Showing papers on "Argon published in 2021"

Enhancement of hydrogen peroxide production from an atmospheric pressure argon plasma jet and implications to the antibacterial activity of plasma activated water

Abstract: We explore how to configure an argon atmospheric-pressure plasma jet for enhancing its production of hydrogen peroxide (H2O2) in deionised water (DIW). The plasma jet consists of a quartz tube of 1.5 mm inner diameter and 3 mm outer diameter, with an upstream internal needle electrode (within the tube) and a downstream external cylindrical electrode (surrounding the tube). The plasma is operated by purging argon through the glass tube and applying a sinusoidal AC voltage to the internal needle electrode at 10 kV (peak-peak) with a frequency of 23.5 kHz. We study how the following operational parameters influence the production rate of H2O2 in water: tube length, inter-electrode separation distance, distance of the ground electrode from the tube orifice, distance between tube orifice and the DIW, argon flow rate and treatment time. By examining the electrical and optical properties of the plasma jet, we determine how the above operational parameters influence the major plasma processes that promote H2O2 generation through electron-induced dissociation reactions and UV photolysis within the plasma core and in the plasma afterglow; but with a caveat being that these processes are highly dependent on the water vapour content from the argon gas supply and ambient environment. We then demonstrate how the synergistic action between H2O2 and other plasma generated molecules at a plasma induced low pH in the DIW is highly effective at decontaminating common wound pathogens Gram-positive Staphylococus aureus and Gram-negative Pseudomonas aeruginosa. The information presented in this study is relevant in the design of medical plasma devices where production of plasma reactive species such as H2O2 at physiologically useful concentrations is needed to help realise the full clinical potential of the technology.

Scaling rules for high quality soliton self-compression in hollow-core fibers

Abstract: Soliton dynamics can be used to temporally compress laser pulses to few fs durations in many different spectral regions. Here we study analytically, numerically and experimentally the scaling of soliton dynamics in noble gas-filled hollow-core fibers. We identify an optimal parameter region, taking account of higher-order dispersion, photoionization, self-focusing, and modulational instability. Although for single-shots the effects of photoionization can be reduced by using lighter noble gases, they become increasingly important as the repetition rate rises. For the same optical nonlinearity, the higher pressure and longer diffusion times of the lighter gases can considerably enhance the long-term effects of ionization, as a result of pulse-by-pulse buildup of refractive index changes. To illustrate the counter-intuitive nature of these predictions, we compressed 250 fs pulses at 1030 nm in an 80-cm-long hollow-core photonic crystal fiber (core radius 15 µm) to ∼5 fs duration in argon and neon, and found that, although neon performed better at a repetition rate of 1 MHz, stable compression in argon was still possible up to 10 MHz.

Development of a lumping methodology for the analysis of the excited states in plasma discharges operated with argon, neon, krypton, and xenon

Abstract: In this paper, a methodology is presented to compute the plasma properties (e.g.,, density and temperature) accounting for the dynamics of the excited states. The proposed strategy applies to both zero-dimensional (0D) models and multidimensional fluid and hybrid codes handling low-pressure (<50 mTorr) plasma discharges filled with argon, neon, krypton, and xenon gases. The paper focuses on two main aspects: (i) a lumping methodology is proposed to reduce the number of reactions and species considered in order to keep at bay the computational cost without a major loss of accuracy; (ii) the influence that different datasets of cross sections have on the results has been assessed. First, the lumping methodology has been implemented in a 0D model accounting for singly charged ions, neutrals, along with 1s and 2p excited states (Paschen notation). Metastable and resonant are treated as two separate species within the 1s energy level ( 1sM and 1sR, respectively). The results have been benchmarked against those obtained treating each energy level of the excited states as an individual species. Differences lower than 1% have been obtained. Second, the results of the 0D model have been compared against measurements of electron density and temperature performed on an inductively coupled plasma. Numerical predictions and experiments present a disagreement up to 20%–30%, which is comparable to the uncertainty band of the measurements. Finally, the lumping strategy has been implemented in a 2D fluid code to assess its computational affordability, and the results have been compared against the experiments as well. A variance up to 30% in electron density and temperature is registered adopting different datasets of cross sections.

