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High-Resolution Inkjet Printing of All-Polymer Transistor Circuits

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TLDR
It is shown that the use of substrate surface energy patterning to direct the flow of water-based conducting polymer inkjet droplets enables high-resolution definition of practical channel lengths of 5 micrometers, and high mobilities were achieved.
Abstract
Direct printing of functional electronic materials may provide a new route to low-cost fabrication of integrated circuits. However, to be useful it must allow continuous manufacturing of all circuit components by successive solution deposition and printing steps in the same environment. We demonstrate direct inkjet printing of complete transistor circuits, including via-hole interconnections based on solution-processed polymer conductors, insulators, and self-organizing semiconductors. We show that the use of substrate surface energy patterning to direct the flow of water-based conducting polymer inkjet droplets enables high-resolution definition of practical channel lengths of 5 micrometers. High mobilities of 0.02 square centimeters per volt second and on-off current switching ratios of 10 5 were achieved.

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Journal ArticleDOI

Jetting Micron-Scale Droplets onto Chemically Heterogeneous Surfaces

TL;DR: In this article, the behavior of micron-scale fluid droplets jetted onto surfaces patterned with lyophobic and lyophilic stripes was investigated and the final droplet shape was shown to depend on the droplet size relative to that of the stripes.
Journal ArticleDOI

Controlled Self‐Assembly of Organic Semiconductors for Solution‐Based Fabrication of Organic Field‐Effect Transistors

TL;DR: Two solution-based methods for self-organized formation of organic semiconductor crystals, including area selective nucleation of crystalline semiconductor films and direct formation oforganic single crystals are developed.
Journal ArticleDOI

Harnessing supramolecular interactions in organic solid-state devices: Current status and future potential

TL;DR: In this paper, a review describes current progress in solid-state devices in which the molecular components possess designed supramolecular interactions, as opposed to non-specific cohesive forces, used to instill or modify functionality.
Journal ArticleDOI

Printing mesoscale architectures

TL;DR: A growing palette of printable materials, coupled with the ability to programmably control mesoscale architecture, open new avenues for creating designer materials with unprecedented performance.
Journal ArticleDOI

Field-Effect Mobility of Charge Carriers in Blends of Regioregular Poly(3-alkylthiophene)s

TL;DR: In this paper, the field effect mobility of holes (μh) in a series of 10 binary blends of poly(3-hexylthiophene) (PHT) and poly (3-decylthyphene)(PDT) and their binary blends were investigated and the blend composition dependence of the charge carrier mobility was determined.
References
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Journal ArticleDOI

Two-dimensional charge transport in self-organized, high-mobility conjugated polymers

TL;DR: In this article, the authors used thin-film, field effect transistor structures to probe the transport properties of the ordered microcrystalline domains in the conjugated polymer poly(3-hexylthiophene), P3HT.
Journal ArticleDOI

Integrated Optoelectronic Devices Based on Conjugated Polymers

TL;DR: An all-polymer semiconductor integrated device is demonstrated with a high-mobility conjugated polymer field-effect transistor driving a polymer light-emitting diode (LED) of similar size, which represents a step toward all- polymer optoelectronic integrated circuits such as active-matrix polymer LED displays.
Journal ArticleDOI

Ultrahigh-Density Nanowire Arrays Grown in Self-Assembled Diblock Copolymer Templates

TL;DR: A simple, robust, chemical route to the fabrication of ultrahigh-density arrays of nanopores with high aspect ratios using the equilibrium self-assembled morphology of asymmetric diblock copolymers is shown.
Journal ArticleDOI

All-polymer field-effect transistor realized by printing techniques

TL;DR: A field-effect transistor has been fabricated from polymer materials by printing techniques, which shows high current output, and opens the way for large-area, low-cost plastic electronics.
Journal ArticleDOI

A soluble and air-stable organic semiconductor with high electron mobility

TL;DR: A crystallographically engineered naphthalenetetracarboxylic diimide derivative is reported that allows us to fabricate solution-cast n-channel FETs with promising performance at ambient conditions and to produce a complementary inverter circuit whose active layers are deposited entirely from the liquid phase.
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