Dalian University of Technology

About: Dalian University of Technology is a education organization based out in Dalian, China. It is known for research contribution in the topics: Catalysis & Finite element method. The organization has 60890 authors who have published 71921 publications receiving 1188356 citations. The organization is also known as: Dàlián Lǐgōng Dàxué.

Flexible MXene/Silver Nanowire-Based Transparent Conductive Film with Electromagnetic Interference Shielding and Electro-Photo-Thermal Performance.

Abstract: Transparent conductive film (TCF) is promising for optoelectronic instrument applications. However, designing a robust, stable, and flexible TCF that can shield electromagnetic waves and work in harsh conditions remains a challenge. Herein, a multifunctional and flexible TCF with effective electromagnetic interference shielding (EMI) performance and outstanding electro-photo-thermal effect is proposed by orderly coating Ti3C2Tx MXene and a silver nanowire (AgNW) hybrid conductive network using a simple and scalable solution-processed method. Typically, the air-plasma-treated polycarbonate (PC) film was sequentially spray-coated with MXene and AgNW to construct a highly conductive network, which was transferred and partly embedded into an ultrathin poly(vinyl alcohol) (PVA) film using spin coating coupled with hot pressing to enhance the interfacial adhesion. The peeled MXene/AgNW-PVA TCF exhibits an optimal optical and electrical performance of sheet resistance 18.3 Ω/sq and transmittance 52.3%. As a consequence, the TCF reveals an effective EMI shielding efficiency of 32 dB in X-band with strong interfacial adhesion and satisfactory flexibility. Moreover, the high electrical conductivity and localized surface plasmon resonance (LSPR) effect of hybrid conductive network endow the TCF with low-voltage-driven Joule heating performance and excellent photothermal effect, respectively, which can ensure the normal functioning under extreme cold condition. In view of the comprehensive performance, this work offers new solutions for next-generation transparent EMI shielding challenges.

Output-Feedback Cooperative Formation Maneuvering of Autonomous Surface Vehicles With Connectivity Preservation and Collision Avoidance

Abstract: In this paper, a cooperative time-varying formation maneuvering problem with connectivity preservation and collision avoidance is investigated for a fleet of autonomous surface vehicles (ASVs) with position–heading measurements. Each vehicle is subject to unknown kinetics induced by internal model uncertainty and external disturbances. At first, a nonlinear state observer is used to recover the unmeasured linear velocity and yaw rate as well as unknown uncertainty and disturbances. Then, observer-based cooperative time-varying formation maneuvering control laws are designed based on artificial potential functions, nonlinear tracking differentiators, and a backstepping technique. The stability of closed-loop distributed formation control system is analyzed based on input-to-state stability and cascade stability. The salient features of the proposed method are as follows. First, cooperative time-varying formation maneuvering with the capability of connectivity preservation and collision avoidance can be achieved in the absence of velocity measurements. Second, the complexity of the cooperative time-varying formation maneuvering control laws is reduced without resorting to dynamic surface control. Third, the uncertainty and disturbance are actively rejected in the presence of position–heading measurements. Simulation results are given to substantiate the proposed output feedback control method for cooperative time-varying formation maneuvering of ASVs with connectivity preservation and collision avoidance.

Luminescent Metal‐Organic Frameworks for Selectively Sensing Nitric Oxide in an Aqueous Solution and in Living Cells

Abstract: Cu2+-based metal-organic framework (Cu−TCA) (H3TCA = tricarboxytriphenyl amine) having triphenylamine emitters was assembled and structurally characterized. Cu−TCA features a three-dimensional porous structure consolidated by the well-established Cu2(O2CR)4 paddlewheel units with volume of the cavities approximately 4000 nm3. Having paramagnetic Cu2+ ions to quench the luminescence of triphenylamine, Cu−TCA only exhibited very weak emission at 430 nm; upon the addition of NO up to 0.1 mM, the luminescence was recovered directly and provided about 700-fold fluorescent enhancement. The luminescence detection exhibited high selectivity – other reactive species present in biological systems, including H2O2, NO3−, NO2−, ONOO−, ClO− and 1O2, did not interfere with the NO detection. The brightness of the emission of Cu−TCA also led to its successful application in the biological imaging of NO in living cells. As a comparison, lanthanide metal-organic framework Eu−TCA having triphenylamine emitters and characteristic europium emitters was also assembled. Eu−TCA exhibited ratiometric fluorescent responses towards NO with the europium luminescence maintained as the internal standard and the triphenylamine emission exhibited more than 1000-fold enhancement.

Acid hydrazides, potent reagents for synthesis of oxygen-, nitrogen-, and/or sulfur-containing heterocyclic rings.

Abstract: Nitrogen‐, and/or Sulfur-Containing Heterocyclic Rings Poulomi Majumdar,†,‡ Anita Pati,†,§ Manabendra Patra, Rajani Kanta Behera,† and Ajaya Kumar Behera*,† †Organic Synthesis Laboratory, School of Chemistry, Sambalpur University, Jyoti Vihar, Burla 768019, Orissa, India ‡State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, Dalian, 116024, P.R. China School of Applied Sciences (Chemistry), KIIT University, Bhubaneswar 751024, India National Institute of Science & Technology, Palur Hill, Berhampur 761068, Orissa, India