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Rational Design of Three-Layered TiO2 @Carbon@MoS2 Hierarchical Nanotubes for Enhanced Lithium Storage.

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TLDR
The rational design and synthesis of three-layered TiO2 @carbon@MoS2 hierarchical nanotubes for anode applications in lithium-ion batteries (LIBs) manifest remarkable lithium storage performance with good rate capability and long cycle life.
Abstract
Here we demonstrate the rational design and synthesis of three-layered TiO2 @carbon@MoS2 hierarchical nanotubes for anode applications in lithium-ion batteries (LIBs). Through an efficient step-by-step strategy, ultrathin MoS2 nanosheets are grown on nitrogen-doped carbon (NC) coated TiO2 nanotubes to achieve the TiO2 @NC@MoS2 tubular nanostructures. This smart design can effectively shorten the diffusion length of Li+ ions, increase electric conductivity of the electrode, relax volume variation of electrode materials upon cycling, and provide more active sites for electrochemical reactions. Owing to these structural and compositional features, the hierarchical TiO2 @NC@MoS2 nanotubes manifest remarkable lithium storage performance with good rate capability and long cycle life.

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Confined MoS2 growth in a unique composite matrix for ultra-stable and high-rate lithium/sodium-ion anodes

TL;DR: In this article, a new concept of "confined-growth MoS2" (noted as c-MoS2) is proposed to successfully prepare MoS 2 with long life cycle performance especially in harsh conditions for lithium/sodium-ion batteries (LIBs/SIBs).
Journal ArticleDOI

WS2-decorated graphene foam@CNTs hybrid anode for enhanced lithium-ion storage

TL;DR: In this article, a 3D flexible graphene foam/carbon nanotubes/WS2 hybrid has been prepared for lithium-ion batteries (LIBs) anode applications, which can offer numerous open channels for the easy access of electrolyte, enhanced flexibility and conductivity, and active sites for electrochemical reactions.
Journal ArticleDOI

When MoS2 meets TiO2: facile synthesis strategies, hybrid nanostructures, synergistic properties, and photocatalytic applications

TL;DR: In this paper, several typical preparation methods of TiO2/MoS2 hybrid materials are introduced in detail, including hydrothermal methods, atomic layer deposition methods and mechanochemical synthesis methods.
Journal ArticleDOI

Selective phosphidation and reduction strategy to construct heterostructured porous nanorod of CoP coated on Mn3O4 as a bifunctional electrocatalyst for overall water splitting

TL;DR: In this article, a heterostructured porous nanorod of CoP nanoparticles anchored on Mn3O4/CoP PNRs was fabricated via a selective phosphidation and targeted reduction strategy from MnO2/Co3O 4 precursor.
Journal ArticleDOI

Chinese hydrangea lantern-like Co9S8@MoS2 composites with enhanced lithium-ion battery properties.

TL;DR: Chinese hydrangea lantern-like Co9S8@MoS2 composites are prepared by a facile solvothermal method and show excellent electrochemical performance as the anode materials of lithium-ion batteries.
References
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Journal ArticleDOI

Issues and challenges facing rechargeable lithium batteries

TL;DR: A brief historical review of the development of lithium-based rechargeable batteries is presented, ongoing research strategies are highlighted, and the challenges that remain regarding the synthesis, characterization, electrochemical performance and safety of these systems are discussed.
Journal ArticleDOI

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Journal ArticleDOI

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TL;DR: New strategies are needed for batteries that go beyond powering hand-held devices, such as using electrode hosts with two-electron redox centers; replacing the cathode hosts by materials that undergo displacement reactions; and developing a Li(+) solid electrolyte separator membrane that allows an organic and aqueous liquid electrolyte on the anode and cathode sides, respectively.
Journal ArticleDOI

Nitrogen-doped carbon nanotube arrays with high electrocatalytic activity for oxygen reduction.

TL;DR: It is reported that vertically aligned nitrogen-containing carbon nanotubes (VA-NCNTs) can act as a metal-free electrode with a much better electrocatalytic activity, long-term operation stability, and tolerance to crossover effect than platinum for oxygen reduction in alkaline fuel cells.
Journal ArticleDOI

What Are Batteries, Fuel Cells, and Supercapacitors?

TL;DR: Batteries, fuel cells and supercapacitors belong to the same family of energy conversion devices and are needed to service the wide energy requirements of various devices and systems.
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