Journal ArticleDOI
Postsynthetic modification of metal–organic frameworks
Zhenqiang Wang,Seth M. Cohen +1 more
TLDR
The rapid increase in reports on PSM demonstrates this methodology will play an increasingly important role in the development of MOFs for the foreseeable future, and in both scope of chemical reactions and range of suitable MOFs.Abstract:
The modification of metal–organic frameworks (MOFs) in a postsynthetic scheme is discussed in this critical review. In this approach, the MOF is assembled and then modified with chemical reagents with preservation of the lattice structure. Recent findings show amide couplings, isocyanate condensations, ‘click’ chemistry, and other reactions are suitable for postsynthetic modification (PSM). In addition, a number of MOFs, from IRMOF-3 to ZIF-90, are amenable to PSM. The generality of PSM, in both scope of chemical reactions and range of suitable MOFs, clearly indicates that the approach is broadly applicable. Indeed, the rapid increase in reports on PSM demonstrates this methodology will play an increasingly important role in the development of MOFs for the foreseeable future (117 references).read more
Citations
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Journal ArticleDOI
Decoration of the internal structure of mesoporous chromium terephthalate MIL-101 with NiO using atomic layer deposition
Myung-Geun Jeong,Dae Han Kim,Su-Kyung Lee,Ju Ha Lee,Sang Wook Han,Eun Ji Park,Katie A. Cychosz,Matthias Thommes,Young Kyu Hwang,Jong-San Chang,Young Dok Kim +10 more
TL;DR: In this paper, a mesoporous chromium terephthalate MIL-101 was modified with NiO via atomic layer deposition (ALD) process using bis(cyclopentadienyl)nickel (Ni(Cp) 2 ) as a metal precursor and O 2 as an oxidizing agent, respectively.
Journal ArticleDOI
Potential Applications of Nickel‐Based Metal‐Organic Frameworks and their Derivatives
Aasif Helal,Syed Shaheen Shah,Muhammad Usman,Mohd Yusuf Khan,Md. Abdul Aziz,Md. Mizanur Rahman +5 more
TL;DR: The recent achievements of Ni−MOFs and their derivatives as catalysts, membrane materials for CO2 separation and conversion, electrode materials and their respective performance have been discussed in this paper .
Journal ArticleDOI
Efficient Conversion of Biomass-Derived Levulinic Acid to γ-Valerolactone over Polyoxometalate@Zr-Based Metal-Organic Frameworks: The Synergistic Effect of Bro̷nsted and Lewis Acidic Sites.
TL;DR: In this paper, a series of H3PW12O40@Zr-based metal-organic framework (HPW@MOF-808) was fabricated by a facile impregnation method.
Journal ArticleDOI
Assorted functionality-appended UiO-66-NH2 for highly efficient uranium(VI) sorption at acidic/neutral/basic pH
Sarita Tripathi,Sarita Tripathi,B. Sreenivasulu,A. Suresh,A. Suresh,C. V. S. Brahmmananda Rao,C. V. S. Brahmmananda Rao,N. Sivaraman,N. Sivaraman +8 more
TL;DR: In this paper, a series of functionalized metal organic frameworks (MOFs) were synthesized by the post-synthetic modification (PSM) of Zr(IV)-containing UiO-66-NH2 MOFs using covalent grafting with various functional groups utilizing pendant NH2 moieties.
Journal ArticleDOI
Postsynthetic modification of IRMOF-3 with a copper iminopyridine complex as heterogeneous catalyst for the synthesis of 2-aminobenzothiazoles
TL;DR: In this article, a copper iminopyridine complex has been immobilized on to a metal-organic framework (MOF) through postsynthetic modification of IRMOF-3.
References
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Journal ArticleDOI
Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
Journal ArticleDOI
Click Chemistry: Diverse Chemical Function from a Few Good Reactions.
TL;DR: In this paper, a set of powerful, highly reliable, and selective reactions for the rapid synthesis of useful new compounds and combinatorial libraries through heteroatom links (C-X-C), an approach called click chemistry is defined, enabled, and constrained by a handful of nearly perfect "springloaded" reactions.
Journal ArticleDOI
Reticular synthesis and the design of new materials
Omar M. Yaghi,Michael O'Keeffe,Nathan W. Ockwig,Hee K. Chae,Hee K. Chae,Mohamed Eddaoudi,Jaheon Kim +6 more
TL;DR: This work has shown that highly porous frameworks held together by strong metal–oxygen–carbon bonds and with exceptionally large surface area and capacity for gas storage have been prepared and their pore metrics systematically varied and functionalized.
Journal ArticleDOI
Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
Journal ArticleDOI
Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.