Journal ArticleDOI
Postsynthetic modification of metal–organic frameworks
Zhenqiang Wang,Seth M. Cohen +1 more
TLDR
The rapid increase in reports on PSM demonstrates this methodology will play an increasingly important role in the development of MOFs for the foreseeable future, and in both scope of chemical reactions and range of suitable MOFs.Abstract:
The modification of metal–organic frameworks (MOFs) in a postsynthetic scheme is discussed in this critical review. In this approach, the MOF is assembled and then modified with chemical reagents with preservation of the lattice structure. Recent findings show amide couplings, isocyanate condensations, ‘click’ chemistry, and other reactions are suitable for postsynthetic modification (PSM). In addition, a number of MOFs, from IRMOF-3 to ZIF-90, are amenable to PSM. The generality of PSM, in both scope of chemical reactions and range of suitable MOFs, clearly indicates that the approach is broadly applicable. Indeed, the rapid increase in reports on PSM demonstrates this methodology will play an increasingly important role in the development of MOFs for the foreseeable future (117 references).read more
Citations
More filters
Journal ArticleDOI
Synthesis of a Chiral Crystal Form of MOF-5, CMOF-5, by Chiral Induction
Shi-Yuan Zhang,Shi-Yuan Zhang,Dan Li,Dong Guo,Hui Zhang,Wei Shi,Peng Cheng,Lukasz Wojtas,Michael J. Zaworotko +8 more
TL;DR: CMOF-5 undergoes a reversible single crystal-to-single crystal phase change to MOF- 5 when immersed in a variety of organic solvents, although N-methyl-2-pyrrolidone (NMP) does not induce loss of chirality.
Journal ArticleDOI
Advanced Smart Nanomaterials with Integrated Logic-Gating and Biocomputing: Dawn of Theranostic Nanorobots.
TL;DR: The concepts of nanomaterials with built-in biocomputing capabilities, which can be potentially used for drug delivery and other theranostic applications, are reviewed.
Journal ArticleDOI
Direct extraction of U(VI) from alkaline solution and seawater via anion exchange by metal-organic framework
Jian Qiang Li,Le Le Gong,Xue Feng Feng,Le Zhang,Hui Qiong Wu,Chang Sheng Yan,Yang Yang Xiong,Heng Ya Gao,Feng Luo +8 more
TL;DR: In this paper, a method of anionic exchange, based on a cationic MOF (metal-organic framework) adsorbent, was proposed to directly extract U(VI) from alkaline solution and seawater (South China Sea).
Journal ArticleDOI
Recent progress in the syntheses of mesoporous metal–organic framework materials
TL;DR: In this article, a review of the recent developments in the fabrication of hierarchically structured MOFs based on nanoscience techniques is presented, mainly focusing on the recent development of hierarchical structure of MOFs.
Journal ArticleDOI
Hydrophobic Metal-Organic Frameworks: Assessment, Construction, and Diverse Applications.
TL;DR: An overview of the recent studies on hydrophobic MOFs for various applications suggests the high versatility of this unique class of materials for practical use as either adsorbents or nanomaterials.
References
More filters
Journal ArticleDOI
Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
Journal ArticleDOI
Click Chemistry: Diverse Chemical Function from a Few Good Reactions.
TL;DR: In this paper, a set of powerful, highly reliable, and selective reactions for the rapid synthesis of useful new compounds and combinatorial libraries through heteroatom links (C-X-C), an approach called click chemistry is defined, enabled, and constrained by a handful of nearly perfect "springloaded" reactions.
Journal ArticleDOI
Reticular synthesis and the design of new materials
Omar M. Yaghi,Michael O'Keeffe,Nathan W. Ockwig,Hee K. Chae,Hee K. Chae,Mohamed Eddaoudi,Jaheon Kim +6 more
TL;DR: This work has shown that highly porous frameworks held together by strong metal–oxygen–carbon bonds and with exceptionally large surface area and capacity for gas storage have been prepared and their pore metrics systematically varied and functionalized.
Journal ArticleDOI
Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
Journal ArticleDOI
Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.