Showing papers in "Nature Photonics in 2009"

Bulk heterojunction solar cells with internal quantum efficiency approaching 100

Abstract: A polymer solar-cell based on a bulk hetereojunction design with an internal quantum efficiency of over 90% across the visible spectrum (425 nm to 575 nm) is reported. The device exhibits a power-conversion efficiency of 6% under standard air-mass 1.5 global illumination tests.

Polymer solar cells with enhanced open-circuit voltage and efficiency

Abstract: Following the development of the bulk heterojunction1 structure, recent years have seen a dramatic improvement in the efficiency of polymer solar cells. Maximizing the open-circuit voltage in a low-bandgap polymer is one of the critical factors towards enabling high-efficiency solar cells. Study of the relation between open-circuit voltage and the energy levels of the donor/acceptor2 in bulk heterojunction polymer solar cells has stimulated interest in modifying the open-circuit voltage by tuning the energy levels of polymers3. Here, we show that the open-circuit voltage of polymer solar cells constructed based on the structure of a low-bandgap polymer, PBDTTT4, can be tuned, step by step, using different functional groups, to achieve values as high as 0.76 V. This increased open-circuit voltage combined with a high short-circuit current density results in a polymer solar cell with a power conversion efficiency as high as 6.77%, as certified by the National Renewable Energy Laboratory. Adding electron-withdrawing groups to the backbone of the polymer PBDTTT is shown to increase the open-circuit voltage of photovoltaic cells, resulting in a polymer solar-cell that has a certified power-conversion efficiency of 6.77%.

Photonic quantum technologies

Abstract: The first quantum technology that harnesses quantum mechanical effects for its core operation has arrived in the form of commercially available quantum key distribution systems. This technology achieves enhanced security by encoding information in photons such that an eavesdropper in the system can be detected. Anticipated future quantum technologies include large-scale secure networks, enhanced measurement and lithography, and quantum information processors, which promise exponentially greater computational power for particular tasks. Photonics is destined to have a central role in such technologies owing to the high-speed transmission and outstanding low-noise properties of photons. These technologies may use single photons, quantum states of bright laser beams or both, and will undoubtedly apply and drive state-of-the-art developments in photonics.

Large single-molecule fluorescence enhancements produced by a bowtie nanoantenna

Abstract: A 1,340-fold increase in single-molecule fluorescence has been observed from a lithographically fabricated gold bowtie nanoantenna — approximately an order of magnitude greater than that achieved in previous reports on such structures. The improvement results from an estimated ninefold increase in quantum efficiency, caused by enhanced absorption and an increased radiative emission rate.

Prospects for LED lighting

Abstract: More than one-fifth of US electricity is used to power artificial lighting. Light-emitting diodes based on group III/nitride semiconductors are bringing about a revolution in energy-efficient lighting.

Single-photon detectors for optical quantum information applications

Abstract: This review highlights the recent progress which has been made towards improved single-photon detector technologies and the impact these developments will have on quantum optics and quantum information science.

Multiscale photoacoustic microscopy and computed tomography.

Abstract: Photoacoustic tomography (PAT) is probably the fastest-growing area of biomedical imaging technology, owing to its capacity for high-resolution sensing of rich optical contrast in vivo at depths beyond the optical transport mean free path (~1 mm in human skin). Existing high-resolution optical imaging technologies, such as confocal microscopy and two-photon microscopy, have had a fundamental impact on biomedicine but cannot reach the penetration depths of PAT. By utilizing low ultrasonic scattering, PAT indirectly improves tissue transparency up to 1000-fold and consequently enables deeply penetrating functional and molecular imaging at high spatial resolution. Furthermore, PAT promises in vivo imaging at multiple length-scales; it can image subcellular organelles to organs with the same contrast origin — an important application in multiscale systems biology research.

