Institution
Environmental Molecular Sciences Laboratory
Facility•Richland, Washington, United States•
About: Environmental Molecular Sciences Laboratory is a facility organization based out in Richland, Washington, United States. It is known for research contribution in the topics: Mass spectrometry & Ion. The organization has 1471 authors who have published 3010 publications receiving 169961 citations.
Topics: Mass spectrometry, Ion, X-ray photoelectron spectroscopy, Catalysis, Fourier transform ion cyclotron resonance
Papers published on a yearly basis
Papers
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TL;DR: A sample calculation is presented and its performance and accuracy is compared to an “exact” direct SCF calculation and problems and limitations of the method are discussed.
Abstract: The resolution of the identity (RI) approximation to the Hartree–Fock method was implemented within the NWChem suite of ab initio programs for parallel computers. After a description of the method, a detailed account of the implementation is given. We present a sample calculation and compare its performance and accuracy to an “exact” direct SCF calculation. Problems and limitations of the method are also discussed. © 1997 John Wiley & Sons, Inc. Int J Quant Chem 64: 63–69, 1997
69 citations
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TL;DR: Comparison of the UV and green laser data suggests that the green wavelength energy was absorbed less efficiently than the UV wavelength because of differences in absorption at 355 and 532 nm for LiFePO₄.
69 citations
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TL;DR: The combined experimental and theoretical study provides insights into the evolution of geometric and electronic structures as a function of charge state in doubly and singly charged Group VIB dimetalate species.
Abstract: We produced both doubly and singly charged Group VIB dimetalate species-M2O7 2-, MM'O72-, and M2O7 - (M, M'=) Cr, Mo, W)susing two different experimental techniques (electrospray ionization for the doubly charged anions and laser vaporization for the singly charged anions) and investigated their electronic and geometric structures using photoelectron spectroscopy and density functional calculations. Distinct changes in the electronic and geometric structures were observed as a function of the metal and charge state. The electron binding energies of the heteronuclear dianions MM'O7 2- were observed to be roughly the average of those of their homonuclear counterparts (M2O7 2- and M'2O7 2-). Density functional calculations indicated that W2O7 2-, W2O7-, and W2O7 possess different ground-state structures: the dianion is highly symmetric (D3d,1A1g) with a single bridging oxo ligand, the monoanion is a doublet (C1, 2A) with two bridging oxo ligands and a radical terminal oxo ligand, whereas the neutral is a singlet (C1, 1A) with two bridging oxo ligands and a terminal peroxo ligand. The combined experimental and theoretical study provides insights into the evolution of geometric and electronic structures as a function of charge state. The clusters identified might provide insights into the possible structures of reactive species present inmore » early transition-metal oxide catalysts that are relevant to their reactivity and catalytic function.« less
68 citations
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TL;DR: In this paper, a novel method for the characterization and classification of unknown vapors based on the response on an array of polymer-coated acoustic wave vapor sensors is presented, which does not require that the system be trained on all samples to be identified.
Abstract: A novel method for the characterization and classification of unknown vapors based on the response on an array of polymer-coated acoustic wave vapor sensors is presented. Unlike existing classification algorithms, the method does not require that the system be trained on all samples to be identified. Instead, the solvation parameters of the unknown vapor are estimated given the sensor responses and the linear solvation energy relationship coefficients of the sorbent polymer coatings. The vapors can then be identified from a database of candidate vapor parameters. The method is implemented in a way that is analogous to multivariate calibration with classical least squares, where the individual vapor parameters are treated as pure compounds. It is not necessary to know the vapor concentration of the vapor to perform the classification. In principle, it is possible to estimate the concentration of an unknown vapor for which the system has not been trained or calibrated. It is also possible to implement the m...
68 citations
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TL;DR: In this article, the authors show that water drop impaction of soils generates solid organic particles, with impacts on clouds and radiation absorption, and that these particles affect Earth's climate.
Abstract: Airborne organic particles affect Earth’s climate. Imaging of particles after rain events and experimental irrigation shows that water drop impaction of soils generates solid organic particles, with impacts on clouds and radiation absorption.
68 citations
Authors
Showing all 1477 results
Name | H-index | Papers | Citations |
---|---|---|---|
George M. Whitesides | 240 | 1739 | 269833 |
Yi Cui | 220 | 1015 | 199725 |
Donald G. Truhlar | 165 | 1518 | 157965 |
Ronald W. Davis | 155 | 644 | 151276 |
Richard D. Smith | 140 | 1180 | 79758 |
Yuehe Lin | 118 | 641 | 55399 |
Robert C. Haddon | 112 | 577 | 52712 |
Lai-Sheng Wang | 103 | 576 | 36212 |
Mark H. Engelhard | 103 | 545 | 39864 |
Alex Guenther | 100 | 447 | 45476 |
Gordon E. Brown | 100 | 454 | 32152 |
X. Sunney Xie | 98 | 225 | 44104 |
Jun Li | 98 | 631 | 40958 |
Richard A. Friesner | 97 | 367 | 52729 |
Chongmin Wang | 95 | 451 | 33983 |