University of Texas at Arlington

About: University of Texas at Arlington is a education organization based out in Arlington, Texas, United States. It is known for research contribution in the topics: Population & Large Hadron Collider. The organization has 11758 authors who have published 28598 publications receiving 801626 citations. The organization is also known as: UT Arlington & University of Texas-Arlington.

Iron-containing nanomaterials: synthesis, properties, and environmental applications

Abstract: Available data on the iron-containing nanomaterials are reviewed. Main attention is paid to the following themes: synthetic methods, structures, composition and properties of the nano zerovalent iron (NZVI), and polymorphic forms of iron oxides and FeOOH. Synthetic methods summarized here include a series of physico-chemical methods such as microwave heating, electrodeposition, laser ablation, radiolytical techniques, arc discharge, metal-membrane incorporation, pyrolysis, combustion, reverse micelle and co-deposition routes. We have also included a few “greener” methods. Coated, doped, supported with polymers or inert inorganic materials, core–shell nanostructures, in particular those of iron and its oxides with gold, are discussed. Studies of remediation involving iron-containing nanomaterials are discussed and special attention is paid to the processes of remediation of organic contaminants (chlorine-containing pollutants, benzoic and formic acids, dyes) and inorganic cations (Zn(II), Cu(II), Cd(II) and Pb(II)) and anions (nitrates, bromates, arsenates). Water disinfection (against viruses and bacteria), toxicity and risks of iron nanomaterials application are also examined.

Brightly Phosphorescent Trinuclear Copper(I) Complexes of Pyrazolates: Substituent Effects on the Supramolecular Structure and Photophysics

Abstract: Synthetic details, solid-state structures, and photophysical properties of a group of trimeric copper(I) complexes containing pyrazolate ligands are described. The reaction of copper(I) oxide and the fluorinated pyrazoles [3-(CF3)Pz]H, [3-(CF3),5-(Me)Pz]H, and [3-(CF3),5-(Ph)Pz]H leads to the corresponding trinuclear copper(I) pyrazolates, {[3-(CF3)Pz]Cu}3, {[3-(CF3),5-(Me)Pz]Cu}3, and {[3-(CF3),5-(Ph)Pz]Cu}3, respectively, in high yield. The {[3,5-(i-Pr)2Pz]Cu}3 compound was obtained by a reaction between [Cu(CH3CN)4][BF4], [3,5-(i-Pr)2Pz]H, and NEt3. These compounds as well as {[3,5-(Me)2Pz]Cu}3 and {[3,5-(CF3)2Pz]Cu}3 adopt trimeric structures with nine-membered Cu3N6 metallacycles. There are varying degrees and types of intertrimer Cu···Cu interactions. These contacts give rise to zigzag chains in the fluorinated complexes, {[3-(CF3)Pz]Cu}3, {[3-(CF3),5-(Me)Pz]Cu}3, {[3-(CF3),5-(Ph)Pz]Cu}3, and {[3,5-(CF3)2Pz]Cu}3, whereas the nonfluorinated complexes, {[3,5-(Me)2Pz]Cu}3 and {[3,5-(i-Pr)2Pz]Cu}3 form ...

Informal Family Business in Africa

Abstract: Employing grounded theory based on comparative case studies of informal microfinanced businesses in East Africa, we build a theoretical foundation for studying the establishment and evolution of family firms in emerging markets. We show that East African entrepreneurs not only use both strong family and strong community ties to establish and grow businesses, but they also use strong community ties to counterbalance the obligations that strong extended family ties create. In addition, we show that economic informality presents opportunities for some entrepreneurial businesses but not others to cycle rapidly from opportunity to opportunity as they maneuver toward higher value-creating ventures.

Effects of Ethical Climate and Supervisory Trust on Salesperson's Job Attitudes and Intentions to Quit.

Abstract: This study builds on previous research to investigate the integrated effects of ethical climate and supervisory trust on salesperson’s job attitudes and intentions to quit. Responses from 344 sales...

Silent Positioning in Underwater Acoustic Sensor Networks

Abstract: In this paper, we present a silent positioning scheme termed UPS for underwater acoustic sensor networks. UPS relies on the time difference of arrivals locally measured at a sensor to detect range differences from the sensor to four anchor nodes. These range differences are averaged over multiple beacon intervals before they are combined to estimate the 3-D sensor location through trilateration. UPS requires no time synchronization and provides location privacy at underwater vehicles/sensors whose locations need to be determined. To study the performance of UPS, we model the underwater acoustic channel as a modified ultrawideband Saleh-Valenzuela model: The arrival of each path cluster and the paths within each cluster follow double Poisson distributions, and the multipath channel gain follows a Rician distribution. Based on this channel model, we perform both theoretical analysis and simulation study on the position error of UPS under acoustic fading channels. The obtained results indicate that UPS is an effective scheme for underwater vehicle/sensor self-positioning.