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Issues and challenges facing rechargeable lithium batteries

TLDR
A brief historical review of the development of lithium-based rechargeable batteries is presented, ongoing research strategies are highlighted, and the challenges that remain regarding the synthesis, characterization, electrochemical performance and safety of these systems are discussed.
Abstract
Technological improvements in rechargeable solid-state batteries are being driven by an ever-increasing demand for portable electronic devices. Lithium-ion batteries are the systems of choice, offering high energy density, flexible and lightweight design, and longer lifespan than comparable battery technologies. We present a brief historical review of the development of lithium-based rechargeable batteries, highlight ongoing research strategies, and discuss the challenges that remain regarding the synthesis, characterization, electrochemical performance and safety of these systems.

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Polymer-bound pyrene-4,5,9,10-tetraone for fast-charge and -discharge lithium-ion batteries with high capacity.

TL;DR: It is shown that the Li-ion battery composed of pyrene-4,5,9,10-tetraone (PYT), which has two six-membered cyclic 1,2-diketone units, exhibits remarkable charge-discharge properties with a high specific capacity of 231 mAh/g, excellent rechargeability, and charge- Discharge ability in the LiNTf(2)/tetraglyme ionic-liquid system.
Journal ArticleDOI

Homogeneous core–shell NiCo2S4 nanostructures supported on nickel foam for supercapacitors

TL;DR: In this article, the NiCo2S4 was used as a supercapacitor electrode and achieved a high specific capacitance of 1948 mF cm−2 at a current density of 1 mA cm− 2, and an excellent cycling stability.
Journal ArticleDOI

A review of cathode materials and structures for rechargeable lithium–air batteries

TL;DR: In this article, the role of the cathode in non-aqueous Li-air batteries including the reaction mechanisms and the properties and morphologies of cathode materials, followed by approaches to optimize cathode performance.
Journal ArticleDOI

Two-phase electrochemical lithiation in amorphous silicon

TL;DR: The two-phase lithiation can be the fundamental mechanism underpinning the anomalous morphological change of microfabricated a-Si electrodes, i.e., from a disk shape to a dome shape, which is critical to the development of microstructurally stable electrodes for high-performance lithium-ion batteries.
References
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Journal ArticleDOI

Nano-sized transition-metal oxides as negative-electrode materials for lithium-ion batteries

TL;DR: It is reported that electrodes made of nanoparticles of transition-metal oxides (MO), where M is Co, Ni, Cu or Fe, demonstrate electrochemical capacities of 700 mA h g-1, with 100% capacity retention for up to 100 cycles and high recharging rates.
Journal ArticleDOI

LixCoO2 (0<x<-1): A new cathode material for batteries of high energy density

TL;DR: In this paper, a new system LixCoO2 (0 Li x CoO 2 Li ) is proposed, which shows low overvoltages and good reversibility for current densities up to 4 mA cm−2 over a large range of x.
Journal ArticleDOI

Nanocomposite polymer electrolytes for lithium batteries

TL;DR: In this article, the authors showed that nanometre-sized ceramic powders can be used as solid plasticizers for polyethylene oxide (PEO) electrolytes to prevent crystallization on annealing from amorphous state above 60°C.
Journal ArticleDOI

Tin-Based Amorphous Oxide: A High-Capacity Lithium-Ion-Storage Material

TL;DR: A tin-based amorphous composite oxide (TCO) was synthesized in this paper to replace the carbon-based lithium intercalation materials currently in extensive use as the negative electrode (anode) of lithium-ion rechargeable batteries.
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Issues and challenges facing rechargeable lithium batteries

The paper discusses the challenges in the synthesis, characterization, electrochemical performance, and safety of rechargeable lithium batteries.