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Mega-electron-volt proton irradiation on supported and suspended graphene: A Raman spectroscopic layer dependent study

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TLDR
Graphene samples with 1, 2, and 4 layers and 1'+'1 folded bi-layers and graphite have been irradiated with 2 MeV protons at fluences ranging from 1'×'1015' to 6'× '1018' ions/cm2.
Abstract
Graphene samples with 1, 2, and 4 layers and 1 + 1 folded bi-layers and graphite have been irradiated with 2 MeV protons at fluences ranging from 1 × 1015 to 6 × 1018 ions/cm2. The samples were characterized using visible and UV Raman spectroscopy and Raman microscopy. The ion-induced defects were found to decrease with increasing number of layers. Graphene samples suspended over etched holes in SiO2 have been fabricated and used to investigate the influence of the substrate SiO2 for defect creation in graphene. While Raman vibrational modes at 1460 cm−1 and 1555 cm−1 have been observed in the visible Raman spectra of substantially damaged graphene samples, these modes were absent in the irradiated-suspended monolayer graphene.

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Study of supported CVD graphene irradiated by He and Au ions

TL;DR: In this article, a graphene monolayer deposited on the SiO2/Si substrate by means of Chemical Vapour Deposition (CVD) was irradiated using He and Au ions.
References
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Journal ArticleDOI

Electric Field Effect in Atomically Thin Carbon Films

TL;DR: Monocrystalline graphitic films are found to be a two-dimensional semimetal with a tiny overlap between valence and conductance bands and they exhibit a strong ambipolar electric field effect.
Journal ArticleDOI

Raman spectrum of graphene and graphene layers.

TL;DR: This work shows that graphene's electronic structure is captured in its Raman spectrum that clearly evolves with the number of layers, and allows unambiguous, high-throughput, nondestructive identification of graphene layers, which is critically lacking in this emerging research area.
Journal ArticleDOI

Interpretation of Raman spectra of disordered and amorphous carbon

TL;DR: In this paper, a model and theoretical understanding of the Raman spectra in disordered and amorphous carbon is given, and the nature of the G and D vibration modes in graphite is analyzed in terms of the resonant excitation of \ensuremath{\pi} states and the long-range polarizability of the long range bonding.
Journal ArticleDOI

Two-dimensional atomic crystals

TL;DR: By using micromechanical cleavage, a variety of 2D crystals including single layers of boron nitride, graphite, several dichalcogenides, and complex oxides are prepared and studied.
Book

The Stopping and Ranges of Ions in Matter

TL;DR: In this article, the authors reviewed the calculation of the stopping and the final range distribution of ions in matter, and showed the development of ion penetration theory by tracing how, as the theory developed through the years, various parts have been incorporated into tables and increased their accuracy.
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