Journal ArticleDOI
Catalytic asymmetric induction. Highly enantioselective addition of dialkylzincs to aldehydes
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This article is published in Journal of the American Chemical Society.The article was published on 1986-09-01. It has received 479 citations till now. The article focuses on the topics: Addition reaction & Enantioselective synthesis.read more
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Stereoselective organic reactions: catalysts for carbonyl addition processes.
TL;DR: This review attempts to unify one aspect of this field, the development of catalysts and catalyst models for the enantioselective addition of hydride and carbon nucleophiles to carbonyl substrates.
Journal ArticleDOI
Organische Synthese — wohin?
TL;DR: In this article, a survey of the state-of-the-art Synthese-methoden is presented, e.g., enantioselektiven Herstellung bestimmter Verbindungen verwendet, enzyme, Enzyme, ganze Mikroorganismen or Zellkulturen.
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Enantioselective preparation of sec. Alcohols from aldehydes and dialkyl zinc compounds, generated in situ from Grignard reagents, using substoichiometric amounts of TADDOL-titanates
TL;DR: Using the Schlenk trick (precipitation of MgX2 from ethereal solutions by the addition of 1,4-dioxane) mixtures of a Grignard reagent RMgX (X = Cl, Br, I) and 0.5 equiv.
Journal ArticleDOI
Zirconocene−Zinc Transmetalation and in Situ Catalytic Asymmetric Addition to Aldehydes
Peter Wipf,Seth Ribe +1 more
Journal ArticleDOI
From Highly Enantioselective Monomeric Catalysts to Highly Enantioselective Polymeric Catalysts: Application of Rigid and Sterically Regular Chiral Binaphthyl Polymers to the Asymmetric Synthesis of Chiral Secondary Alcohols
TL;DR: In this article, a 1,1'binaphthyl-based polymeric chiral catalyst with the most general enantioselectivity for the alkylzinc addition to a broad range of aldehydes has been obtained.
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