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Issues and challenges facing rechargeable lithium batteries

TLDR
A brief historical review of the development of lithium-based rechargeable batteries is presented, ongoing research strategies are highlighted, and the challenges that remain regarding the synthesis, characterization, electrochemical performance and safety of these systems are discussed.
Abstract
Technological improvements in rechargeable solid-state batteries are being driven by an ever-increasing demand for portable electronic devices. Lithium-ion batteries are the systems of choice, offering high energy density, flexible and lightweight design, and longer lifespan than comparable battery technologies. We present a brief historical review of the development of lithium-based rechargeable batteries, highlight ongoing research strategies, and discuss the challenges that remain regarding the synthesis, characterization, electrochemical performance and safety of these systems.

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Citations
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Journal ArticleDOI

The cathode-electrolyte interface in the Li-ion battery

TL;DR: In this article, the same experimental techniques as used earlier to characterize the composition and properties of the so-called solid electrolyte interphase (SEI) layer formed at the graphite-anode-electrolyte interface of a Li-ion battery are used to acquire some degree of understanding of interface phenomena occurring on the cathode side of the cell, even though the validity of the SEI-layer concept is still somewhat tenuous in this “cathode” context.
Journal ArticleDOI

Strongly coupled inorganic–nano-carbon hybrid materials for energy storage

TL;DR: It is shown that the inorganic-nano-carbon hybrid materials represent a new approach to synthesize electrode materials with higher electrochemical performance than traditional counterparts made by simple physical mixtures of electrochemically active inorganic particles and conducting carbon materials.
Journal ArticleDOI

Single lithium-ion conducting solid polymer electrolytes: advances and perspectives

TL;DR: A brief overview of synthetic strategies on how to realize single lithium-ion (Li-ion) conducting solid polymer electrolytes (SLIC-SPEs), which have anions covalently bonded to the polymer, inorganic backbone, or immobilized by anion acceptors, are given.
Journal ArticleDOI

An amorphous red phosphorus/carbon composite as a promising anode material for sodium ion batteries.

TL;DR: The amorphous red phosphorus/carbon composite shows excellent electrochemical performance including a high specific capacity, negligible capacity fading over 30 cycles, an ideal redox potential, and an excellent rate performance, thus making it a promising candidate for Na ion batteries.
Journal ArticleDOI

Single-crystalline NiCo2O4 nanoneedle arrays grown on conductive substrates as binder-free electrodes for high-performance supercapacitors

TL;DR: In this article, single-crystalline nanoneedle arrays of NiCo2O4 were grown on conductive substrates such as Ni foam and Ti foil through a simple solution method together with a post-annealing treatment.
References
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Journal ArticleDOI

Nano-sized transition-metal oxides as negative-electrode materials for lithium-ion batteries

TL;DR: It is reported that electrodes made of nanoparticles of transition-metal oxides (MO), where M is Co, Ni, Cu or Fe, demonstrate electrochemical capacities of 700 mA h g-1, with 100% capacity retention for up to 100 cycles and high recharging rates.
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LixCoO2 (0<x<-1): A new cathode material for batteries of high energy density

TL;DR: In this paper, a new system LixCoO2 (0 Li x CoO 2 Li ) is proposed, which shows low overvoltages and good reversibility for current densities up to 4 mA cm−2 over a large range of x.
Journal ArticleDOI

Nanocomposite polymer electrolytes for lithium batteries

TL;DR: In this article, the authors showed that nanometre-sized ceramic powders can be used as solid plasticizers for polyethylene oxide (PEO) electrolytes to prevent crystallization on annealing from amorphous state above 60°C.
Journal ArticleDOI

Tin-Based Amorphous Oxide: A High-Capacity Lithium-Ion-Storage Material

TL;DR: A tin-based amorphous composite oxide (TCO) was synthesized in this paper to replace the carbon-based lithium intercalation materials currently in extensive use as the negative electrode (anode) of lithium-ion rechargeable batteries.
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Issues and challenges facing rechargeable lithium batteries

The paper discusses the challenges in the synthesis, characterization, electrochemical performance, and safety of rechargeable lithium batteries.