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High-Resolution Inkjet Printing of All-Polymer Transistor Circuits

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TLDR
It is shown that the use of substrate surface energy patterning to direct the flow of water-based conducting polymer inkjet droplets enables high-resolution definition of practical channel lengths of 5 micrometers, and high mobilities were achieved.
Abstract
Direct printing of functional electronic materials may provide a new route to low-cost fabrication of integrated circuits. However, to be useful it must allow continuous manufacturing of all circuit components by successive solution deposition and printing steps in the same environment. We demonstrate direct inkjet printing of complete transistor circuits, including via-hole interconnections based on solution-processed polymer conductors, insulators, and self-organizing semiconductors. We show that the use of substrate surface energy patterning to direct the flow of water-based conducting polymer inkjet droplets enables high-resolution definition of practical channel lengths of 5 micrometers. High mobilities of 0.02 square centimeters per volt second and on-off current switching ratios of 10 5 were achieved.

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Aggregation of the hairy rod conjugated polyelectrolyte poly{1,4-phenylene-[9,9-bis(4-phenoxybutylsulfonate)]fluorene-2,7-diyl} in aqueous solution: an experimental and molecular modelling study

TL;DR: It is suggested that similar factors are involved in both the association behaviour and aggregate disruption with other hairy rod conjugated polyelectrolytes in water, which is due to preferential solvation of the polymer chains.
Journal ArticleDOI

Drop impact on microwetting patterned surfaces

TL;DR: In this article, the dynamics of a liquid drop that impacts on a solid surface whose wettability is patterned at the microscopic scale is investigated, and it is shown that the fingering instability of the drop edge is affected by the initial spreading stages.
Journal ArticleDOI

Anionic Water-Soluble Poly(phenylenevinylene) Alternating Copolymer: High-Efficiency Photoluminescence and Dual Electroluminescence

TL;DR: In this paper, a facile chemical approach to enhance the photoluminescence of poly(2methoxy-5-propyloxysulfonate-1,4-phenylenevinylene) (MPS-PPV) by alternately incorporating the rigid pphenylene-vinylene comonomer units into the conjugated backbone is reported.
Journal ArticleDOI

Flexible semitransparent pentacene thin-film transistors with polymer dielectric layers and NiOx electrodes

TL;DR: In this paper, a flexible semitransparent pentacene-based thin-film transistors (TFTs) with poly-4-vinylphenol (PVP) dielectric layers were fabricated by spin coating on a thermostable plastic substrate with a conductive film.
References
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Journal ArticleDOI

Two-dimensional charge transport in self-organized, high-mobility conjugated polymers

TL;DR: In this article, the authors used thin-film, field effect transistor structures to probe the transport properties of the ordered microcrystalline domains in the conjugated polymer poly(3-hexylthiophene), P3HT.
Journal ArticleDOI

Integrated Optoelectronic Devices Based on Conjugated Polymers

TL;DR: An all-polymer semiconductor integrated device is demonstrated with a high-mobility conjugated polymer field-effect transistor driving a polymer light-emitting diode (LED) of similar size, which represents a step toward all- polymer optoelectronic integrated circuits such as active-matrix polymer LED displays.
Journal ArticleDOI

Ultrahigh-Density Nanowire Arrays Grown in Self-Assembled Diblock Copolymer Templates

TL;DR: A simple, robust, chemical route to the fabrication of ultrahigh-density arrays of nanopores with high aspect ratios using the equilibrium self-assembled morphology of asymmetric diblock copolymers is shown.
Journal ArticleDOI

All-polymer field-effect transistor realized by printing techniques

TL;DR: A field-effect transistor has been fabricated from polymer materials by printing techniques, which shows high current output, and opens the way for large-area, low-cost plastic electronics.
Journal ArticleDOI

A soluble and air-stable organic semiconductor with high electron mobility

TL;DR: A crystallographically engineered naphthalenetetracarboxylic diimide derivative is reported that allows us to fabricate solution-cast n-channel FETs with promising performance at ambient conditions and to produce a complementary inverter circuit whose active layers are deposited entirely from the liquid phase.
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