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Lignocellulosic biomass pyrolysis mechanism: A state-of-the-art review

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TLDR
A broad review of the state-of-the-art biomass pyrolysis research can be found in this article, where three major components (cellulose, hemicellulose and lignin) are discussed in detail.
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This article is published in Progress in Energy and Combustion Science.The article was published on 2017-09-01. It has received 1613 citations till now. The article focuses on the topics: Lignocellulosic biomass & Biomass.

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In situ evolution of functional groups in char during cellulose pyrolysis under the catalysis of KCl and CaCl2

TL;DR: In this paper, a combination of in situ diffuse reflectance infrared Fourier transform (DRIFT) spectroscopy, perturbation-correlation moving-window 2D-COS and PCMW2D was used to reveal the catalytic mechanism of KCl and CaCl2 on cellulose char evolution during slow pyrolysis.
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Influence of reaction atmosphere (N2, CO, CO2 and H2) on ZSM-5 catalyzed microwave-induced fast pyrolysis of medicinal herb residue for biofuel production

TL;DR: In this article, the effect of reaction atmosphere on pyrolytic product yields and oil chemical compositions was explored and it was shown that CO atmosphere leads to the lowest total liquid and oil fraction yields and the highest water yield.
Journal ArticleDOI

Strengthened dewaterability of coke-oven plant oily sludge by altering extracellular organics using Fe(II)-activated persulfate oxidation.

TL;DR: Analysis via scanning electron microscopy and thermogravimetric-Fourier transform infrared spectrometry revealed that Fe2+/S2O82- oxidation destroyed the water-oil-gel-like structure of the oily sludge, thereby accelerating the separation of solids and water while reducing CO2 emissions during the subsequent pyrolysis.
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Catalytic Transfer Hydrogenolysis of Native Lignin to Monomeric Phenols over a Ni–Pd Bimetallic Catalyst

TL;DR: In this article, catalytic transfer hydrogenolysis of native lignin from birch, pine, and co-can be used to convert biomass into monomeric phenols.
References
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Journal ArticleDOI

Exact Stochastic Simulation of Coupled Chemical Reactions

TL;DR: In this article, a simulation algorithm for the stochastic formulation of chemical kinetics is proposed, which uses a rigorously derived Monte Carlo procedure to numerically simulate the time evolution of a given chemical system.
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Features of promising technologies for pretreatment of lignocellulosic biomass.

TL;DR: This paper reviews process parameters and their fundamental modes of action for promising pretreatment methods and concludes that pretreatment processing conditions must be tailored to the specific chemical and structural composition of the various, and variable, sources of lignocellulosic biomass.
Journal ArticleDOI

Characteristics of hemicellulose, cellulose and lignin pyrolysis

TL;DR: In this article, the pyrolysis characteristics of three main components (hemicellulose, cellulose and lignin) of biomass were investigated using, respectively, a thermogravimetric analyzer (TGA) with differential scanning calorimetry (DSC) detector and a pack bed.
Journal ArticleDOI

Kinetic Parameters from Thermogravimetric Data

A. W. Coats, +1 more
- 01 Jan 1964 - 
TL;DR: In this article, a thermocouple is used to measure the sample temperature in a Stanton HT-D thermobalance, the bead of which is positioned in or near the sample, depending on crucible design.
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