Journal ArticleDOI
Lignocellulosic biomass pyrolysis mechanism: A state-of-the-art review
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TLDR
A broad review of the state-of-the-art biomass pyrolysis research can be found in this article, where three major components (cellulose, hemicellulose and lignin) are discussed in detail.About:
This article is published in Progress in Energy and Combustion Science.The article was published on 2017-09-01. It has received 1613 citations till now. The article focuses on the topics: Lignocellulosic biomass & Biomass.read more
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Chemicals from lignin: an interplay of lignocellulose fractionation, depolymerisation, and upgrading
Wouter Schutyser,Wouter Schutyser,Tom Renders,S. Van den Bosch,S.-F. Koelewijn,Gregg T. Beckham,Bert F. Sels +6 more
TL;DR: This review provides a summary and perspective of the extensive research that has been devoted to each of these three interconnected biorefinery aspects, ranging from industrially well-established techniques to the latest cutting edge innovations.
Journal ArticleDOI
Valorization of biomass waste to engineered activated biochar by microwave pyrolysis: Progress, challenges, and future directions
Shin Ying Foong,Shin Ying Foong,Rock Keey Liew,Yafeng Yang,Yoke Wang Cheng,Peter Nai Yuh Yek,Wan Adibah Wan Mahari,Xie Yi Lee,Chai Sean Han,Dai-Viet N. Vo,Quyet Van Le,Mortaza Aghbashlo,Meisam Tabatabaei,Christian Sonne,Wanxi Peng,Su Shiung Lam,Su Shiung Lam +16 more
TL;DR: In this paper, a microwave pyrolysis of biomass is proposed to produce activated biochar with desirable properties for wide application in pollution control, catalysis and energy storage, and the key implications for future development are highlighted.
Journal ArticleDOI
Hard carbons for sodium-ion batteries: Structure, analysis, sustainability, and electrochemistry
Xinwei Dou,Ivana Hasa,Damien Saurel,Christoph Vaalma,Liming Wu,Daniel Buchholz,Dominic Bresser,Shinichi Komaba,Stefano Passerini +8 more
TL;DR: This review aims at providing a comprehensive overview of the up-to-date known structural models of hard carbons and their correlation with the proposed models for the sodium-ion storage mechanisms and a careful evaluation of potential strategies to ensure a high degree of sustainability.
Journal ArticleDOI
Biomass pyrolysis: A review of the process development and challenges from initial researches up to the commercialisation stage
Xun Hu,Mortaza Gholizadeh +1 more
TL;DR: In this article, a review of various pyrolysis process, especially focusing on the effects of essential parameters, the process design, the reactors and the catalysts on the process, is presented.
Journal ArticleDOI
Progress in biomass torrefaction: Principles, applications and challenges
Wei Hsin Chen,Bo Jhih Lin,Bo Jhih Lin,Yu Ying Lin,Yen Shih Chu,Aristotle T. Ubando,Aristotle T. Ubando,Pau Loke Show,Hwai Chyuan Ong,Jo Shu Chang,Jo Shu Chang,Shih-Hsin Ho,Alvin B. Culaba,Anélie Pétrissans,Mathieu Pétrissans +14 more
TL;DR: A comprehensive review of the progress in biomass torrefaction technologies is provided in this article, where the authors perform an in-depth literature survey and identify a current trend in practical tor-refaction development and environmental performance.
References
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Journal ArticleDOI
Direct detection of products from the pyrolysis of 2-phenethyl phenyl ether
Mark W. Jarvis,John W. Daily,Hans-Heinrich Carstensen,Anthony M. Dean,Shantanu Sharma,David C. Dayton,David J. Robichaud,Mark R. Nimlos +7 more
TL;DR: The pyrolysis of 2-phenethyl phenyl ether in a hyperthermal nozzle was studied to determine the importance of concerted and homolytic unimolecular decomposition pathways and suggest that the concerted retro-ene and Maccoll reactions are dominant at low temperatures (below 1000 °C), whereas the contribution of the C(6)H(5)C(2)H
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Effect of Torrefaction on Biomass Physicochemical Characteristics and the Resulting Pyrolysis Behavior
TL;DR: In this article, the authors investigated the changes in biomass physicochemical characteristics during torrefaction and its influence on the resulting pyrolysis behavior and found that the main reactions occurring during torification were dehydration, deacetylation, and cleavage of ether linkages.
Journal ArticleDOI
Kinetic modeling of the thermal degradation and combustion of biomass
TL;DR: In this paper, a multi-step kinetic model for the pyrolysis of biomass particles, the homogeneous gas phase reactions, and the heterogeneous reactions of the residual char is presented.
Journal ArticleDOI
Pyrolysis behaviors of four O-acetyl-preserved hemicelluloses isolated from hardwoods and softwoods
TL;DR: The pyrolysis mechanisms of O-acetyl-preserved hemicelluloses isolated from both hardwoods and softwoods have been systematically studied as discussed by the authors, and a double-Gaussian distributed activation energy model has been introduced to simulate the pyroxymethylfurfural and anhydro sugars were typical products.
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Computational Study of Bond Dissociation Enthalpies for Lignin Model Compounds. Substituent Effects in Phenethyl Phenyl Ethers
Ariana Beste,A. C. Buchanan +1 more
TL;DR: It is found that the oxygen-carbon bond dissociation enthalpy is substantially lowered by oxygen substituents situated at the phenyl ring adjacent to the ether oxygen, which could be a competitive initial reaction under high-temperature pyrolysis conditions.