China Three Gorges University

About: China Three Gorges University is a education organization based out in Yichang, China. It is known for research contribution in the topics: Catalysis & Landslide. The organization has 11161 authors who have published 8011 publications receiving 82224 citations. The organization is also known as: Sanxia Daxue.

Unique ability of BiOBr to decarboxylate d-Glu and d-MeAsp in the photocatalytic degradation of microcystin-LR in water.

Abstract: Bismuth oxide bromide, BiOBr, was used to catalyze the degradation of microcystin-LR (MC-LR) in water at neutral pH under visible light. During the investigation, twelve intermediates from MC-LR decomposition were identified by LC-MS. In addition to attacking MC-LR at the typically susceptible sites (i.e., the conjugated double bond of the Adda chain and terminal unsaturated bond of the Mdha chain), the BiOBr photocatalyst has the remarkable ability to decarboxylate the free acid groups on D-glutamic acid (Glu) and methyl-D-aspartic acid (MeAsp). This reactivity has not been previously observed with TiO2 photocatalysis or with other MC-LR treatments in which decarboxylation does not occur until the MC-LR ring has been cleaved or mineralized to CO2. Some expected intermediate products were detected with oxygen-18 labeling by using (H2O)-O-18 as the solvent to confirm that the decarboxylation process is mediated by BiOBr. Results from characterizing the intermediates as well as oxygen-18 labeling studies indicates that oxidative decarboxylation of MC-LR by BiOBr photocatalysis is not always initiated by hydroxyl radical attack (and/or interaction with a hole followed by hydrolysis) proposed mechanism in TiO2 photocatalysis, whereas likely caused by a direct interaction between photoinduced hole of BiOBr and free carboxyl groups of MC-LR This unusual decarboxylation behavior seems to be associated with the particular valence band and conduction band state of BiOBr photocatalyst. Also under BiOBr catalysis, a very stable guanidine group of L-arginine (L-Arg) that is nonreactive with TiO2 photocatalysis is converted to an amino group and subsequently oxidized to a nitro group during the decomposition of MC-LR This reaction sequence is also related to decarboxylation because the guanidine conversion requires a completely or partially decarboxylated precursor. Our results indicate that BiOBr, a photocatalyst that selectively destroys sites crucial to MC-LR toxicity, shows great promise as a means of effectively treating drinking water.

Remote Sensing Image Fusion Using Multiscale Mapped LS-SVM

Abstract: The panchromatic (Pan) sharpening of multispectral (MS) bands is an important technique in the various applications of satellite remote sensing. This paper presents an MS Pan- sharpening method using the proposed multiscale mapped least-squares support vector machine (LS-SVM). Under the LS-SVM framework, the salient features underlying the image are represented by support values, and the support value transform (SVT) is developed for image information extraction. The low-resolution MS bands are resampled to the fine scale of the Pan image and sharpened by injecting the detailed features extracted from the high-resolution Pan image. The support value analysis is implemented by using a series of multiscale support value filters that are deduced from the mapped LS-SVM with multiscale Gaussian radial basis function kernels. Experiments are carried out on very high resolution QuickBird MS + Pan data. Fusion simulations on spatially degraded data, whose original MS bands are available for reference, show that the proposed MS Pan-sharpening method performs comparable to the state-of-the-art in terms of the pertained quantitative quality evaluation indexes, such as the Spectral Angle Mapper, relative dimensionless global error in synthesis (ERGAS), modulation-transfer-function-based tool and quality index (Q4), etc. The SVT is an effective tool for remote sensing image fusion.

SPH model for fluid–structure interaction and its application to debris flow impact estimation

Abstract: On 13 August 2010, significant debris flows were triggered by intense rainfall events in Wenchuan earthquake-affected areas, destroying numerous houses, bridges, and traffic facilities. To investigate the impact force of debris flows, a fluid–structure coupled numerical model based on smoothed particle hydrodynamics is established in this work. The debris flow material is modeled as a viscous fluid, and the check dams are simulated as elastic solid (note that only the maximum impact forces are evaluated in this work). The governing equations of both phases are solved respectively, and their interaction is calculated. We validate the model with the simulation of a sand flow model test and confirm its ability to calculate the impact force. The Wenjia gully and Hongchun gully debris flows are simulated as the application of the coupled smoothed particle hydrodynamic model. The propagation of the debris flows is then predicted, and we obtain the evolution of the impact forces on the check dams.