Journal ArticleDOI
Postsynthetic modification of metal–organic frameworks
Zhenqiang Wang,Seth M. Cohen +1 more
TLDR
The rapid increase in reports on PSM demonstrates this methodology will play an increasingly important role in the development of MOFs for the foreseeable future, and in both scope of chemical reactions and range of suitable MOFs.Abstract:
The modification of metal–organic frameworks (MOFs) in a postsynthetic scheme is discussed in this critical review. In this approach, the MOF is assembled and then modified with chemical reagents with preservation of the lattice structure. Recent findings show amide couplings, isocyanate condensations, ‘click’ chemistry, and other reactions are suitable for postsynthetic modification (PSM). In addition, a number of MOFs, from IRMOF-3 to ZIF-90, are amenable to PSM. The generality of PSM, in both scope of chemical reactions and range of suitable MOFs, clearly indicates that the approach is broadly applicable. Indeed, the rapid increase in reports on PSM demonstrates this methodology will play an increasingly important role in the development of MOFs for the foreseeable future (117 references).read more
Citations
More filters
Post-Assembly Transformations of Porphyrin-Containing Metal-Organic Framework (MOF) Films Fabricated Via Automated Layer-By-Layer Coordination
Monica C. So,M. Hassan Beyzavi,Rohan Sawhney,Osama Shekhah,Mohamed Eddaoudi,Salih S. Al-Juaid,Joseph T. Hupp,Omar K. Farha,Omar K. Farha +8 more
TL;DR: In this article, the robustness of layer-by-layer (LbL)-assembled, pillared-paddlewheel-type MOF films toward conversion to new or modified MOFs via solvent-assisted linker exchange (SALE) and post-assembly linker metalation is demonstrated.
Journal ArticleDOI
Site-directed reduction engineering within bimetal-organic frameworks for efficient size-selective catalysis
TL;DR: In this paper, the reducibility of MOF clusters is first revealed via theoretical calculations from the viewpoint of the reduction potential energy (Ereduction), which serves as the basic principle for the site-directed reduction processing of MOFs.
Journal ArticleDOI
Recent advance in porous coordination polymers from the viewpoint of crystalline-state transformation
Zheng Yin,Ming-Hua Zeng +1 more
TL;DR: Recently, research of crystalline-state transformation involving the removal/inclusion of guest molecules in porous coordination polymers (PCPs) was underway as discussed by the authors, which can reveal the intrinsic relevance and interaction between the framework and guest molecules.
Journal ArticleDOI
Synthesis of Isoreticular Zinc(II)‐Phosphonocarboxylate Frameworks and Their Application in the Friedel–Crafts Benzylation Reaction
TL;DR: The catalytic results reveal that ZnPC-2 is an excellent heterogeneous Lewis acid catalyst with a high selectivity towards less bulky para-oriented products.
Journal ArticleDOI
Tuning the Subunits and Topologies in Cluster-Based Cobalt–Organic Frameworks by Varying the Reaction Conditions
TL;DR: In this paper, three tetra-, penta-, and hexanuclear cluster-based cobalt-organic frameworks, [Co2(L)3(HCO2)·MeOH]n (1), [Co5(L),6(OH)2(NO3)2·2H2O]n(2), and [CoL(H CO2)]n (3) [L = (E)-3-(pyridin-3-yl)acrylate], have been successfully synthesized.
References
More filters
Journal ArticleDOI
Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
Journal ArticleDOI
Click Chemistry: Diverse Chemical Function from a Few Good Reactions.
TL;DR: In this paper, a set of powerful, highly reliable, and selective reactions for the rapid synthesis of useful new compounds and combinatorial libraries through heteroatom links (C-X-C), an approach called click chemistry is defined, enabled, and constrained by a handful of nearly perfect "springloaded" reactions.
Journal ArticleDOI
Reticular synthesis and the design of new materials
Omar M. Yaghi,Michael O'Keeffe,Nathan W. Ockwig,Hee K. Chae,Hee K. Chae,Mohamed Eddaoudi,Jaheon Kim +6 more
TL;DR: This work has shown that highly porous frameworks held together by strong metal–oxygen–carbon bonds and with exceptionally large surface area and capacity for gas storage have been prepared and their pore metrics systematically varied and functionalized.
Journal ArticleDOI
Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
Journal ArticleDOI
Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.