Journal ArticleDOI
Postsynthetic modification of metal–organic frameworks
Zhenqiang Wang,Seth M. Cohen +1 more
TLDR
The rapid increase in reports on PSM demonstrates this methodology will play an increasingly important role in the development of MOFs for the foreseeable future, and in both scope of chemical reactions and range of suitable MOFs.Abstract:
The modification of metal–organic frameworks (MOFs) in a postsynthetic scheme is discussed in this critical review. In this approach, the MOF is assembled and then modified with chemical reagents with preservation of the lattice structure. Recent findings show amide couplings, isocyanate condensations, ‘click’ chemistry, and other reactions are suitable for postsynthetic modification (PSM). In addition, a number of MOFs, from IRMOF-3 to ZIF-90, are amenable to PSM. The generality of PSM, in both scope of chemical reactions and range of suitable MOFs, clearly indicates that the approach is broadly applicable. Indeed, the rapid increase in reports on PSM demonstrates this methodology will play an increasingly important role in the development of MOFs for the foreseeable future (117 references).read more
Citations
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Journal ArticleDOI
Versatile Synthesis of Luminescent Tetradentate Cyclometalated Alkynylgold(III) Complexes and Their Application in Solution-Processable Organic Light-Emitting Devices
TL;DR: This work describes for the first time the use of post-synthetic ligand modification approach to overcome the synthetic challenge for tetradentate alkynylgold(III) complexes.
Journal ArticleDOI
Stabilizing Metal-Organic Polyhedra (MOP): Issues and Strategies.
TL;DR: Highlighting structure-property relationships among the structural and compositional features of these metal carboxylate polyhedra, the related scientific challenges and state-of-the-art research directions related to their further exploration are put forward.
Journal ArticleDOI
Progress in the synthetic and functional aspects of chiral metal–organic frameworks
Kamal Kumar Bisht,Kamal Kumar Bisht,Bhavesh Parmar,Yadagiri Rachuri,Amal Cherian Kathalikattil,Amal Cherian Kathalikattil,Eringathodi Suresh +6 more
TL;DR: In this paper, two aspects of chiral metal-organic frameworks, in particular synthetic approaches to achieve chiral MOFs and their applications, have been discussed, and seminal as well as recent reports from the literature are provided.
Journal ArticleDOI
Enhanced hydrothermal stability of Cu MOF by post synthetic modification with amino acids
TL;DR: In this paper, the authors reported the solvothermal synthesis of copper metal organic framework (Cu MOF) also known as HKUST 1 and its functionalization with amino acids to increase hydrothermal stability.
Journal ArticleDOI
A Metal–Organic Framework Containing Unusual Eight-Connected Zr–Oxo Secondary Building Units and Orthogonal Carboxylic Acids for Ultra-sensitive Metal Detection
TL;DR: Two metal-organic frameworks with Zr-oxo secondary building units (SBUs) were prepared by using p,p'-terphenyldicarboxylate bridging ligands pre-functionalized with orthogonal succinic acid and maleic acid groups to provide the first direct evidence for eight-connected SBUs in UiO-type MOFs.
References
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Journal ArticleDOI
Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
Journal ArticleDOI
Click Chemistry: Diverse Chemical Function from a Few Good Reactions.
TL;DR: In this paper, a set of powerful, highly reliable, and selective reactions for the rapid synthesis of useful new compounds and combinatorial libraries through heteroatom links (C-X-C), an approach called click chemistry is defined, enabled, and constrained by a handful of nearly perfect "springloaded" reactions.
Journal ArticleDOI
Reticular synthesis and the design of new materials
Omar M. Yaghi,Michael O'Keeffe,Nathan W. Ockwig,Hee K. Chae,Hee K. Chae,Mohamed Eddaoudi,Jaheon Kim +6 more
TL;DR: This work has shown that highly porous frameworks held together by strong metal–oxygen–carbon bonds and with exceptionally large surface area and capacity for gas storage have been prepared and their pore metrics systematically varied and functionalized.
Journal ArticleDOI
Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
Journal ArticleDOI
Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.