Journal ArticleDOI
Postsynthetic modification of metal–organic frameworks
Zhenqiang Wang,Seth M. Cohen +1 more
TLDR
The rapid increase in reports on PSM demonstrates this methodology will play an increasingly important role in the development of MOFs for the foreseeable future, and in both scope of chemical reactions and range of suitable MOFs.Abstract:
The modification of metal–organic frameworks (MOFs) in a postsynthetic scheme is discussed in this critical review. In this approach, the MOF is assembled and then modified with chemical reagents with preservation of the lattice structure. Recent findings show amide couplings, isocyanate condensations, ‘click’ chemistry, and other reactions are suitable for postsynthetic modification (PSM). In addition, a number of MOFs, from IRMOF-3 to ZIF-90, are amenable to PSM. The generality of PSM, in both scope of chemical reactions and range of suitable MOFs, clearly indicates that the approach is broadly applicable. Indeed, the rapid increase in reports on PSM demonstrates this methodology will play an increasingly important role in the development of MOFs for the foreseeable future (117 references).read more
Citations
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Journal ArticleDOI
Biopolymer@Metal-Organic Framework Hybrid Materials: A Critical Survey
TL;DR: In this article, a review article spotlights the fashionable trend in bridging the field of MOF-based materials through the use of bio-based precursors (mainly biopolymers) and discusses how the holistic association of the MOF crystals and the biopolymer matrices resulted in promising materials with prominent properties.
Journal ArticleDOI
Enhancing CO2 adsorption of a Zn-phosphonocarboxylate framework by pore space partitions.
Yun Ling,Mingli Deng,Zhenxia Chen,Bing Xia,Xiaofeng Liu,Yongtai Yang,Yaming Zhou,Linhong Weng +7 more
TL;DR: Using structure-directing agents, pore space partitions of a Zn-phosphonocarboxylate framework have been achieved and selective adsorption of CO(2) over N( 2) has been greatly improved.
Journal ArticleDOI
Covalent and Selective Grafting of Polyethylene Glycol Brushes at the Surface of ZIF-8 for the Processing of Membranes for Pervaporation
Marvin Benzaqui,Marvin Benzaqui,Rocio Semino,Florent Carn,Sérgio R. Tavares,Nicolas Menguy,Mónica Giménez-Marqués,Mónica Giménez-Marqués,Elena Bellido,Patricia Horcajada,Thomas Berthelot,Anna I. Kuzminova,Maria E. Dmitrenko,Anastasia V. Penkova,Denis Roizard,Christian Serre,Christian Serre,Guillaume Maurin,Nathalie Steunou +18 more
TL;DR: In this article, the so-called graftfast reaction in water and at room temperature (RT) was applied to graft polyethylene glycol (PEG) at the surface of the microporous zeolitic imidazolate framework ZIF-8 nanoparticles (NPs) using acrylPEG of different chain lengths (480 Da and 5 kDa).
Journal ArticleDOI
Selective Adsorption Properties of Cationic Metal–Organic Frameworks Based on Imidazolic Linker
TL;DR: In this article, the imidazolium salt linker H2ImidCl was prepared in five steps and converted with zinc and copper nitrate, respectively, to give two topologically different cationic frameworks.
Journal ArticleDOI
Recent progress on synthesis of ZIF-67-based materials and their application to heterogeneous catalysis
TL;DR: In this paper, the authors summarized the latest strategies of synthesizing ZIF-67-based materials by exploring the prominent examples and shed some light on the large-scale industrial production of Zif-67based materials and their applications.
References
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Journal ArticleDOI
Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
Journal ArticleDOI
Click Chemistry: Diverse Chemical Function from a Few Good Reactions.
TL;DR: In this paper, a set of powerful, highly reliable, and selective reactions for the rapid synthesis of useful new compounds and combinatorial libraries through heteroatom links (C-X-C), an approach called click chemistry is defined, enabled, and constrained by a handful of nearly perfect "springloaded" reactions.
Journal ArticleDOI
Reticular synthesis and the design of new materials
Omar M. Yaghi,Michael O'Keeffe,Nathan W. Ockwig,Hee K. Chae,Hee K. Chae,Mohamed Eddaoudi,Jaheon Kim +6 more
TL;DR: This work has shown that highly porous frameworks held together by strong metal–oxygen–carbon bonds and with exceptionally large surface area and capacity for gas storage have been prepared and their pore metrics systematically varied and functionalized.
Journal ArticleDOI
Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
Journal ArticleDOI
Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.