National Chemical Laboratory

About: National Chemical Laboratory is a facility organization based out in Pune, Maharashtra, India. It is known for research contribution in the topics: Catalysis & Nanoparticle. The organization has 8891 authors who have published 14837 publications receiving 387600 citations.

Characterization and catalytic activity of gold nanoparticles synthesized by autoreduction of aqueous chloroaurate ions with fumed silica

Abstract: In this report, a novel method for the synthesis of gold nanoparticles on an amorphous silica support is described wherein silanol groups on the surface of the fumed silica spontaneously reduce aqueous chloroaurate ions. This results in the formation of gold nanoparticles that are bound fairly strongly to the fumed silica surface. Alkylamine molecules present in solution were observed to reduce the size of the gold nanoparticles thus formed by self-assembling on the nanoparticles and preventing further growth. The gold nanoparticle size is dependent on the concentration of alkylamine molecules in solution. The gold nanoparticle-fumed silica composite material was found to be catalytically active in the hydrogenation of cyclohexene.

Effect of Coarse Surface Layer on Bed-Load Transport

Abstract: Existing bed-load transport formulas may overestimate the transport rate in mountain rivers by two orders of magnitude or more. Recently published field data sets provide an opportunity to take a fresh look at the bed-load transport relationship and it is hypothesized that the overestimate is due to a failure to account for the effect of a coarse surface layer of bed material inhibiting the release of fine subsurface material. Bed-load transport is determined as gs =aρ(q− qc ) where q =water discharge per unit width; qc =critical value for initiation of bed material movement; ρ =water density; and a =coefficient. The gs ∕q relationship is typically piecewise linear, characterized by two transport phases with, respectively, low and high rates of change. Twenty-one flume and 25 field data sets were used to quantify the relationship for Phase 2. The flume data confirm the dependence of a on S1.5 , where S =channel slope, in agreement with earlier studies. The field data additionally show that a varies invers...

Emotionally intelligent research

Abstract: Key to this paper is not so much the emotions of the researcher that emanate from fieldwork, but those of the researched (and their emotional intelligence). Using a vignette of research on the impact of the 2001 foot and mouth disease outbreak on rural economies in the north of England, the paper explores emotions as clues and ways of seeing. It is broadly influenced by a social constructionist approach that views emotion as created and understood in the context of relationships with others and made meaningful through discourses, language and signifiers. It does not, though, deny the physical sensations that accompany emotion and the ways in which emotions are embodied as individuals interact with others (human and non-human).

Solvent-Dependent Coordination Polymers: Cobalt Complexes of 3,5-Dinitrobenzoic Acid and 3,5-Dinitro-4-methylbenzoic Acid with 4,4‘-Bipyrdine

Abstract: The synthesis, structure elucidation, and analysis of the self-assembly of Co(II) complexes of 3,5-dinitrobenzoic acid and 3,5-dinitro-4-methylbenzoic acid with 4,4‘-bipyridine have been reported. Formation of the complexes and the self-assembly in the three-dimensional structures have been found to be dependent on the solvents (such as acetone, dimethly sulfoxide, etc.) employed for the synthesis of the aggregates. 3,5-Dinitrobenzoic acid forms two coordination polymers, 1a and 1b, from methanol and a mixture of methanol and acetone solvents, respectively, with entirely different recognition patterns. Similarly, 3,5-dinitro-4-methylbenzoic acid also forms two coordination complexes, 2a and 2b, incorporating the solvent of the reaction medium into the crystal lattice. Complex 2a forms a solvated channel structure, whereas 2b gives a bilayered structure, with the layers being separated by solvent of crystallization (dimethyl sulfoxide) molecules. All the complexes have been characterized by single-crystal ...

Comparative biochemical and structural characterizations of fungal polygalacturonases

Abstract: Endo- and exo-polygalacturonases produced by various fungi are involved in the degradation of pectic substances They have found a wide range of applications in the food and textile industries Several phyto-pathogenic fungi secrete polygalacturonases and they act as virulence factors during plant pathogenesis The comparison of biochemical properties of different fungal polygalacturonases, their mechanism of actions, structural aspects and interactions with inhibitors/proteins could be used as a possible strategy for the fungal-crop disease management This review focuses on fungal polygalacturonases, including their regulation, comparative biochemical and structural characterizations and their interactions with inhibitors