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Enhanced photocatalytic activity of Co doped ZnO nanodisks and nanorods prepared by a facile wet chemical method

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TLDR
The results showed that Co doped ZnO nanodisks and nanorods exhibit highly enhanced photocatalytic activity, as compared to pure Zn O nanod risks and nanors, due to the combined effects of enhanced surface area and improved charge separation efficiency due to optimal Co doping.
Abstract
Cobalt doped ZnO nanodisks and nanorods were synthesized by a facile wet chemical method and well characterized by X-ray diffraction, field emission scanning electron microscopy (FESEM), high resolution transmission electron microscopy (HRTEM) with energy dispersive X-ray spectroscopy, photoluminescence spectroscopy, Raman spectroscopy and UV-visible absorption spectroscopy. The photocatalytic activities were evaluated for sunlight driven degradation of an aqueous methylene blue (MB) solution. The results showed that Co doped ZnO nanodisks and nanorods exhibit highly enhanced photocatalytic activity, as compared to pure ZnO nanodisks and nanorods. The enhanced photocatalytic activities of Co doped ZnO nanostructures were attributed to the combined effects of enhanced surface area of ZnO nanodisks and improved charge separation efficiency due to optimal Co doping which inhibit recombination of photogenerated charge carriers. The possible mechanism for the enhanced photocatalytic activity of Co doped ZnO nanostructures is tentatively proposed.

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Review on the improvement of the photocatalytic and antibacterial activities of ZnO

TL;DR: In this paper, a review of the application of photocatalytic degradation and the antibacterial properties of zinc oxide (ZnO) nanomaterials is reviewed, and the main methods that improve antibacterial activities are coating inorganic or organic antimicrobial agents, doping ZnO, and tuning the size, morphological characteristics, and concentration of ZnOs.
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Defect engineering in photocatalytic materials

TL;DR: In this paper, the state-of-the-art progress on defect-engineered photocatalytic materials is reviewed and the future opportunities and challenges regarding defect engineering in photocatalysis are highlighted.
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Recent progress on doped ZnO nanostructures for visible-light photocatalysis

TL;DR: In this article, the effect of dopant type, ionic size and its concentration on the crystal structure, electronic property and morphology of doped ZnO with a narrower band gap is reviewed systematically.
Journal ArticleDOI

Influence of crystal structure of nanosized ZrO2 on photocatalytic degradation of methyl orange.

TL;DR: The higher activity of the monoclinic ZrO2 sample for the photocatalytic degradation of methyl orange can be attributed to the combining effects of factors including the presence of small amount of oxygen-deficient zirconium oxide phase, high crystallinity, large pores, and high density of surface hydroxyl groups.
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Enhanced photocatalytic degradation of methylene blue and methyl orange by ZnO:Eu nanoparticles

TL;DR: In this paper, the influence of europium doping and solvents on size, particles agglomeration, light absorption and photocatalytic activity was analyzed in ZnO nanoparticles.
References
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Journal ArticleDOI

Environmental Applications of Semiconductor Photocatalysis

TL;DR: The slow pace of hazardous waste remediation at military installations around the world is causing a serious delay in conversion of many of these facilities to civilian uses as discussed by the authors, which is a serious problem.
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An overview of semiconductor photocatalysis

TL;DR: An overview of the field of semiconductor photocatalysis can be found in this paper, where a brief examination of its roots, achievements and possible future is presented, and the semiconductor titanium dioxide (TiO 2 ) features predominantly in past and present work.
Journal ArticleDOI

Photocatalytic degradation pathway of methylene blue in water

TL;DR: In this article, the TiO2/UV photocatalytic degradation of methylene blue (MB) has been investigated in aqueous heterogeneous suspensions, and it has been shown that the degradation pathway can be determined by a careful identification of intermediate products, in particular aromatics, whose successive hydroxylations lead to the aromatic ring opening.
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Blue Luminescence of ZnO Nanoparticles Based on Non‐Equilibrium Processes: Defect Origins and Emission Controls

TL;DR: In this article, high concentrations of defects are introduced into nanoscale ZnO through non-equilibrium processes and resultant blue emissions are comprehensively analyzed, focusing on defect origins and broad controls.
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