Institution
National Chemical Laboratory
Facility•Pune, Maharashtra, India•
About: National Chemical Laboratory is a facility organization based out in Pune, Maharashtra, India. It is known for research contribution in the topics: Catalysis & Nanoparticle. The organization has 8891 authors who have published 14837 publications receiving 387600 citations.
Papers published on a yearly basis
Papers
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TL;DR: In this article, the performance of these novel catalyst systems as solid oxyhalogenation catalysts in utilizing O2 and halide ions in the manufacture of halogenated aromatics holds promise in the organic chemicals industry.
90 citations
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TL;DR: Silk fibroin was regenerated from cocoons produced by the silkworm Bombyx Mori and was investigated as a function of the pH, concentration, temperature and temperature, finding the structure to be self-similar and correlated to, and perhaps caused by, the formation of beta-sheets.
Abstract: Silk fibroin was regenerated from cocoons produced by the silkworm Bombyx Mori. Light scattering showed that an aqueous solution of the regenerated silk fibroin (RSF) was made of individual proteins with a weight average molar mass of about 4 × 105 g mol−1 and a hydrodynamic radius of about 10 nm. Gel formation of RSF in acidic solutions was investigated as a function of the pH (2–4), concentration (0.5–10 g L−1) and temperature (5–70 °C). The structure of the gels was studied using light scattering and confocal laser scanning microscopy. The structure was found to be self-similar from length scales of less than 15 nm up to length scales of about 1 μm, and characterized by a correlation length of a few microns. Gel formation was tracked using turbidity, rheology, light scattering and circular dichroism. Gelation involves the formation of self-similar aggregates with a growth rate that increases exponentially. The protein aggregation is correlated to, and perhaps caused by, the formation of β-sheets, the fraction of which also increases exponentially with time.
90 citations
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TL;DR: In this paper, the authors used MnO4−1-exchanged Mg-Al hydrotalcite (Mg/Al=2−10) for the liquid phase selective oxidation of a methylene group attached to an aromatic ring by molecular oxygen to a carbonyl group.
90 citations
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TL;DR: This review aims to provide a comprehensive overview of the processes and techniques using supercritical fluid processing based on the supercritical properties, the role of supercritical carbon dioxide during the process, and the mechanism of formulation production for each process discussed.
Abstract: The unique properties of supercritical fluids, in particular supercritical carbon dioxide (CO2), provide numerous opportunities for the development of processes for pharmaceutical applications. One of the potential applications for pharmaceuticals includes microencapsulation and nanoencapsulation for drug delivery purposes. Supercritical CO2 processes allow the design and control of particle size, as well as drug loading by utilizing the tunable properties of supercritical CO2 at different operating conditions (flow ratio, temperature, pressures, etc.). This review aims to provide a comprehensive overview of the processes and techniques using supercritical fluid processing based on the supercritical properties, the role of supercritical carbon dioxide during the process, and the mechanism of formulation production for each process discussed. The considerations for equipment configurations to achieve the various processes described and the mechanisms behind the representative processes such as RESS (rapid expansion of supercritical solutions), SAS (supercritical antisolvent), SFEE (supercritical fluid extraction of emulsions), PGSS (particles from gas-saturated solutions), drying, and polymer foaming will be explained via schematic representation. More recent developments such as fluidized bed coating using supercritical CO2 as the fluidizing and drying medium, the supercritical CO2 spray drying of aqueous solutions, as well as the production of microporous drug releasing devices via foaming, will be highlighted in this review. Development and strategies to control and optimize the particle morphology, drug loading, and yield from the major processes will also be discussed.
89 citations
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TL;DR: The effect of Fe-doping on the surface chemistry and gas-sensing properties of nanocrystalline tin oxide is analyzed in this article, where the authors show that Fe-decoupled SnO 2 shows significantly high selectivity towards hydrogen sulfide gas with capability to detect even 10ppm of H 2 S at room temperature, with change of about one order of magnitude in the resistance within 5-15 seconds.
89 citations
Authors
Showing all 8913 results
Name | H-index | Papers | Citations |
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Ashok Kumar | 151 | 5654 | 164086 |
Rajesh Kumar | 149 | 4439 | 140830 |
Tak W. Mak | 148 | 807 | 94871 |
John T. O'Brien | 121 | 819 | 63242 |
Clive Ballard | 117 | 736 | 61663 |
Yoshinori Tokura | 117 | 858 | 70258 |
John S. Mattick | 116 | 367 | 64315 |
Michael Dean | 107 | 419 | 63335 |
Ian G. McKeith | 107 | 468 | 51954 |
David J. Burn | 100 | 446 | 39120 |
Anil Kumar | 99 | 2124 | 64825 |
Vikas Kumar | 89 | 859 | 39185 |
Detlef W. Bahnemann | 88 | 517 | 48826 |
Gautam R. Desiraju | 88 | 458 | 45301 |
Praveen Kumar | 88 | 1339 | 35718 |