Optical quantum memory

Abstract: Quantum memory is essential for the development of many devices in quantum information processing, including a synchronization tool that matches various processes within a quantum computer, an identity quantum gate that leaves any state unchanged, and a mechanism to convert heralded photons to on-demand photons. In addition to quantum computing, quantum memory will be instrumental for implementing long-distance quantum communication using quantum repeaters. The importance of this basic quantum gate is exemplified by the multitude of optical quantum memory mechanisms being studied, such as optical delay lines, cavities and electromagnetically induced transparency, as well as schemes that rely on photon echoes and the off-resonant Faraday interaction. Here, we report on state-of-the-art developments in the field of optical quantum memory, establish criteria for successful quantum memory and detail current performance levels.

A metamaterial solid-state terahertz phase modulator

Abstract: Using a single layer of electrically controlled metamaterial, researchers have achieved active control of the phase of terahertz waves and demonstrated high-speed broadband modulation.

Heat-assisted magnetic recording by a near-field transducer with efficient optical energy transfer

Abstract: Although near-field microscopy has allowed optical imaging with sub-20 nm resolution, the optical throughput of this technique is notoriously small. As a result, applications such as optical data storage have been impractical. However, with an optimized near-field transducer design, we show that optical energy can be transferred efficiently to a lossy metallic medium and yet remain confined in a spot that is much smaller than the diffraction limit. Such a transducer was integrated into a recording head and flown over a magnetic recording medium on a rotating disk. Optical power from a semiconductor laser at a wavelength of 830 nm was efficiently coupled by the transducer into the medium to heat a 70-nm track above the Curie point in nanoseconds and record data at an areal density of ∼375 Tb m−2. This transducer design should scale to even smaller optical spots. Using a near-field transducer with efficient optical energy transfer, researchers demonstrate proof-of-principle heat-assisted magnetic recording with multi-track data density of ∼375 Tb m−2.

All-optical high-speed signal processing with silicon–organic hybrid slot waveguides

Abstract: Integrated optical circuits based on silicon-on-insulator technology are likely to become the mainstay of the photonics industry. Over recent years an impressive range of silicon-on-insulator devices has been realized, including waveguides1,2, filters3,4 and photonic-crystal devices5. However, silicon-based all-optical switching is still challenging owing to the slow dynamics of two-photon generated free carriers. Here we show that silicon–organic hybrid integration overcomes such intrinsic limitations by combining the best of two worlds, using mature CMOS processing to fabricate the waveguide, and molecular beam deposition to cover it with organic molecules that efficiently mediate all-optical interaction without introducing significant absorption. We fabricate a 4-mm-long silicon–organic hybrid waveguide with a record nonlinearity coefficient of γ ≈ 1 × 105 W−1 km−1 and perform all-optical demultiplexing of 170.8 Gb s−1 to 42.7 Gb s−1. This is—to the best of our knowledge—the fastest silicon photonic optical signal processing demonstrated. A silicon–organic hybrid slot waveguide with a strong optical nonlinearity is demonstrated to perform ultrafast all-optical demultiplexing of high-bit-rate data streams. The approach could form the basis of compact high-speed optical processing units for future communication networks.

STED microscopy reveals crystal colour centres with nanometric resolution.

Abstract: Based on a far-field fluorescence-based optical super-resolution scheme – stimulated emission depletion microscopy – scientists resolve densely packed individual fluorescent colour centres inside crystals with a far-field spatial resolution of 5.8 nm without photobleaching. The approach will support future studies of solid-state single-photon sources and quantum optics.

Complete optical isolation created by indirect interband photonic transitions

Abstract: Achieving on-chip optical signal isolation is a fundamental difficulty in integrated photonics1. The need to overcome this difficulty is becoming increasingly urgent, especially with the emergence of silicon nano-photonics2,3,4, which promises to create on-chip optical systems at an unprecedented scale of integration. Until now, there have been no techniques that provide complete on-chip signal isolation using materials or processes that are fundamentally compatible with silicon CMOS processes. Based on the effects of photonic transitions5,6, we show here that a linear, broadband and non-reciprocal isolation can be accomplished by spatial–temporal refractive index modulations that simultaneously impart frequency and wavevector shifts during the photonic transition process. We further show that a non-reciprocal effect can be accomplished in dynamically modulated micrometre-scale ring-resonator structures. This work demonstrates that on-chip isolation can be accomplished with dynamic photonic structures in standard material systems that are widely used for integrated optoelectronic applications. The realization of a chip-based, broadband optical isolator is of considerable interest for integrated photonics. To date, no technique has been shown to be able to do this using materials and processes that are CMOS-compatible. Now, scientists propose that the use of direction-dependent photonic mode transitions in silicon nanophotonic structures could be the solution.

