Journal ArticleDOI
Catalytic asymmetric induction. Highly enantioselective addition of dialkylzincs to aldehydes
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This article is published in Journal of the American Chemical Society.The article was published on 1986-09-01. It has received 479 citations till now. The article focuses on the topics: Addition reaction & Enantioselective synthesis.read more
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Kombinierte Säurekatalyse in der asymmetrischen Synthese durch “Designer‐Säuren”
TL;DR: In this paper, a Katalysatorplanung wird insbesondere das Konzept der kombinierten Sauren zum Design enantioselektiver Katalysen genutzt.
Journal ArticleDOI
Enantioselective addition of diethylzinc to aromatic aldehydes catalyzed by Ti(BINOL) complex
TL;DR: In this article, the enantioselective addition of diethylzinc to aldehydes was conveniently achieved by using a catalyst prepared in situ by mixing titanium tetraisopropoxide with S - or R -binaphthol.
Journal ArticleDOI
Transition-metal ligands bound onto the micelle-templated silica surface
Daniel Brunel,Nathalie Bellocq,P. Sutra,Anne Cauvel,Monique Laspéras,Patrice Moreau,Francesco Di Renzo,Anne Galarneau,François Fajula +8 more
TL;DR: In this paper, a review of ligand anchorage on polymeric supports and encapsulation of transition-metal complexes inside layered or zeolitic minerals is reported, and the grafting of ligands onto the silicic wall surface of micelle-templated silicas (MTS) is reported.
Journal ArticleDOI
Enantioselective alkylation of aldehyde catalyzed by disulfonamide-Ti(O-i-Pr)4-dialkyl zinc system
TL;DR: In this article, the reaction of Et 2 Zn-Ti(O- i -Pr) 4 -disulfonamide with various aldehydes was examined and it was shown that high enantioselectivity (> 90% e.g.
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