Journal ArticleDOI
Postsynthetic modification of metal–organic frameworks
Zhenqiang Wang,Seth M. Cohen +1 more
TLDR
The rapid increase in reports on PSM demonstrates this methodology will play an increasingly important role in the development of MOFs for the foreseeable future, and in both scope of chemical reactions and range of suitable MOFs.Abstract:
The modification of metal–organic frameworks (MOFs) in a postsynthetic scheme is discussed in this critical review. In this approach, the MOF is assembled and then modified with chemical reagents with preservation of the lattice structure. Recent findings show amide couplings, isocyanate condensations, ‘click’ chemistry, and other reactions are suitable for postsynthetic modification (PSM). In addition, a number of MOFs, from IRMOF-3 to ZIF-90, are amenable to PSM. The generality of PSM, in both scope of chemical reactions and range of suitable MOFs, clearly indicates that the approach is broadly applicable. Indeed, the rapid increase in reports on PSM demonstrates this methodology will play an increasingly important role in the development of MOFs for the foreseeable future (117 references).read more
Citations
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The strategies for improving carbon dioxide chemisorption by functionalized ionic liquids
Guokai Cui,Sheng Dai,De-en Jiang,Haoran Li,Chongmin Wang,Xiaoyan Luo,Xiang Zhu,Deng Dongshun +7 more
TL;DR: In this article, a perspective review focuses on the recent advances in chemical absorption of CO2 using functionalized ionic liquids, including amino acid-based ionic liquid, azole-based Ionic Liquid, phenol-based liquid, and so on.
Journal ArticleDOI
Enhancing Mixed-Matrix Membrane Performance with Metal–Organic Framework Additives
TL;DR: In this paper, the authors present a review of the challenges in the context of MOF synthesis and membrane fabrication by the choice of appropriate polymer/MOF combinations, utilization of the MOF functional sites, modification of the surface chemistry or pore texture and s...
Journal ArticleDOI
Self-Mineralized Photothermal Bacteria Hybridizing with Mitochondria-Targeted Metal–Organic Frameworks for Augmenting Photothermal Tumor Therapy
Qi-Wen Chen,Xin-Hua Liu,Jin-Xuan Fan,Si-Yuan Peng,Jia-Wei Wang,Xia-Nan Wang,Cheng Zhang,Chuanjun Liu,Xian-Zheng Zhang +8 more
TL;DR: The PTB‐based therapeutic platform of PTB@ZIF‐90/MB demonstrated here will find great potential to overcome the challenges of tumor targeting and tumor heat tolerance in PTT.
Journal ArticleDOI
Improved Interfacial Affinity and CO2 Separation Performance of Asymmetric Mixed Matrix Membranes by Incorporating Postmodified MIL-53(Al)
TL;DR: The strategy of post covalent modification for MOFs provides an effective way to improve the interfacial affinity and gas separation performance of asymmetric MMMs.
Journal ArticleDOI
Rational design of metal-organic frameworks with anticipated porosities and functionalities
TL;DR: This highlight review will outline the recent advances on this topic from both the authors' and other groups and provide a systematic overview of different methods for the rational design of MOFs with desired porosities and functionalities.
References
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Journal ArticleDOI
Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
Journal ArticleDOI
Click Chemistry: Diverse Chemical Function from a Few Good Reactions.
TL;DR: In this paper, a set of powerful, highly reliable, and selective reactions for the rapid synthesis of useful new compounds and combinatorial libraries through heteroatom links (C-X-C), an approach called click chemistry is defined, enabled, and constrained by a handful of nearly perfect "springloaded" reactions.
Journal ArticleDOI
Reticular synthesis and the design of new materials
Omar M. Yaghi,Michael O'Keeffe,Nathan W. Ockwig,Hee K. Chae,Hee K. Chae,Mohamed Eddaoudi,Jaheon Kim +6 more
TL;DR: This work has shown that highly porous frameworks held together by strong metal–oxygen–carbon bonds and with exceptionally large surface area and capacity for gas storage have been prepared and their pore metrics systematically varied and functionalized.
Journal ArticleDOI
Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
Journal ArticleDOI
Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.