Rapid and precise absolute distance measurements at long range

Abstract: The ability to determine absolute distance to an object is one of the most basic measurements of remote sensing. High-precision ranging has important applications in both large-scale manufacturing and in future tight formation-flying satellite missions, where rapid and precise measurements of absolute distance are critical for maintaining the relative pointing and position of the individual satellites. Using two coherent broadband fibre-laser frequency comb sources, we demonstrate a coherent laser ranging system that combines the advantages of time-of-flight and interferometric approaches to provide absolute distance measurements, simultaneously from multiple reflectors, and at low power. The pulse time-of-flight yields a precision of 3 µm with an ambiguity range of 1.5 m in 200 µs. Through the optical carrier phase, the precision is improved to better than 5 nm at 60 ms, and through the radio-frequency phase the ambiguity range is extended to 30 km, potentially providing 2 parts in 1013 ranging at long distances. Using two coherent broadband fibre-laser frequency comb sources, a coherent laser ranging system for absolute distance measurements is demonstrated. Its combination of precision, speed and long range may prove particularly useful for space-based sciences.

Plasmonics for near-field nano-imaging and superlensing

Abstract: Diffraction of light prevents optical microscopes from having spatial resolution beyond a value comparable to the wavelength of the probing light. This essentially means that visible light cannot image nanomaterials. Here we review the mechanism for going beyond this diffraction limit and discuss how manipulation of light by means of surface plasmons propagating along the metal surface can help to achieve this. The interesting behaviour of light under the influence of plasmons not only allows superlensing, in which perfect imaging is possible through a flat thin metal film, but can also provide nano-imaging of practical samples by using a localized surface plasmon mode at the tip of a metallic nanoprobe. We also discuss the current research status and some intriguing future possibilities.

Ultrafast active plasmonics

Abstract: Surface plasmon polaritons, propagating bound oscillations of electrons and light at a metal surface, have great potential as information carriers for next-generation, highly integrated nanophotonic devices [1,2]. Since the term 'active plasmonics' was coined in 2004 [3], a number of techniques for controlling the propagation of guided surface plasmon polariton signals have been demonstrated [4-7]. However, with sub-microsecond or nanosecond response times at best, these techniques are likely to be too slow for future applications in such fields as data transport and processing. Here we report that femtosecond optical frequency plasmon pulses can propagate along a metal-dielectric waveguide and that they can be modulated on the femtosecond timescale by direct ultrafast optical excitation of the metal, thereby offering unprecedented terahertz modulation bandwidth - a speed at least five orders of magnitude faster than existing technologies.

III -nitride photonic-crystal light-emitting diodes with high extraction efficiency

Abstract: Blue light-emitting diodes with a light extraction efficiency of 73% are reported. The InGaN–GaN devices use a photonic-crystal structure for superior optical mode control; their performance has been characterized experimentally and modelled theoretically.

Multispectral opto-acoustic tomography of deep-seated fluorescent proteins in vivo

Abstract: Fluorescent proteins have become essential reporter molecules for studying life at the cellular and sub-cellular level, re-defining the ways in which we investigate biology. However, because of intense light scattering, most organisms and tissues remain inaccessible to current fluorescence microscopy techniques at depths beyond several hundred micrometres. We describe a multispectral opto-acoustic tomography technique capable of high-resolution visualization of fluorescent proteins deep within highly light-scattering living organisms. The method uses multiwavelength illumination over multiple projections combined with selective-plane opto-acoustic detection for artifact-free data collection. Accurate image reconstruction is enabled by making use of wavelength-dependent light propagation models in tissue. By performing whole-body imaging of two biologically important and optically diffuse model organisms, Drosophila melanogaster pupae and adult zebrafish, we demonstrate the facility to resolve tissue-specific expression of eGFP and mCherrry fluorescent proteins for precise morphological and functional observations in vivo.

