Cross River University of Technology

About: Cross River University of Technology is a education organization based out in Calabar, Nigeria. It is known for research contribution in the topics: Population & Exergy. The organization has 465 authors who have published 507 publications receiving 2705 citations.

Public Expenditure and Human Development in Nigeria

Abstract: This paper examines public expenditure and the pace of human development in Nigeria. It advocates that irrespective of huge spending pattern and trend of government, there is a growing incidence of poverty in the land. Even though public spending plays a significant role in the development of sub-Saharan economies, the experience of Nigeria reflects a backward movement. This calls for severe antidote so as to curb the excesses of the situation. There has been serious external and internal imbalances, narrow and disarticulate production base, lopsided pattern of development and declining foreign exchange earnings among other drawbacks. This implies that the human development situation in Nigeria does not offer any cheering news.

Synthesis, characterization, DFT, and TD-DFT studies of (E)-5-((4,6-dichloro-1,3,5-triazin-2-yl)amino)-4-hydroxy-3-(phenyldiazenyl)naphthalene-2,7-diylbis(hydrogen sulfite)

Abstract: In this study, (E)-5-((4,6-dichloro-1,3,5-triazin-2-yl)amino)-4-hydroxy-3-(phenyldiazenyl)naphthalene-2,7-diylbis(hydrogen sulfite), a cyanurated H-acid (CHA) azo dye, was synthesized and characterized using FT-IR spectrophotometer and GC-MS spectroscopy. A density functional theory (DFT) based B3LYP and CAM-B3LYP method with 6–311 + G (d,p) basis set analysis was computed for HOMO-LUMO, natural bonding orbitals (NBO), UV-Vis absorptions and excitation interactions, in order to understand its molecular orbital excitation properties. A low Energy gap (Eg) of 2.947 eV was obtained from the molecular orbital analysis, which showed that HOMO to LUMO transition is highly feasible; hence CHA is adequate for diverse electronic and optic applications. Studies of the first five excitations (S0 → S1/S2/S3/S4/S5) of CHA revealed that S0 → S1 and S0 → S3 are π → π* type local excitations distributed around the –N=N– group; S0 → S2, a Rydberg type local excitation; S0 → S4, a highly localized π → π* excitation; while S0 → S5 is an n → π* charge transfer from a benzene ring to –N=N– group. From NBO analysis, we obtained the various donor–acceptor orbital interactions contributing to the stabilization of the studied compound. Most significantly, some strong hyper-conjugations (n → n*) within fragments, and non-bondingand anti-bonding intermolecular (n → n*/π* and π → n*/π*) interactions were observed to contribute appreciable energies. This study is valuable for understanding the molecular properties of the azo dyes compounds and for synthesizing new ones in the future.

Analysis of the effects of meteorological parameters on radio refractivity, equivalent potential temperature and field strength via Mann-Kendall test

Abstract: Trend analysis of meteorological parameters (temperature, pressure, and relative humidity) as well as calculated refractivity, equivalent potential temperature (EPT) for a pseudo-adiabatic process, and field strength in Calabar, Southern Nigeria has been analyzed using Mann-Kendall (M-K) trend test and Sen’s slope estimator (SSE). Data of the meteorological parameters were obtained from the Nigerian Meteorological Agency (NiMet) in Calabar for 14 years (2005–2018). Results show that the maximum and average temperature, atmospheric pressure, refractivity, EPT, and field strength all exhibited a positive Kendall Z value with 2.52, 0.33, 3.83, 0.77, 0.44, and 3.18 respectively which indicated an increase in trend over time, with only maximum temperature, atmospheric pressure and field strength showing a significant increase at 5% (0.05) level of significance, since their calculated p values (0.012, 0.0001, and 0.001) were less than 0.05. The relative humidity and minimum ambient temperature had a decrease in trend over time as they both had negative Kendall Z values (− 0.11 and − 1.09 respectively); however, together with the average ambient temperature and refractivity, their trend was not significant at 5% level of significance since their calculated p values were all more than 0.05. Linear regression, correlation, and partial differentiation showed that relative humidity has the most effect on the changes in seasonal refractivity and an indirect relationship with field strength variability. The novel relationship between EPT and refractivity has been discovered to be very strong and positive. Descriptive statistics has been used to portray the seasonal and annual trend of all parameters.

Flood vulnerability assessment of the upper Cross River basin using morphometric analysis

Abstract: Cross River, which originates from Cameroon, flows through several communities in Nigeria. The population upsurge and settlements near the river channel, however, portends the possibility of natura...