SiPM-matrix readout of two-phase argon detectors using electroluminescence in the visible and near infrared range

Abstract: Proportional electroluminescence (EL) in noble gases is used in two-phase detectors for dark matter searches to record (in the gas phase) the ionization signal induced by particle scattering in the liquid phase. The “standard” EL mechanism is considered to be due to noble gas excimer emission in the vacuum ultraviolet (VUV). In addition, there are two alternative mechanisms, producing light in the visible and near infrared (NIR) ranges. The first is due to bremsstrahlung of electrons scattered on neutral atoms (“neutral bremsstrahlung”, NBrS). The second, responsible for electron avalanche scintillation in the NIR at higher electric fields, is due to transitions between excited atomic states. In this work, we have for the first time demonstrated two alternative techniques of the optical readout of two-phase argon detectors, in the visible and NIR range, using a silicon photomultiplier matrix and electroluminescence due to either neutral bremsstrahlung or avalanche scintillation. The amplitude yield and position resolution were measured for these readout techniques, which allowed to assess the detection threshold for electron and nuclear recoils in two-phase argon detectors for dark matter searches. To the best of our knowledge, this is the first practical application of the NBrS effect in detection science.

Physical and mathematical modeling of interaction of detonation waves with inert gas plugs

Abstract: In the paper the physical and mathematical model for the description of the processes of transition, attenuation and suppression of detonation in hydrogen-air mixture in one- and two-dimensional formulation, taking into account reduced and detailed kinetics of chemical transformations in reactive gases, by inert gas plugs was proposed. On the basis of this model calculations of the interaction of plane (in one-dimensional formulation) and cellular (in two-dimensional formulation) detonation wave propagating in hydrogen-air mixture with layer of inert gases (argon, nitrogen, carbon dioxide) were performed. It was shown that depending on the type of isolating gas and the length of the plug various flow regimes were realized after the shock wave exits from the inert gas plug: a) reinitiation of detonation wave; b) suppression of the detonation wave with the formation of a deflagration wave at the end of the inert gas plug; c) suppression of the detonation wave with the combustion zone isolation by inert gas plug. The geometric limits of detonation (minimum inert gas plug length leads to detonation suppression with combustion zone isolation) for all three types of inert gas plugs were calculated. Comparison of the effectiveness of detonation suppression by various inert gas plugs shows that the carbon dioxide is more efficient for suppressing the detonation wave, i.e. geometric limits of detonation during interaction of detonation with carbon dioxide plug is smallest compared with other two types of plugs.

Reduction of incandescent spatter with helium addition to the process gas during laser powder bed fusion of Ti-6Al-4V

Abstract: The effect of the process gas during laser powder bed fusion (L-PBF) was investigated using high-speed shadowgraphy while melting Ti-6Al-4V powder under high purity argon, helium, and a mixture of both, on a laboratory-scale machine. These recordings reveal that the generation of incandescent spatters can be reduced by at least 60% using pure helium and by ∼30% using addition of helium to argon in comparison to the use of traditional argon. The quantity of colder spatters appeared unaffected by the change of process gas. Different configurations of gas flow versus laser scanning direction were investigated and revealed that fumes and spatters are less accumulated at the laser spot with helium addition. Furthermore, the use of the argon–helium mixture proved to be as efficient as pure argon in the dragging and extraction of the fumes. Shadowgraphs revealed the more rapid expansion of fumes in helium-rich atmospheres, limiting the accumulation of scattering objects close to the laser spot and thus melt pool instability. These results were correlated to process snapshots on an industrial-scale system, confirming the reduction of hot spatter generation. Finally, the findings put in evidence the more rapid cooling of spatters with helium addition to the process gas – a promising aspect to limit powder bed degradation during L-PBF. In addition, the use of mixtures of helium and argon would be economically interesting compared to pure helium, typically more expensive than the traditionally used argon.

