halide precursors, this approach gives access to perovskite semiconductor NCs with both structural and optical qualities comparable to those of directly synthesized NCs.