Silicon nanostructure cloak operating at optical frequencies

Abstract: The ability to render objects invisible using a cloak (such that they are not detectable by an external observer) has long been a tantalizing goal1,2,3,4,5,6. Here, we demonstrate a cloak operating in the near infrared at a wavelength of 1,550 nm. The cloak conceals a deformation on a flat reflecting surface, under which an object can be hidden. The device has an area of 225 µm2 and hides a region of 1.6 µm2. It is composed of nanometre-size silicon structures with spatially varying densities across the cloak. The density variation is defined using transformation optics to define the effective index distribution of the cloak. A triangular array of silicon nanostructures is experimentally demonstrated to function as an optical cloaking device, operating in the near-infrared at a wavelength of 1550 nm. This approach could, in principle, be extended to larger areas using fabrication techniques such as nanoimprinting.

Structural colour printing using a magnetically tunable and lithographically fixable photonic crystal

Abstract: Many creatures in nature, such as butterflies and peacocks, display unique brilliant colours, known as ‘structural colours’, which result from the interaction of light with periodic nanostructures on their surfaces. Mimicking such nanostructures found in nature, however, requires state-of-the-art nanofabrication techniques that are slow, expensive and not scalable. Herein, we demonstrate high-resolution patterning of multiple structural colours within seconds, based on successive tuning and fixing of colour using a single material along with a maskless lithography system. We have invented a material called ‘M-Ink’, the colour of which is tunable by magnetically changing the periodicity of the nanostructure and fixable by photochemically immobilizing those structures in a polymer network. We also demonstrate a flexible photonic crystal for the realization of structural colour printing. The simple, controllable and scalable structural colour printing scheme presented may have a significant impact on colour production for general consumer goods. Maskless high-resolution patterning of structural colours is demonstrated using a new material called ‘M-Ink’. The period of the material is patterned magnetically and a photochemical process immobilizes the structure in a polymer network.

Near-infrared imaging with quantum-dot-sensitized organic photodiodes

Abstract: Solution-processed photodiodes with infrared sensitivities at wavelengths beyond the bandgap of silicon (corresponding to a wavelength of ∼1,100 nm) would be a significant advance towards cost-effective imaging. Colloidal quantum dots are highly suitable as infrared absorbers for photodetection, but high quantum yields have only been reported with photoconductors1,2,3. For imaging, photodiodes are required to ensure low-power operation and compatibility to active matrix backplanes4. Organic bulk heterojunctions5 are attractive as solution-processable diodes, but are limited to use in the visible spectrum. Here, we report the fabrication and application of hybrid bulk heterojunction photodiodes containing PbS nanocrystalline quantum dots as sensitizers for near-infrared detection up to 1.8 µm, with rectification ratios of ∼6,000, minimum lifetimes of one year and external quantum efficiencies of up to 51%. By integration of the solution-processed devices on amorphous silicon active matrix backplanes, we demonstrate for the first time near-infrared imaging with organic/inorganic hybrid photodiodes. Near-infrared imaging with solution-processed organic–inorganic hybrid photodiodes is demonstrated for the first time. The hybrid bulk-heterojunction photodiodes contain PbS nanocrystalline quantum dots as sensitizers for the detection of light of up to 1.8 µm in wavelength, have a minimum lifetime of one year, and external quantum efficiencies of up to 51%.

Monolithic germanium/silicon avalanche photodiodes with 340 GHz gain-bandwidth product

Abstract: Significant progress has been made recently in demonstrating that silicon photonics is a promising technology for low-cost optical detectors, modulators and light sources1,2,3,4,5,6,7,8,9,10,11,12. It has often been assumed, however, that their performance is inferior to InP-based devices. Although this is true in most cases, one of the exceptions is the area of avalanche photodetectors, where silicon's material properties allow for high gain with less excess noise than InP-based avalanche photodetectors and a theoretical sensitivity improvement of 3 dB or more. Here, we report a monolithically grown germanium/silicon avalanche photodetector with a gain–bandwidth product of 340 GHz, a keff of 0.09 and a sensitivity of −28 dB m at 10 Gb s−1. This is the highest reported gain–bandwidth product for any avalanche photodetector operating at 1,300 nm and a sensitivity that is equivalent to mature, commercially available III–V compound avalanche photodetectors. This work paves the way for the future development of low-cost, CMOS-based germanium/silicon avalanche photodetectors operating at data rates of 40 Gb s−1 or higher. A monolithically grown Ge/Si avalanche photodetectors (APD) with a gain–bandwidth product of 340 GHz, the highest value for any APDs operating at 1,300 nm, and a sensitivity equivalent to commercially available III-V compound APDs is reported. The excellent performance paves the way to achieving low-cost, CMOS-based, Ge/Si APDs operating at data rates of 40 Gb s−1 or higher, where the performance of III-V APDs is severely limited.