Benchmarked and upgraded particle-in-cell simulations of a capacitive argon discharge at intermediate pressure : the role of metastable atoms

Abstract: The capacitive argon discharge operated in the intermediate pressure regime is studied by performing one-dimensional particle-in-cell Monte Carlo collision simulations. First, the basic object-oriented plasma device code (oopd1-v1) is strictly benchmarked against the well-established xpdp1 code over a wide range of pressure (0.05 – 15 Torr) and varying blocking capacitor of the external circuit (5 – 10^5nF), and excellent agreement is obtained. The oopd1-v1 is upgraded to v2 and v3, by adding excited atoms modeled as time- and space-evolving fluid species. The metastable Arm, the radiative Arr, and the Ar(4p) manifold, and their roles in discharge equilibrium are explored. It is found that the presence of the metastable Arm enhances the plasma density by a factor of 3 at 1.6 Torr and even higher at pressures up to 5 Torr. At low pressure (0.05 Torr), electron impact ionization from the ground state atom dominates the ionization over the whole discharge region, while metastable pooling and step-wise ionization has small contribution. The proportion of metastable pooling ionization and step-wise ionization increases with increasing pressure and becomes the dominant ionization source at 5 – 15 Torr.

Comparison of divertor behavior and plasma confinement between argon and neon seeding in EAST

Abstract: The exhaust of excessively high heat and particle fluxes on the divertor target is crucial for EAST long-pulse operation. In the recent EAST experiments, stable partial energy detachment around the upper outer strike point with H 98,y2 ∼ 1 was achieved with either Ne or Ar seeding from the upper outer divetor target in the upper single null configuration with ITER-like tungsten divertor. With either Ar or Ne seeding, the electron temperature around the upper outer strike point (T et,UOSP) was maintained at around 5 eV, the peak temperature of divertor target surface around the upper outer strike point (T div,UO) decreased significantly, and material sputtering was well suppressed. It was observed that there was less Ar seeding needed for partial energy detachment onset than Ne seeding, which shows that Ar is more efficient in the cooling of T et on the upper outer divertor than Ne. However, there was no detachment on the upper inner divertor with T et around strike point (T et,UISP) remaining >10 eV with either Ar or Ne seeding from the upper outer divertor. Accompanied with the disappearance of double peak phenomenon of ion flux density on the upper inner divertor target (j s,UI), the peak T div,UI around the strike point increased to around 300 °C. Although the heat flux on the upper inner divertor target (q t,UI) is still in the acceptable level, either Ar or Ne seeding only from the upper outer divertor target is not enough to protect the upper inner divertor target from sputtering under current EAST conditions. On the other hand, Ar seeding always causes confinement degradation in the partial energy detachment state. It was observed that there is a slight confinement improvement (∼10%) with Ne seeding, which may be due to density peaking, dilution effects and stabilization of the ion temperature gradient mode.

Physicochemical Properties of Pure Water Treated by Pure Argon Plasma Jet Generated by Microwave Discharge in Opened Atmosphere

Abstract: The physicochemical properties of water activated by high-purity low-temperature argon plasma of electrodeless microwave discharge at atmospheric pressure are investigated. Such parameters of activated water as electrical conductivity, redox potential, hydrogen index (pH), the concentrations of dissolved molecular oxygen, hydrogen peroxide, OH-radicals, nitrate and nitrite anions depending on the plasma jet distance above the water surface and duration of activation were studied. Under irradiation conditions close to optimum, it was shown that the generation rate in the absence of impurities are 200 M/min for H2O2; 800 M/min for •OH and 2 mM/min for NOx. The use of plasma activated water (PAW) in agriculture has been tested. It was shown that strawberry seeds treated with a surfactant solution grow much faster than control seeds. The mechanisms of the chemical composition formation of activated water and its biological properties are discussed.

Electron dynamics in radio frequency magnetron sputtering argon discharges with a dielectric target

Abstract: We demonstrate a self-consistent and complete description of electron dynamics in a typical electropositive radio frequency magnetron sputtering (RFMS) argon discharge with a dielectric target. The electron dynamics, including the electron power absorption dynamics in one radio frequency (RF) period, is studied via a fully kinetic 2d3v particle-in-cell/Monte Carlo collision (PIC/MCC) electrostatic simulation. The interplay between the fundamental plasma parameters is analyzed through their spatiotemporal dynamics. Due to the influence of magnetic trap on the electron transport, a spatially dependent charging that perturbs the electric potential is observed on the dielectric target surface, resulting in a spatially dependent ion energy distribution along the target surface. The E × B drift-to-discharge current ratio is in approximate agreement with Bohm diffusion. The electron power absorption can be primarily decoupled into the positive Ohmic power absorption in the bulk plasma region and the negative pressure-induced power absorption near the target surface. Ohmic power absorption is the dominant electron power absorption mechanism, mostly contributed by the azimuthal electron current. The power absorption due to electron inertial effects is negligible on time-average. Both the maximum power absorption and dissipation of electrons appear in the bulk plasma region during the second half of the RF period, implying a strong electron trapping in magnetron discharges. The contribution of secondary electrons is negligible under typical RFMS discharge conditions.

