University of Waterloo

About: University of Waterloo is a education organization based out in Waterloo, Ontario, Canada. It is known for research contribution in the topics: Population & Context (language use). The organization has 36093 authors who have published 93906 publications receiving 2948139 citations. The organization is also known as: UW & uwaterloo.

Aqueous vs. nonaqueous Zn-ion batteries: consequences of the desolvation penalty at the interface

Abstract: Zinc ion batteries using metallic zinc as the negative electrode have gained considerable interest for electrochemical energy storage, whose development is crucial for the adoption of renewable energy technologies, as zinc has a very high volumetric capacity (5845 mA h cm−3), is inexpensive and compatible with aqueous electrolytes. However, the divalent charge of zinc ions, which restricts the choice of host material due to hindered solid-state diffusion, can also pose a problem for interfacial charge transfer. Here, we report our findings on reversible intercalation of up to two Zn2+ ions in layered V3O7·H2O. This material exhibits very high capacity and power (375 mA h g−1 at a 1C rate, and 275 mA h g−1 at an 8C rate) in an aqueous electrolyte compared to a very low capacity and slow rate capabilities in a nonaqueous medium. Operando XRD studies, together with impedance analysis, reveal solid solution behavior associated with Zn2+-ion diffusion within a water monolayer in the interlayer gap in both systems, but very sluggish interfacial charge transfer in the nonaqueous electrolyte. This points to desolvation at the interface as a major factor in dictating the kinetics. Temperature dependent impedance studies show high activation energies associated with the nonaqueous charge transfer process, identifying the origin of poor electrochemical performance.

The Chandra COSMOS Survey. I. Overview and Point Source Catalog

Abstract: The Chandra COSMOS Survey (C-COSMOS) is a large, 1.8 Ms, Chandra program that has imaged the central 0.5 deg^2 of the COSMOS field (centered at 10 ^h , +02 ^o ) with an effective exposure of ~160 ks, and an outer 0.4 deg^2 area with an effective exposure of ~80 ks. The limiting source detection depths are 1.9 × 10^(–16) erg cm^(–2) s^(–1) in the soft (0.5-2 keV) band, 7.3 × 10^(–16) erg cm^(–2) s^(–1) in the hard (2-10 keV) band, and 5.7 × 10^(–16) erg cm^(–2) s^(–1) in the full (0.5-10 keV) band. Here we describe the strategy, design, and execution of the C-COSMOS survey, and present the catalog of 1761 point sources detected at a probability of being spurious of <2 × 10^(–5) (1655 in the full, 1340 in the soft, and 1017 in the hard bands). By using a grid of 36 heavily (~50%) overlapping pointing positions with the ACIS-I imager, a remarkably uniform (±12%) exposure across the inner 0.5 deg^2 field was obtained, leading to a sharply defined lower flux limit. The widely different point-spread functions obtained in each exposure at each point in the field required a novel source detection method, because of the overlapping tiling strategy, which is described in a companion paper. This method produced reliable sources down to a 7-12 counts, as verified by the resulting logN-logS curve, with subarcsecond positions, enabling optical and infrared identifications of virtually all sources, as reported in a second companion paper. The full catalog is described here in detail and is available online.

Changing the resilience paradigm

Abstract: Resilience management goes beyond risk management to address the complexities of large integrated systems and the uncertainty of future threats, especially those associated with climate change.

Breaking the Hierarchy: Distributed Control and Economic Optimality in Microgrids

Abstract: Modeled after the hierarchical control architecture of power transmission systems, a layering of primary, secondary, and tertiary control has become the standard operation paradigm for islanded microgrids. Despite this superficial similarity, the control objectives in microgrids across these three layers are varied and ambitious, and they must be achieved while allowing for robust plug-and-play operation and maximal flexibility, without hierarchical decision making and time-scale separations. In this paper, we explore control strategies for these three layers and illuminate some possibly unexpected connections and dependencies among them. Building from a first-principle analysis of decentralized primary droop control, we study centralized, decentralized, and distributed architectures for secondary frequency regulation. We find that averaging-based distributed controllers using communication among the generation units offer the best combination of flexibility and performance. We further leverage these results to study constrained ac economic dispatch in a tertiary control layer. Surprisingly, we show that the minimizers of the economic dispatch problem are in one-to-one correspondence with the set of steady states reachable by droop control. In other words, the adoption of droop control is necessary and sufficient to achieve economic optimization. This equivalence results in simple guidelines to select the droop coefficients, which include the known criteria for power sharing. We illustrate the performance and robustness of our designs through simulations.