Journal ArticleDOI
Catalytic asymmetric induction. Highly enantioselective addition of dialkylzincs to aldehydes
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This article is published in Journal of the American Chemical Society.The article was published on 1986-09-01. It has received 479 citations till now. The article focuses on the topics: Addition reaction & Enantioselective synthesis.read more
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Journal ArticleDOI
Highly enantioselective addition of diethylzinc to aldehydes catalyzed by chiral s-amino-t-alcohols
TL;DR: In this article, a chiral acyclic s-amino-t-alcohols derived from (S)-phenylalanine and (S-tyrosine) were used as catalysts for the enantioselective addition of diethylzinc to aldehydes.
Book ChapterDOI
4.17 Asymmetric 1,2-Addition of Organometallics to Carbonyl and Imine Groups
S. Suga,M. Kitamura +1 more
TL;DR: The development of asymmetric 1,2-additions of organometallics to carbonyl compounds and imines for the synthesis of chiral alcohols and amines has been overviewed in this paper.
Journal ArticleDOI
Enantioselective addition of diethylzinc to aldehydes catalyzed by d-glucosamine derivatives: Highly pronounced effect of trifluoromethylsulfonamide
Tomasz Bauer,Sławomir Smoliński +1 more
TL;DR: In this paper, the synthesis of β-hydroxy sulfonamides derived from d-glucosamine and their application as ligands in titanium tetraisopropoxide promoted enantioselective addition of diethylzinc to benzaldehyde and selected aromatic and aliphatic aldehydes was presented.
Book ChapterDOI
9.11 – Selenium
TL;DR: Various important aspects of organoselenium chemistry are summarized in this chapter and the conceptual presentation of main principles will allow the reader to identify important research directions and should allow also the non-specialist reader to understand the significant advantages of organosiene chemistry.
Journal ArticleDOI
Supramolecular Interlocked Biphenyl Ligands for EnantioselectiveTi-Catalyzed Alkylation of Aromatic Aldehydes
TL;DR: In this article, the substitution of tropos 2,2′-biphenols with (S)-amino acid-derived interaction sites in the 5,5′-position results in spontaneous desymmetrization.
Related Papers (5)
Enantioselective Addition of Organometallic Reagents to Carbonyl Compounds: Chirality Transfer, Multiplication, and Amplification†
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Enantioselective addition of diethylzinc to benzaldehyde catalyzed by a small amount of chiral 2-amino-1-alcohols
Nobuki Oguni,Takao Omi +1 more