Measurement of electron temperature and density of atmospheric-pressure non-equilibrium argon plasma examined with optical emission spectroscopy

Abstract: Electron temperature Te and density Ne of the atmospheric-pressure non-equilibrium dielectric barrier discharge (DBD) Ar plasma are measured with optical emission spectroscopy (OES). Continuum emission due to bremsstrahlung is applied to the analysis of the electron temperature and density with spectrometric system in the visible wavelength range calibrated absolutely. The assumption of Maxwellian electron energy distribution function (EEDF) results in Te~0.29 eV and Ne~1.1×1016cm-3, whereas the Druyvesteyn EEDF leads to the result Te~0.79eV and Ne~1.4×1014cm-3. To confirm the validity of these values, several line intensities of excited states of Ar atom are observed experimentally and compared with the theoretical population densities calculated by the argon collisional radiative (CR) model that includes atomic collisional processes. It is confirmed that the order of the observed excited-state number densities agrees well with the ones calculated numerically by the CR model with the Druyvesteyn EEDF, while the Maxwellian EEDF gives poor results.

Effect of a helium gas atmosphere on the mechanical properties of Ti-6Al-4V alloy built with laser powder bed fusion: A comparative study with argon gas

Abstract: In metal additive manufacturing, the microstructures and associated mechanical properties of metal specimens can be controlled over a wide range. Although process parameters are considered important in the fabrication of functional parts, the effect of atmospheric gas has not been comprehensively documented. In laser powder bed fusion (LPBF), gas flow is used to eliminate fumes generated by laser irradiation. Simultaneously, the gas removes heat from the laser-irradiated part, which is exposed to high temperature. In this study, we investigated the capacity of helium as an alternative to argon, which is conventionally used as the LPBF atmosphere gas. He has a higher thermal conductivity and lower gas density than Ar, which may result in enhanced heat removal from the Ti-6Al-4V alloy during fabrication. Numerical simulations suggest a greater cooling rate under He flow. Further, the material built under He flow contained finer α' martensite grains and showed improved mechanical properties compared to those fabricated under Ar flow, despite the identical laser irradiation conditions. Thus, He gas is advantageous in LPBF for fabricating products with superior mechanical performance through microstructural refinement, and this is a result of its capacity for cooling and fume generation inhibition. Therefore, this study reveals the importance of the choice of atmospheric gas because of its effects on the characteristics of metallic specimens fabricated using LPBF.

Hydrogen isotopic analysis of nuclear reactor materials using ultrafast laser-induced breakdown spectroscopy.

Abstract: Laser-induced breakdown spectroscopy is a promising method for rapidly measuring hydrogen and its isotopes, critical to a wide range of disciplines (e.g. nuclear energy, hydrogen storage). However, line broadening can hinder the ability to detect finely spaced isotopic shifts. Here, the effects of varying plasma generation conditions (nanosecond versus femtosecond laser ablation) and ambient environments (argon versus helium gas) on spectral features generated from Zircaloy-4 targets with varying hydrogen isotopic compositions were studied. Time-resolved 2D spectral imaging was employed to detail the spatial distribution of species throughout plasma evolution. Results highlight that hydrogen and deuterium isotopic shifts can be measured with minimal spectral broadening in a ∼ 10 Torr helium gas environment using ultrafast laser-produced plasmas.

