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Lignocellulosic biomass pyrolysis mechanism: A state-of-the-art review

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TLDR
A broad review of the state-of-the-art biomass pyrolysis research can be found in this article, where three major components (cellulose, hemicellulose and lignin) are discussed in detail.
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This article is published in Progress in Energy and Combustion Science.The article was published on 2017-09-01. It has received 1613 citations till now. The article focuses on the topics: Lignocellulosic biomass & Biomass.

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Chemicals from lignin: an interplay of lignocellulose fractionation, depolymerisation, and upgrading

TL;DR: This review provides a summary and perspective of the extensive research that has been devoted to each of these three interconnected biorefinery aspects, ranging from industrially well-established techniques to the latest cutting edge innovations.
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Hard carbons for sodium-ion batteries: Structure, analysis, sustainability, and electrochemistry

TL;DR: This review aims at providing a comprehensive overview of the up-to-date known structural models of hard carbons and their correlation with the proposed models for the sodium-ion storage mechanisms and a careful evaluation of potential strategies to ensure a high degree of sustainability.
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Biomass pyrolysis: A review of the process development and challenges from initial researches up to the commercialisation stage

TL;DR: In this article, a review of various pyrolysis process, especially focusing on the effects of essential parameters, the process design, the reactors and the catalysts on the process, is presented.
References
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Journal ArticleDOI

Aerosol generation by reactive boiling ejection of molten cellulose

TL;DR: In this article, high speed photography is utilized to elucidate the ejection mechanism of aerosol particles from thermally decomposing cellulose at the timescale of milliseconds, based on first principles, and experimental measurement of ejection phenomenon supports the proposed mechanism of interfacial gas bubble collapse forming a liquid jet which subsequently fragments to form ejected aerosol particle capable of transporting nonvolatile chemicals.
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Pyrolysis of biomass by thermal analysis-mass spectrometry (TA-MS).

TL;DR: The kinetic parameters such as pre-exponential factor and activation energy of hemicellulose, cellulose, and lignin were well determined by the linear regressions of selected, sufficient thermogravimetric data, and close to literature values.
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Fast pyrolysis of potassium impregnated poplar wood and characterization of its influence on the formation as well as properties of pyrolytic products.

TL;DR: Gas chromatography/mass spectroscopy analysis revealed that potassium promoted thermochemical reactions, thus causing a decrease of levoglucosan and an increase of small molecules and lignin-derived phenols in bio-oil.
Journal ArticleDOI

Pyrolysis of Centimeter-Scale Woody Biomass Particles: Kinetic Modeling and Experimental Validation

TL;DR: In this article, an updated comprehensive pyrolysis model including chemical reactions and transport of heat and species, implemented independently in two different software environments, is compared to experimental results of three independent sets of centimeter-scale experiments.
Journal ArticleDOI

Aims and methods in non-isothermal reaction kinetics

TL;DR: In this article, the aim of the non-isothermal kinetic evaluation is to obtain better, more informative results from the experiments, since the most important errors of thermal analysis are not random, the laws of the mathematical statistics do not offer means to find the best set of model parameters.
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