Istanbul Technical University

About: Istanbul Technical University is a education organization based out in Istanbul, Turkey. It is known for research contribution in the topics: Fuzzy logic & Large Hadron Collider. The organization has 12889 authors who have published 25081 publications receiving 518242 citations. The organization is also known as: İstanbul Teknik Üniversitesi & Technical University of Istanbul.

Role of Cu–Mg–Al Mixed Oxide Catalysts in Lignin Depolymerization in Supercritical Ethanol

Abstract: We investigated the role of Cu–Mg–Al mixed oxides in depolymerization of soda lignin in supercritical ethanol. A series of mixed oxides with varying Cu content and (Cu+Mg)/Al ratio were prepared. The optimum catalyst containing 20 wt % Cu and having a (Cu+Mg)/Al ratio of 4 yielded 36 wt % monomers without formation of char after reaction at 340 °C for 4 h. Comparison with Cu/MgO and Cu/γ-Al2O3 catalysts emphasized the excellent performance of Cu–Mg–Al oxides. These mixed oxides catalyze the reaction between formaldehyde and ethanol, which limits polymerization reactions between phenolic products and formaldehyde. The combination of Cu and basic sites catalyzes the associated Guerbet and esterification reactions. These reactions also protect lignin side-chains (e.g., aldehyde groups). Lewis acid sites of the catalyst, mainly Cu and Al cations, catalyze C- and O-alkylation reactions that protect phenolic products and phenolic moieties in lignin oligomers. Hydrogen produced by dehydrogenation reactions is in...

A search for a doubly-charged Higgs boson in pp collisions at √s=7 TeV

Abstract: A search for a doubly-charged Higgs boson in pp collisions at root s = 7 TeV is presented. The data correspond to an integrated luminosity of 4.9 fb(-1), collected by the CMS experiment at the LHC. The search is performed using events with three or more isolated charged leptons of any flavor, giving sensitivity to the decays of pair-produced triplet components Phi(++)Phi(--), and Phi(++)Phi(-) from associated production. No excess is observed compared to the background prediction, and upper limits at the 95 % confidence level are set on the Phi(++) production cross section, under specific assumptions on its branching fractions. Lower bounds on the Phi(++) mass are reported, providing significantly more stringent constraints than previously published limits.