Comparison of atmospheric pressure argon producing O(1S) and helium plasma jet on methylene blue degradation

Abstract: A solution of methylene blue dye was degraded under an atmospheric pressure plasma jet operating in a linear field configuration with pure argon or pure helium as working gases. Optical emission spectroscopy was carried out to understand the reactive species present with and without dye treatment. Both plasma jets contain reactive species such as OH, N2, and atomic oxygen (O). However, atomic oxygen takes a greatly different form depending on the working gas. In the argon plasma jet, we observe that most of the atomic oxygen produced is the O(1S)–O(1D) transition that also leads to the green colored plasma plume. On the other hand, the helium plasma jet produces the well known triplet states of oxygen at 777 and 844 nm. The absorption spectra confirmed the faster and more energy efficient degradation of the methylene blue dye when treated by the argon plasma jet. Argon plasma with enhanced atomic oxygen content can be utilized as a cheaper and efficient method for waste water treatment.

Detection capability of the Migdal effect for argon and xenon nuclei with position-sensitive gaseous detectors

Abstract: The Migdal effect is attracting interest because of the potential to enhance the sensitivities of direct dark matter searches to the low-mass region. In spite of its great importance, the Migdal effect has not been experimentally observed yet. A realistic experimental approach towards the first observation of the Migdal effect in the neutron scattering was studied with Monte Carlo simulations. In this study, the potential background rate was studied together with the event rate of the Migdal effect by a neutron source. It was found that a table-top-sized |$\sim (30~\mbox{cm})^3$| position-sensitive gaseous detector filled with argon or xenon target gas can detect characteristic signatures of the Migdal effect with sufficient rates (O(⁠|$10^2\sim10^3$|⁠) events per day). A simulation result of a simple experimental set-up showed two significant background sources, namely the intrinsic neutrons and the neutron-induced gamma-rays. It is found that the intrinsic neutron background rate for the argon gas is at an acceptable level and some future study of the reduction of the gamma-rays from the laboratory would make the observation of the Migdal effect possible. The background for the xenon gas, on the other hand, is found to be much more serious than for the argon gas. Future works on the isotope separation as well as the reduction of the gamma-rays from the detector and laboratory will be needed before the Migdal effect can be observed for the xenon gas case.

High-voltage arc erosion behavior and mechanism of Ti3AlC2 under different ambient atmospheres

Abstract: The arc erosion behavior of Ti3AlC2 in oxygen, air, nitrogen, carbon dioxide, argon, and sulfur hexafluoride atmospheres at 9 kV voltage was studied. The breakdown strength increased in the order of oxygen, air, carbon dioxide, nitrogen, argon, and sulfur hexafluoride, whereas the arc energy decreased. Cracks, pits, and bulges on the eroded surface were investigated using scanning electron microscopy and three-dimensional (3D) laser confocal scanning microscopy. Raman spectroscopy and X-ray photoelectron spectroscopy (XPS) were used to determine the composition of the eroded surface. The arc energy and electromagnetic force lead to the formation of erosion characteristics. The mechanism of erosion under the different atmospheres is discussed systematically, and is called the “decomposition-oxidation” process in oxygen, air, and carbon dioxide and the “decomposition-rereaction” process in nitrogen and sulfur hexafluoride. This study provides a reference for the application of MAX phase materials in high-voltage electrical appliances.

Wavelength-Shifting Performance of Polyethylene Naphthalate Films in a Liquid Argon Environment

Abstract: Liquid argon is commonly used as a detector medium for neutrino physics and dark matter experiments in part due to its copious scintillation light production in response to its excitation and ionization by charged particle interactions. As argon scintillation appears in the vacuum ultraviolet (VUV) regime and is difficult to detect, wavelength-shifting materials are typically used to convert VUV light to visible wavelengths more easily detectable by conventional means. In this work, we examine the wavelength-shifting and optical properties of poly(ethylene naphthalate) (PEN), a recently proposed alternative to tetraphenyl butadiene (TPB), the most widely-used wavelength-shifter in argon-based experiments. In a custom cryostat system with well-demonstrated geometric and response stability, we use 128~nm argon scintillation light to examine various PEN-including reflective samples' light-producing capabilities, and study the stability of PEN when immersed in liquid argon. The best-performing PEN-including test reflector was found to produce 34% as much visible light as a TPB-including reference sample, with widely varying levels of light production between different PEN-including test reflectors. Plausible origins for these variations, including differences in optical properties and molecular orientation, are then identified using additional measurements. Unlike TPB-coated samples, PEN-coated samples did not produce long-timescale light collection increases associated with solvation or suspension of wavelength-shifting material in bulk liquid argon.