Journal ArticleDOI
Postsynthetic modification of metal–organic frameworks
Zhenqiang Wang,Seth M. Cohen +1 more
TLDR
The rapid increase in reports on PSM demonstrates this methodology will play an increasingly important role in the development of MOFs for the foreseeable future, and in both scope of chemical reactions and range of suitable MOFs.Abstract:
The modification of metal–organic frameworks (MOFs) in a postsynthetic scheme is discussed in this critical review. In this approach, the MOF is assembled and then modified with chemical reagents with preservation of the lattice structure. Recent findings show amide couplings, isocyanate condensations, ‘click’ chemistry, and other reactions are suitable for postsynthetic modification (PSM). In addition, a number of MOFs, from IRMOF-3 to ZIF-90, are amenable to PSM. The generality of PSM, in both scope of chemical reactions and range of suitable MOFs, clearly indicates that the approach is broadly applicable. Indeed, the rapid increase in reports on PSM demonstrates this methodology will play an increasingly important role in the development of MOFs for the foreseeable future (117 references).read more
Citations
More filters
Journal ArticleDOI
Palladium(II)@Zirconium-Based Mixed-Linker Metal–Organic Frameworks as Highly Efficient and Recyclable Catalysts for Suzuki and Heck Cross-Coupling Reactions
TL;DR: In this article, two amine-functionalized Zr-based mixed-linker metal-organic frameworks (MOFs) were synthesized with different ratios of 1,4-benzenedicarboxylate/2-amino-1, 4-biphenyldicarboardylic acid and 4,4'-biphenyl-4, 4'-dicaroxyl acid incorporated into their structures.
Journal ArticleDOI
Post-modification of a MOF through a fluorescent-labeling technology for the selective sensing and adsorption of Ag+ in aqueous solution
TL;DR: A new approach inspired by fluorescent labeling technology to fluorescently functionalize MOFs via post-modification through selective sensing and adsorption of Ag(+) in aqueous solution is reported.
Journal ArticleDOI
Control of the charge-transfer interaction between a flexible porous coordination host and aromatic guests by framework isomerism
TL;DR: Based on 2,5-thiophenedicarboxylate (thdc), two isomorphic frameworks are assembled from zinc ions and N,N′-di(4-pyridyl)-1,4,5,8-naphthalenediimide (dpNDI) as discussed by the authors.
Journal ArticleDOI
Postsynthetic Modification of an Alkyne-Tagged Zirconium Metal-Organic Framework via a "Click" Reaction.
TL;DR: The synthesis and postsynthetic modification of a novel alkyne-tagged zirconium metal-organic framework, UiO-68-alkyne, achieves quantitative conversion and maintaining the crystallinity of the framework.
Journal ArticleDOI
Atomic Layer Deposition in a Metal–Organic Framework: Synthesis, Characterization, and Performance of a Solid Acid
Martino Rimoldi,Varinia Bernales,Joshua Borycz,Aleksei Vjunov,Leighanne C. Gallington,Ana E. Platero-Prats,In Soo Kim,John L. Fulton,Alex B. F. Martinson,Johannes A. Lercher,Johannes A. Lercher,Karena W. Chapman,Christopher J. Cramer,Laura Gagliardi,Joseph T. Hupp,Omar K. Farha,Omar K. Farha +16 more
TL;DR: In this article, the aluminum-modified NU-1000 (Al-NU-1-1000) has been characterized with a comprehensive suite of techniques that points to the formation of aluminum oxide clusters well dispersed through the framework and stabilized by confinement within small pores intrinsic to the NU1000 structure.
References
More filters
Journal ArticleDOI
Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
Journal ArticleDOI
Click Chemistry: Diverse Chemical Function from a Few Good Reactions.
TL;DR: In this paper, a set of powerful, highly reliable, and selective reactions for the rapid synthesis of useful new compounds and combinatorial libraries through heteroatom links (C-X-C), an approach called click chemistry is defined, enabled, and constrained by a handful of nearly perfect "springloaded" reactions.
Journal ArticleDOI
Reticular synthesis and the design of new materials
Omar M. Yaghi,Michael O'Keeffe,Nathan W. Ockwig,Hee K. Chae,Hee K. Chae,Mohamed Eddaoudi,Jaheon Kim +6 more
TL;DR: This work has shown that highly porous frameworks held together by strong metal–oxygen–carbon bonds and with exceptionally large surface area and capacity for gas storage have been prepared and their pore metrics systematically varied and functionalized.
Journal ArticleDOI
Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
Journal ArticleDOI
Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.