Journal ArticleDOI
Postsynthetic modification of metal–organic frameworks
Zhenqiang Wang,Seth M. Cohen +1 more
TLDR
The rapid increase in reports on PSM demonstrates this methodology will play an increasingly important role in the development of MOFs for the foreseeable future, and in both scope of chemical reactions and range of suitable MOFs.Abstract:
The modification of metal–organic frameworks (MOFs) in a postsynthetic scheme is discussed in this critical review. In this approach, the MOF is assembled and then modified with chemical reagents with preservation of the lattice structure. Recent findings show amide couplings, isocyanate condensations, ‘click’ chemistry, and other reactions are suitable for postsynthetic modification (PSM). In addition, a number of MOFs, from IRMOF-3 to ZIF-90, are amenable to PSM. The generality of PSM, in both scope of chemical reactions and range of suitable MOFs, clearly indicates that the approach is broadly applicable. Indeed, the rapid increase in reports on PSM demonstrates this methodology will play an increasingly important role in the development of MOFs for the foreseeable future (117 references).read more
Citations
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Journal ArticleDOI
Tb post-functionalized La (III) metal organic framework hybrid probe for simple and highly sensitive detection of acetaldehyde
TL;DR: In this paper, a novel highly fluorescent hybrid system called Tb@La-MOF (Tb@{[La(hisp)(Hhisp(H2O)2]·2H 2O}n) has been synthesized via post-synthetic modification of metal-organic framework centered on inert lanthanum ion.
Journal ArticleDOI
Catalytic transesterifications by a Zn-bissalen mof containing open pyridyl groups inside 1D channels
TL;DR: The bisSalen ligand as mentioned in this paper was used as an organic linker for a Zn-bisSalen MOF and a 2D undulated sheet structure was determined from single-crystal X-ray diffraction studies.
Journal ArticleDOI
A disparate 3-D silver(I) coordination polymer of pyridine-3,5-dicarboxylate and pyrimidine with strong intermetallic interactions: X-ray crystallography, photoluminescence and antimicrobial activity
TL;DR: A polymeric silver complex, [Ag4(μ-pydc)2 (μ-pm)2]n (1) as discussed by the authors, has been synthesized and characterized by elemental analysis, IR spectroscopy, thermal analysis, and single-crystal X-ray diffraction.
Journal ArticleDOI
Breast Cancer Targeting of a Drug Delivery System through Postsynthetic Modification of Curcumin@N 3-bio-MOF-100 via Click Chemistry
Renata Carolina Alves,Zachary M. Schulte,Marcela Tavares Luiz,Patrícia Bento da Silva,Regina Célia Galvão Frem,Nathaniel L. Rosi,Marlus Chorilli +6 more
TL;DR: In this article, a tumor-targeting drug-loaded MOF using click chemistry to anchor functional folic acid (FA) molecules on the surface of N3-bio-MOF-100 was discussed.
Journal ArticleDOI
Circumventing Scaling Relations in Oxygen Electrochemistry Using Metal-Organic Frameworks.
TL;DR: This work shows that the *OOH binding energy and the theoretical limiting potential can be optimized by appropriately tuning the transition metal active site, the oxophilic spectator, and the MOF topology, and establishes bimetallic porphyrin-based MOFs as a viable materials platform for future experimental and theoretical ORR studies.
References
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Journal ArticleDOI
Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
Journal ArticleDOI
Click Chemistry: Diverse Chemical Function from a Few Good Reactions.
TL;DR: In this paper, a set of powerful, highly reliable, and selective reactions for the rapid synthesis of useful new compounds and combinatorial libraries through heteroatom links (C-X-C), an approach called click chemistry is defined, enabled, and constrained by a handful of nearly perfect "springloaded" reactions.
Journal ArticleDOI
Reticular synthesis and the design of new materials
Omar M. Yaghi,Michael O'Keeffe,Nathan W. Ockwig,Hee K. Chae,Hee K. Chae,Mohamed Eddaoudi,Jaheon Kim +6 more
TL;DR: This work has shown that highly porous frameworks held together by strong metal–oxygen–carbon bonds and with exceptionally large surface area and capacity for gas storage have been prepared and their pore metrics systematically varied and functionalized.
Journal ArticleDOI
Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
Journal ArticleDOI
Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.