Journal ArticleDOI
Postsynthetic modification of metal–organic frameworks
Zhenqiang Wang,Seth M. Cohen +1 more
TLDR
The rapid increase in reports on PSM demonstrates this methodology will play an increasingly important role in the development of MOFs for the foreseeable future, and in both scope of chemical reactions and range of suitable MOFs.Abstract:
The modification of metal–organic frameworks (MOFs) in a postsynthetic scheme is discussed in this critical review. In this approach, the MOF is assembled and then modified with chemical reagents with preservation of the lattice structure. Recent findings show amide couplings, isocyanate condensations, ‘click’ chemistry, and other reactions are suitable for postsynthetic modification (PSM). In addition, a number of MOFs, from IRMOF-3 to ZIF-90, are amenable to PSM. The generality of PSM, in both scope of chemical reactions and range of suitable MOFs, clearly indicates that the approach is broadly applicable. Indeed, the rapid increase in reports on PSM demonstrates this methodology will play an increasingly important role in the development of MOFs for the foreseeable future (117 references).read more
Citations
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Journal ArticleDOI
Topological Diversity, Adsorption and Fluorescence Properties of MOFs Based on a Tetracarboxylate Ligand
Ronny Grünker,Irena Senkovska,Ralf Biedermann,Nicole Klein,Andrea Klausch,Igor A. Baburin,Uwe Mueller,Stefan Kaskel +7 more
TL;DR: The combination of a tetradentate ligand with paddle-wheel SBUs based on Zn, Co or Cu has led to a series of new metal-organic frameworks with different structural motifs, depending on the additional acid present and the reaction temperature as discussed by the authors.
Journal ArticleDOI
Near-Infrared Luminescence and Inner Filter Effects of Lanthanide Coordination Polymers with 1,2-Di(4-pyridyl)ethylene.
Nicole Dannenbauer,Philipp R. Matthes,Thomas P. Scheller,Jörn Nitsch,Sven H. Zottnick,Markus S. Gernert,Andreas Steffen,Christoph Lambert,Klaus Müller-Buschbaum +8 more
TL;DR: Dipyridylethylene proves to be a suitable sensitizer for the photoluminescence of lanthanides in the near-infrared region (NIR) only and dpe differs from the related ligand 1,2-di(4-pyridyl)ethane.
Journal ArticleDOI
Metal-organic framework for the extraction and detection of pesticides from food commodities.
TL;DR: This review is based on a brief introduction of MOFs and highlights recent advances in pesticide extraction and detection through MOFs.
Journal ArticleDOI
Immobilization of thiol-functionalized ionic liquids onto the surface of MIL-101(Cr) frameworks by SCr coordination bond for biodiesel production
TL;DR: In this paper, a novel functionalized MOF heterogeneous catalyst (MIL-101(Cr) @MBIAILs), 2-Mercaptobenzimidazole ILs with electron-rich SH groups immobilized onto the surface of the well-defined MIL-101 (Cr) frameworks, was constructed and fabricated by the S Cr coordination bond on the basis of the facile post-synthetic modification strategy.
References
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Journal ArticleDOI
Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
Journal ArticleDOI
Click Chemistry: Diverse Chemical Function from a Few Good Reactions.
TL;DR: In this paper, a set of powerful, highly reliable, and selective reactions for the rapid synthesis of useful new compounds and combinatorial libraries through heteroatom links (C-X-C), an approach called click chemistry is defined, enabled, and constrained by a handful of nearly perfect "springloaded" reactions.
Journal ArticleDOI
Reticular synthesis and the design of new materials
Omar M. Yaghi,Michael O'Keeffe,Nathan W. Ockwig,Hee K. Chae,Hee K. Chae,Mohamed Eddaoudi,Jaheon Kim +6 more
TL;DR: This work has shown that highly porous frameworks held together by strong metal–oxygen–carbon bonds and with exceptionally large surface area and capacity for gas storage have been prepared and their pore metrics systematically varied and functionalized.
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Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
Journal ArticleDOI
Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.