Journal ArticleDOI
Postsynthetic modification of metal–organic frameworks
Zhenqiang Wang,Seth M. Cohen +1 more
TLDR
The rapid increase in reports on PSM demonstrates this methodology will play an increasingly important role in the development of MOFs for the foreseeable future, and in both scope of chemical reactions and range of suitable MOFs.Abstract:
The modification of metal–organic frameworks (MOFs) in a postsynthetic scheme is discussed in this critical review. In this approach, the MOF is assembled and then modified with chemical reagents with preservation of the lattice structure. Recent findings show amide couplings, isocyanate condensations, ‘click’ chemistry, and other reactions are suitable for postsynthetic modification (PSM). In addition, a number of MOFs, from IRMOF-3 to ZIF-90, are amenable to PSM. The generality of PSM, in both scope of chemical reactions and range of suitable MOFs, clearly indicates that the approach is broadly applicable. Indeed, the rapid increase in reports on PSM demonstrates this methodology will play an increasingly important role in the development of MOFs for the foreseeable future (117 references).read more
Citations
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Journal ArticleDOI
Microwave-assisted crystallization inclusion of spiropyran molecules in indium trimesate films with antidromic reversible photochromism
Feng Zhang,Xiaoqin Zou,Wei Feng,Xiaojun Zhao,Xiaofei Jing,Fuxing Sun,Hao Ren,Guangshan Zhu,Guangshan Zhu +8 more
TL;DR: In this paper, the assembly of nitrobenzospiropyran derivatives into JUC-120 nanocrystals (BSP/JUC120) is achieved by a microwave-assisted crystallization inclusion approach.
Journal ArticleDOI
Catalytic properties of pristine and defect-engineered Zr-MOF-808 metal organic frameworks
TL;DR: In this article, defect-engineered Zr-trimesate MOF-808 compounds (DE-MOF-802) have been prepared by mixing the tricarboxylate ligands with dicar boxylates ligands.
Journal ArticleDOI
Recent developments in the construction of metallacycle/metallacage-cored supramolecular polymers via hierarchical self-assembly.
TL;DR: Recent progress in metallacycle/metallacage-cored supramolecular polymers that were constructed by the combination of metal-ligand interactions and other orthogonal interactions (including hydrophobic or hydrophilic interactions, hydrogen bonding, van der Waals forces, π-π stacking, electrostatic interactions, host-guest interactions and covalent bonding) has been discussed.
Journal ArticleDOI
Metal organic framework synthesis in the presence of surfactants: towards hierarchical MOFs?
Beatriz Seoane,Alla Dikhtiarenko,Alvaro Mayoral,Carlos Téllez,Joaquín Coronas,Freek Kapteijn,Jorge Gascon +6 more
TL;DR: The effect of synthesis parameters on the textural properties of Al based MOFs synthesized in the presence of CTAB are reported.
Journal ArticleDOI
A coordination polymer of (Ph3P)AuCl prepared by post-synthetic modification and its application in 1-hexene/n-hexane separation.
Ana J. Nuñez,Lindsey N. Shear,Naween Dahal,Ilich A. Ibarra,Jiwoong Yoon,Young Kyu Hwang,Jong San Chang,Simon M. Humphrey +7 more
TL;DR: PCM-10 is a porous phosphine coordination material based on Ca(II) and tris(p-carboxylated) triphenylphosphine that yields an advanced material that can selectively adsorb 1-hexene over n-hexane at room temperature.
References
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Journal ArticleDOI
Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
Journal ArticleDOI
Click Chemistry: Diverse Chemical Function from a Few Good Reactions.
TL;DR: In this paper, a set of powerful, highly reliable, and selective reactions for the rapid synthesis of useful new compounds and combinatorial libraries through heteroatom links (C-X-C), an approach called click chemistry is defined, enabled, and constrained by a handful of nearly perfect "springloaded" reactions.
Journal ArticleDOI
Reticular synthesis and the design of new materials
Omar M. Yaghi,Michael O'Keeffe,Nathan W. Ockwig,Hee K. Chae,Hee K. Chae,Mohamed Eddaoudi,Jaheon Kim +6 more
TL;DR: This work has shown that highly porous frameworks held together by strong metal–oxygen–carbon bonds and with exceptionally large surface area and capacity for gas storage have been prepared and their pore metrics systematically varied and functionalized.
Journal ArticleDOI
Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
Journal ArticleDOI
Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.