Green light emission in silicon through slow-light enhanced third-harmonic generation in photonic-crystal waveguides

Abstract: Slow light has attracted significant interest recently as a potential solution for optical delay lines and time-domain optical signal processing1,2. Perhaps even more significant is the possibility of dramatically enhancing nonlinear optical effects3,4 due to the spatial compression of optical energy5,6,7. Two-dimensional silicon photonic-crystal waveguides have proven to be a powerful platform for realizing slow light, being compatible with on-chip integration and offering wide-bandwidth and dispersion-free propagation2. Here, we report the slow-light enhancement of a nonlinear optical process in a two-dimensional silicon photonic-crystal waveguide. We observe visible third-harmonic-generation at a wavelength of 520 nm with only a few watts of peak power, and demonstrate strong third-harmonic-generation enhancement due to the reduced group velocity of the near-infrared pump signal. This demonstrates yet another unexpected nonlinear function realized in a CMOS-compatible silicon waveguide. The use of slow light for enhancing a nonlinear optical process in a two-dimensional silicon photonic-crystal waveguide is demonstrated. More specifically, green emission by third-harmonic generation is obtained, highlighting yet another functionality of silicon photonics chips.

Radiative heat transfer at the nanoscale

Abstract: We give a concise introduction into the radiative heat transfer at the nanoscale discussing the contribution of propagating, frustrated and coupled surface modes [1]. Especially, the latter contribution results in a heat flux, which can exceed the heat flux between two black bodies by several orders of magnitude for distances in the nanometer regime [1]. The prediction of such an enormous heat flux enhancement is usually based on Rytov's fluctuational electrodynamics [2] and has been verified in some very recent experiments [3,4,5]. Our aim is to show how the theoretical expression describing the nanoscale heat flux can be interpreted in terms of transmission coefficients and the universal quantum of thermal conductance by means of concepts of mesoscopic physics [6]. Such a formulation allows for studying the fundamental limits of radiative heat transfer [7,8] emphasizing the trade-off between the number of contributing modes and their transmission coefficient. [1] K. Joulain, J.-P. Mulet, F. Marquier, R. Carminati, and J.-J. Greffet, Surface Science Reports 57, 59 (2005). [2] S. M. Rytov, Y. A. Kravtsov, and V. I. Tatarskii, Principles of Statistical Radiophyics (Springer, New York), Vol. 3. (1989). [3] S. Shen, A. Narayanaswamy, and G. Chen, Nano Lett. 9, 2909 (2009). [4] E. Rousseau, A. Siria, G. Jourdan, S. Volz, F. Comin, J. Chevrier, and J.-J. Greffet, Nature Photonics 3, 514 (2009). [5] R. Ottens, V. Quetschke, S. Wise, A. Alemi, R. Lundock, G. Mueller, D. H. Reitze, D. B. Tanner, B. F. Whiting, Phys. Rev. Lett. 107, 014301 (2011). [6] S.-A. Biehs, E. Rousseau, and J.-J. Greffet, Phys. Rev. Lett. 105, 234301 (2010). [7] P. Ben-Abdallah and K. Joulain, Phys. Rev. B 82, 121419 (R) (2010). [8] S. Basu and Z. M. Zhang, J. Appl. Phys. 105, 093535 (2009).

