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Journal ArticleDOI

Iodine Modified Carbon Nitride Semiconductors as Visible Light Photocatalysts for Hydrogen Evolution

TLDR
The as-prepared iodine functionalized g-CN shows enhanced electronic and optical properties, as well as increased photocatalytic activities in an assay of hydrogen evolution.
Abstract
An optimized and general synthetic strategy based on in-situ iodine modifying of polymeric graphitic carbon nitride is discussed. The as-prepared iodine functionalized g-CN shows enhanced electronic and optical properties, as well as increased photocatalytic activities in an assay of hydrogen evolution.

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Graphitic Carbon Nitride (g-C3N4)-Based Photocatalysts for Artificial Photosynthesis and Environmental Remediation: Are We a Step Closer To Achieving Sustainability?

TL;DR: It is anticipated that this review can stimulate a new research doorway to facilitate the next generation of g-C3N4-based photocatalysts with ameliorated performances by harnessing the outstanding structural, electronic, and optical properties for the development of a sustainable future without environmental detriment.
Journal ArticleDOI

Polymeric Photocatalysts Based on Graphitic Carbon Nitride

TL;DR: The photo-catalytic applications of g-C3N4 -based photocatalysts in the fields of water splitting, CO2 reduction, pollutant degradation, organic syntheses, and bacterial disinfection are reviewed, with emphasis on photocatalysis promoted by carbon materials, non-noble-metal coc atalysts, and Z-scheme heterojunctions.
Journal ArticleDOI

A review on g-C3N4-based photocatalysts

TL;DR: In this paper, the fundamental mechanism of heterogeneous photocatalysis, advantages, challenges and the design considerations of g-C3N4-based photocatalysts are summarized, including their crystal structural, surface phisicochemical, stability, optical, adsorption, electrochemical, photoelectrochemical and electronic properties.
Journal ArticleDOI

Alkali-Assisted Synthesis of Nitrogen Deficient Graphitic Carbon Nitride with Tunable Band Structures for Efficient Visible-Light-Driven Hydrogen Evolution.

TL;DR: A facile synthetic strategy for nitrogen-deficient graphitic carbon nitride (g-C3 Nx) is established, involving a simple alkali-assisted thermal polymerization of urea, melamine, or thiourea, with superior visible-light photocatalytic performance compared to pristine g-C2 N4.
Journal ArticleDOI

Graphitic Carbon Nitride Polymers toward Sustainable Photoredox Catalysis.

TL;DR: The methods to modify the electronic structure, nanostructure, crystal structure, and heterostructure of g-C3 N4, together with correlations between its structure and performance are illustrated.
References
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Journal ArticleDOI

Light-emitting diodes based on conjugated polymers

TL;DR: In this article, the authors demonstrate that poly(p-phenylene vinylene), prepared by way of a solution-processable precursor, can be used as the active element in a large-area light-emitting diode.
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A metal-free polymeric photocatalyst for hydrogen production from water under visible light

TL;DR: It is shown that an abundant material, polymeric carbon nitride, can produce hydrogen from water under visible-light irradiation in the presence of a sacrificial donor.
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Polymer photovoltaic cells : enhanced efficiencies via a network of internal donor-acceptor heterojunctions

TL;DR: In this paper, the carrier collection efficiency and energy conversion efficiency of polymer photovoltaic cells were improved by blending of the semiconducting polymer with C60 or its functionalized derivatives.
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A fast and robust algorithm for Bader decomposition of charge density

TL;DR: In this article, an algorithm for decomposition of electronic charge density into atomic contributions is presented. But instead of explicitly finding and representing the dividing surfaces, which is a challenging task, the algorithm assigns each point on a regular (x,y,z) grid to one of the regions by following a steepest ascent path on the grid.
Journal ArticleDOI

Two-dimensional charge transport in self-organized, high-mobility conjugated polymers

TL;DR: In this article, the authors used thin-film, field effect transistor structures to probe the transport properties of the ordered microcrystalline domains in the conjugated polymer poly(3-hexylthiophene), P3HT.
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