Journal ArticleDOI
Postsynthetic modification of metal–organic frameworks
Zhenqiang Wang,Seth M. Cohen +1 more
TLDR
The rapid increase in reports on PSM demonstrates this methodology will play an increasingly important role in the development of MOFs for the foreseeable future, and in both scope of chemical reactions and range of suitable MOFs.Abstract:
The modification of metal–organic frameworks (MOFs) in a postsynthetic scheme is discussed in this critical review. In this approach, the MOF is assembled and then modified with chemical reagents with preservation of the lattice structure. Recent findings show amide couplings, isocyanate condensations, ‘click’ chemistry, and other reactions are suitable for postsynthetic modification (PSM). In addition, a number of MOFs, from IRMOF-3 to ZIF-90, are amenable to PSM. The generality of PSM, in both scope of chemical reactions and range of suitable MOFs, clearly indicates that the approach is broadly applicable. Indeed, the rapid increase in reports on PSM demonstrates this methodology will play an increasingly important role in the development of MOFs for the foreseeable future (117 references).read more
Citations
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Journal ArticleDOI
Direct synthesis of nanoporous carbon nitride fibers using Al-based porous coordination polymers (Al-PCPs)
Ming Hu,Julien Reboul,Shuhei Furukawa,Logudurai Radhakrishnan,Yuanjian Zhang,Pavuluri Srinivasu,Hideo Iwai,Hongjing Wang,Yoshihiro Nemoto,Norihiro Suzuki,Susumu Kitagawa,Yusuke Yamauchi,Yusuke Yamauchi,Yusuke Yamauchi +13 more
TL;DR: A new synthetic route for preparation of nanoporous carbon nitride fibers with graphitic carbon Nitride polymers by calcination of Al-based porous coordination polymers with dicyandiamide under a nitrogen atmosphere is reported.
Journal ArticleDOI
Experimental progress in positronium laser physics
TL;DR: The field of experimental positronium physics has advanced significantly in the last few decades, with new areas of research driven by the development of techniques for trapping and manipulating positrons using Surko-type buffer gas traps as discussed by the authors.
Journal ArticleDOI
Metal–organic frameworks in fuel cell technologies
TL;DR: In this article, the progress in the research and development of MOFs for applications in hydrogen fuel cells with an emphasis on fuel generation, catalysts for cathode, electrolyte membranes, and H2 storage, along with some discussion on challenges and perspectives in this exciting and promising field.
Journal ArticleDOI
Arylation Chemistry for Bioconjugation.
Chi Zhang,Ekaterina V. Vinogradova,Ekaterina V. Vinogradova,Alexander M. Spokoyny,Alexander M. Spokoyny,Stephen L. Buchwald,Bradley L. Pentelute +6 more
TL;DR: Sulfur, nitrogen, selenium, oxygen, and carbon arylative bioconjugation strategies and their applications to modify peptides, proteins, sugars, and nucleic acids are outlined and reviewed.
Journal ArticleDOI
Post-combustion carbon capture
TL;DR: In this article, a review of post-combustion capture techniques, including thermal or pressure swing principles, adsorption or absorption, and electrical swing or membrane separation processes, is presented.
References
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Journal ArticleDOI
Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
Journal ArticleDOI
Click Chemistry: Diverse Chemical Function from a Few Good Reactions.
TL;DR: In this paper, a set of powerful, highly reliable, and selective reactions for the rapid synthesis of useful new compounds and combinatorial libraries through heteroatom links (C-X-C), an approach called click chemistry is defined, enabled, and constrained by a handful of nearly perfect "springloaded" reactions.
Journal ArticleDOI
Reticular synthesis and the design of new materials
Omar M. Yaghi,Michael O'Keeffe,Nathan W. Ockwig,Hee K. Chae,Hee K. Chae,Mohamed Eddaoudi,Jaheon Kim +6 more
TL;DR: This work has shown that highly porous frameworks held together by strong metal–oxygen–carbon bonds and with exceptionally large surface area and capacity for gas storage have been prepared and their pore metrics systematically varied and functionalized.
Journal ArticleDOI
Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
Journal ArticleDOI
Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.