High-performance crosslinked colloidal quantum-dot light-emitting diodes

Abstract: Colloidal quantum-dot light-emitting diodes have recently received considerable attention due to their ease of colour tunability, high brightness and narrow emission bandwidth. Although there have been rapid advances in luminance, efficiency and lifetime, device performance is still limited by the large energy barriers for hole and electron injection into the quantum-dot layer. Here, we show that by crosslinking the colloidal quantum-dot layer, the charge injection barrier in a red-light-emitting quantum-dot light-emitting diode may be considerably reduced by using a sol–gel TiO2 layer for electron transport. The device architecture is compatible with all-solution device fabrication and the resulting device shows a high luminance (12,380 cd m−2), low turn-on voltage (1.9 V) and high power efficiency (2.41 lm W−1). Incorporation of the technology into a display device with an active matrix drive backplane suggests that the approach has promise for use in high-performance, easy-to-fabricate, large-area displays and illumination sources. Bright, efficient and low-drive-voltage colloidal quantum-dot LEDs that have a crosslinked-polymer quantum-dot layer, and use a sol–gel titanium oxide layer for electron transport, are reported. Integrating the QD-LEDs with a silicon thin-film transistor backplane results in a QD-LED display.

Terahertz field enhancement by a metallic nano slit operating beyond the skin-depth limit

Abstract: The effect of a tiny gap in a metal substrate on incident terahertz radiation in the regime where the gap's dimensions are smaller than the metal's skin-depth are investigated. The results and theoretical analysis show that the gap acts as a capacitor charged by light-induced currents, and dramatically enhances the local electric field.

Controlling the near-field oscillations of loaded plasmonic nanoantennas

Abstract: Optical and infrared antennas 1–6 enable a variety of cuttingedge applications ranging from nanoscale photodetectors 7 to highly sensitive biosensors 8 All these applications critically rely on the optical near-field interaction between the antenna and its ‘load’ (biomolecules or semiconductors) However, it is largely unexplored how antenna loading affects the near-field response Here, we use scattering-type near-field microscopy to monitor the evolution of the near-field oscillations of infrared gap antennas progressively loaded with metallic bridges of varying size Our results provide direct experimental evidence that the local near-field amplitude and phase can be controlled by antenna loading, in excellent agreement with numerical calculations By modelling the antenna loads as nanocapacitors and nanoinductors 9–11 , we show that the change of near-field patterns induced by the load can be understood within the framework of circuit theory Targeted antenna loading provides an excellent means of engineering complex antenna configurations in coherent control applications 12 , adaptive nano-optics 13 and metamaterials 14 Optical and infrared antennas based on metal nanostructures allow for efficient conversion of propagating light into nanoscale confined and strongly enhanced optical fields, and vice versa 1–5,15

Nonlinear generation and manipulation of Airy beams

Abstract: Airy beams have so far been generated by linear diffractive elements. Now, scientists show that they can also be created by a nonlinear process, opening the door to all-optical beam control and production at wavelengths unavailable by conventional methods.

Increased light harvesting in dye-sensitized solar cells with energy relay dyes

Abstract: Conventional dye-sensitized solar cells have excellent charge collection efficiencies, high open-circuit voltages and good fill factors. However, dye-sensitized solar cells do not completely absorb all of the photons from the visible and near-infrared domain and consequently have lower short-circuit photocurrent densities than inorganic photovoltaic devices. Here, we present a new design where high-energy photons are absorbed by highly photoluminescent chromophores unattached to the titania and undergo Forster resonant energy transfer to the sensitizing dye. This novel architecture allows for broader spectral absorption, an increase in dye loading, and relaxes the design requirements for the sensitizing dye. We demonstrate a 26% increase in power conversion efficiency when using an energy relay dye (PTCDI) with an organic sensitizing dye (TT1). We estimate the average excitation transfer efficiency in this system to be at least 47%. This system offers a viable pathway to develop more efficient dye-sensitized solar cells.

Manipulation of multiphoton entanglement in waveguide quantum circuits

Abstract: Precise control of single-photon states and multiphoton entanglement is demonstrated on-chip. Two- and four-photon entangled states have now been generated in a waveguide circuit and their interference tuned. These results open up adaptive and reconfigurable photonic quantum circuits not just for single photons, but for all quantum states of light.