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Rational Design of Three-Layered TiO2 @Carbon@MoS2 Hierarchical Nanotubes for Enhanced Lithium Storage.

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TLDR
The rational design and synthesis of three-layered TiO2 @carbon@MoS2 hierarchical nanotubes for anode applications in lithium-ion batteries (LIBs) manifest remarkable lithium storage performance with good rate capability and long cycle life.
Abstract
Here we demonstrate the rational design and synthesis of three-layered TiO2 @carbon@MoS2 hierarchical nanotubes for anode applications in lithium-ion batteries (LIBs). Through an efficient step-by-step strategy, ultrathin MoS2 nanosheets are grown on nitrogen-doped carbon (NC) coated TiO2 nanotubes to achieve the TiO2 @NC@MoS2 tubular nanostructures. This smart design can effectively shorten the diffusion length of Li+ ions, increase electric conductivity of the electrode, relax volume variation of electrode materials upon cycling, and provide more active sites for electrochemical reactions. Owing to these structural and compositional features, the hierarchical TiO2 @NC@MoS2 nanotubes manifest remarkable lithium storage performance with good rate capability and long cycle life.

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High-energy–density carbon-coated bismuth nanodots on hierarchically porous molybdenum carbide for superior lithium storage

TL;DR: In this paper , a three-dimensional hierarchically porous molybdenum carbide (PMC) anode with high energy density, robust mechanical strength, and high electronic conductivity was proposed for suppressing the huge volume expansion of alloying-based materials.
Journal ArticleDOI

Two-Dimensional Graphene/BlueP/MoS2 van der Waals Multilayer Heterostructure as a High-Performance Anode Material for LIBs

TL;DR: Stacking of monolayers in a layer-by-layer fashion is a convenient way of designing multilayer van der Waals (vdW) heterostructures that provide an additional range of flexibility as discussed by the authors.
Journal ArticleDOI

Hierarchical core/shell titanium dioxide/molybdenum disulfide nanosheets coupled with carbon architecture for superior lithium/sodium ion storage

TL;DR: In this paper , a unique core/shell structure composite with diverse interfaces was successfully designed and fabricated via a facile coordination reaction combined with thermal treatment, which can elevate the efficiency of energy storage and conversion.
Journal ArticleDOI

Binder free construction of hollow hierarchical Mn-Co-P nanoarrays on nickel foam as an efficient bifunctional electrocatalyst for overall water splitting

TL;DR: In this article , the structural design of non-noble metal electrocatalysts is essential for tuning their electro-catalytic properties, which is of great significance for overall water splitting.
References
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Journal ArticleDOI

Issues and challenges facing rechargeable lithium batteries

TL;DR: A brief historical review of the development of lithium-based rechargeable batteries is presented, ongoing research strategies are highlighted, and the challenges that remain regarding the synthesis, characterization, electrochemical performance and safety of these systems are discussed.
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TL;DR: Researchers must find a sustainable way of providing the power their modern lifestyles demand to ensure the continued existence of clean energy sources.
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TL;DR: New strategies are needed for batteries that go beyond powering hand-held devices, such as using electrode hosts with two-electron redox centers; replacing the cathode hosts by materials that undergo displacement reactions; and developing a Li(+) solid electrolyte separator membrane that allows an organic and aqueous liquid electrolyte on the anode and cathode sides, respectively.
Journal ArticleDOI

Nitrogen-doped carbon nanotube arrays with high electrocatalytic activity for oxygen reduction.

TL;DR: It is reported that vertically aligned nitrogen-containing carbon nanotubes (VA-NCNTs) can act as a metal-free electrode with a much better electrocatalytic activity, long-term operation stability, and tolerance to crossover effect than platinum for oxygen reduction in alkaline fuel cells.
Journal ArticleDOI

What Are Batteries, Fuel Cells, and Supercapacitors?

TL;DR: Batteries, fuel cells and supercapacitors belong to the same family of energy conversion devices and are needed to service the wide energy requirements of various devices and systems.
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