Journal ArticleDOI
Catalytic asymmetric induction. Highly enantioselective addition of dialkylzincs to aldehydes
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This article is published in Journal of the American Chemical Society.The article was published on 1986-09-01. It has received 479 citations till now. The article focuses on the topics: Addition reaction & Enantioselective synthesis.read more
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Efficient one-step synthesis of chiral bidentate oxazoline-alcohol ligands via a cyclic imidate ester rearrangement
TL;DR: In this paper, various chiral bidentate oxazoline-alcohol ligands were obtained in a straightforward one-step synthesis via a cyclic imidate ester rearrangement.
Journal ArticleDOI
Synthesis of enantiopure 2-(aminoalkyl)phenol derivatives and their application as catalysts in stereoselective reactions.
TL;DR: The uses of 2-(aminoalkyl)phenol derivatives in metal catalysed asymmetric reactions in the addition of dialkyl zinc reagents to aldehydes and in the reduction of ketones with borane are described.
Journal ArticleDOI
Novel synthetic strategies for the preparation of prostacyclin and prostaglandin analogues--off the beaten track.
TL;DR: The recent increase in activity in the fields of neuroscience and life sciences has been mirrored by the design and synthesis of novel chemically and metabolically stable prostaglandin and prostacyclin analogues.
Journal ArticleDOI
Mild and highly enantioselective vinylogous aldol reaction of Brassard's diene with aromatic aldehydes by combined Lewis acid catalyst.
TL;DR: The combined Lewis acid catalytic system effectively catalyzed the enantioselective vinylogous aldol reaction of Brassard's diene with aromatic aldehydes affording the (Z)-delta-hydroxyl-alpha,beta-unsaturated esters exclusively in good yields with excellent enantiOSElectivities (90-99% ee) under mild conditions.
Journal ArticleDOI
Enantioselective alkylation of benzaldehyde with diethylzinc catalyzed by 1,1′- and 1,2-disubstituted ferrocenyl amino alcohols
TL;DR: Optically active 1,1′- and 1,2-disubstituted ferrocenyl amino alcohols have been synthesized from dicarboxaldehyde.
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