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Polymers for 3D Printing and Customized Additive Manufacturing

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TLDR
Polymers are by far the most utilized class of materials for AM and their design, additives, and processing parameters as they relate to enhancing build speed and improving accuracy, functionality, surface finish, stability, mechanical properties, and porosity are addressed.
Abstract
Additive manufacturing (AM) alias 3D printing translates computer-aided design (CAD) virtual 3D models into physical objects. By digital slicing of CAD, 3D scan, or tomography data, AM builds objects layer by layer without the need for molds or machining. AM enables decentralized fabrication of customized objects on demand by exploiting digital information storage and retrieval via the Internet. The ongoing transition from rapid prototyping to rapid manufacturing prompts new challenges for mechanical engineers and materials scientists alike. Because polymers are by far the most utilized class of materials for AM, this Review focuses on polymer processing and the development of polymers and advanced polymer systems specifically for AM. AM techniques covered include vat photopolymerization (stereolithography), powder bed fusion (SLS), material and binder jetting (inkjet and aerosol 3D printing), sheet lamination (LOM), extrusion (FDM, 3D dispensing, 3D fiber deposition, and 3D plotting), and 3D bioprinting....

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Polymer Design for 3D Printing Elastomers: Recent Advances in Structure, Properties, and Printing

TL;DR: In this paper, the authors provide an in-depth discussion of the current state of silicone and polyurethane polymers for AM, and also discuss polyesters/polycarbonates, liquid crystalline elastomers, and monomer compositions that provide elastomeric properties upon photocuring.
Journal ArticleDOI

Polymeric Systems for Bioprinting.

TL;DR: A review of recent bioprinting innovations, such as increasing architectural complexity and cell viability in heterogeneous tissue constructs, which allow for the investigation of biological questions that could not be addressed before.
Journal ArticleDOI

Additive manufacturing of metals: Microstructure evolution and multistage control

TL;DR: In this article, the formation and binding of melt pools is studied, and a comprehensive processing map is proposed that integrates melt pool energy and geometry-related process parameters together, based on which additively manufactured microstructures are developed during and after the solidification of constituent melt pool.
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4D printed thermally activated self-healing and shape memory polycaprolactone-based polymers

TL;DR: In this paper, a shape memory polymer with thermally induced healing abilities is first presented and achieved by digital light projection (DLP) technology, where shape memory and self-healing functionalities are thermally triggered and obtained respectively using polycaprolactone (PCL) chains and 2-ureido-4[1H]-pyrimidinone (UPy) units co-crosslinked in this newly prepared material.
References
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Journal ArticleDOI

3D bioprinting of tissues and organs

TL;DR: 3D bioprinting is being applied to regenerative medicine to address the need for tissues and organs suitable for transplantation and developing high-throughput 3D-bioprinted tissue models for research, drug discovery and toxicology.
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Hydrogels for tissue engineering: scaffold design variables and applications.

TL;DR: Hydrogels are an appealing scaffold material because they are structurally similar to the extracellular matrix of many tissues, can often be processed under relatively mild conditions, and may be delivered in a minimally invasive manner.
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Nonlinear magic: multiphoton microscopy in the biosciences

TL;DR: Multiphoton microscopy has found a niche in the world of biological imaging as the best noninvasive means of fluorescence microscopy in tissue explants and living animals and its use is now increasing exponentially.
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Thiol–Ene Click Chemistry

TL;DR: The radical-mediated thiol-ene reaction has all the desirable features of a click reaction, being highly efficient, simple to execute with no side products and proceeding rapidly to high yield.
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Applications of hybrid organic–inorganic nanocomposites

TL;DR: In this article, the authors propose a vectorial chemistry approach for the generation of new generations of hybrid materials, which will open a land of promising applications in many areas: optics, electronics, ionics, mechanics, energy, environment, biology, medicine for example as membranes and separation devices, functional smart coatings, fuel and solar cells, catalysts, sensors, etc.
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