Journal ArticleDOI
Postsynthetic modification of metal–organic frameworks
Zhenqiang Wang,Seth M. Cohen +1 more
TLDR
The rapid increase in reports on PSM demonstrates this methodology will play an increasingly important role in the development of MOFs for the foreseeable future, and in both scope of chemical reactions and range of suitable MOFs.Abstract:
The modification of metal–organic frameworks (MOFs) in a postsynthetic scheme is discussed in this critical review. In this approach, the MOF is assembled and then modified with chemical reagents with preservation of the lattice structure. Recent findings show amide couplings, isocyanate condensations, ‘click’ chemistry, and other reactions are suitable for postsynthetic modification (PSM). In addition, a number of MOFs, from IRMOF-3 to ZIF-90, are amenable to PSM. The generality of PSM, in both scope of chemical reactions and range of suitable MOFs, clearly indicates that the approach is broadly applicable. Indeed, the rapid increase in reports on PSM demonstrates this methodology will play an increasingly important role in the development of MOFs for the foreseeable future (117 references).read more
Citations
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Journal ArticleDOI
Spin-crossover modulation via single-crystal to single-crystal photochemical [2 + 2] reaction in Hofmann-type frameworks.
Long-Fei Wang,Wei-Man Zhuang,Guo-Zhang Huang,Yan-Cong Chen,Jiang-Zhen Qiu,Zhao-Ping Ni,Ming-Liang Tong +6 more
TL;DR: The dimerization of azastilbene ligands dramatically modulated SCO properties, providing a new strategy for exploiting photo-responsive SCO materials.
Journal ArticleDOI
Urea-modified metal-organic framework of type MIL-101(Cr) for the preconcentration of phosphorylated peptides
Xiaoqing Yang,Yan Xia +1 more
TL;DR: In this article, a two-step method for the synthesis of a metal organic framework of the type MIL-101(Cr) that is modified with urea (then designated as MIL 101(Cr)-UR2) was described.
Journal ArticleDOI
Homochiral metal–organic frameworks as heterogeneous catalysts
TL;DR: In this article, a mini-review of the structural design and catalytic performance of homochiral metal-organic frameworks (HMOFs) is presented, focusing on the relevance of the chemical reactions tested.
Journal ArticleDOI
Carbon Dioxide in Ionic Liquid Microemulsions
TL;DR: Tailor-made emulsion: a CO(2) -in-ionic-liquid microemulsion was produced for the first time, which has potential applications in materials synthesis, chemical reactions, and extraction.
Journal ArticleDOI
Post-Synthetic Annealing: Linker Self-Exchange in UiO-66 and Its Effect on Polymer–Metal Organic Framework Interaction
Stefan J. D. Smith,Stefan J. D. Smith,Kristina Konstas,Cher Hon Lau,Cher Hon Lau,Yesim Gozukara,Christopher D. Easton,Roger J. Mulder,Bradley P. Ladewig,Bradley P. Ladewig,Matthew R. Hill,Matthew R. Hill +11 more
TL;DR: In this article, the intersection of defect engineering and post-synthetic exchange is explored by exchanging an MOF with linkers already present within the framework, showing that PSA causes one linker species to preferentially accumulate on the MOF's crystal surface.
References
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Journal ArticleDOI
Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
Journal ArticleDOI
Click Chemistry: Diverse Chemical Function from a Few Good Reactions.
TL;DR: In this paper, a set of powerful, highly reliable, and selective reactions for the rapid synthesis of useful new compounds and combinatorial libraries through heteroatom links (C-X-C), an approach called click chemistry is defined, enabled, and constrained by a handful of nearly perfect "springloaded" reactions.
Journal ArticleDOI
Reticular synthesis and the design of new materials
Omar M. Yaghi,Michael O'Keeffe,Nathan W. Ockwig,Hee K. Chae,Hee K. Chae,Mohamed Eddaoudi,Jaheon Kim +6 more
TL;DR: This work has shown that highly porous frameworks held together by strong metal–oxygen–carbon bonds and with exceptionally large surface area and capacity for gas storage have been prepared and their pore metrics systematically varied and functionalized.
Journal ArticleDOI
Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
Journal ArticleDOI
Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.