Journal ArticleDOI
Molecular-Level Dispersion of Graphene into Poly(vinyl alcohol) and Effective Reinforcement of their Nanocomposites
Reads0
Chats0
TLDR
In this paper, the preparation of polyvinyl alcohol (PVA) nanocomposites with graphene oxide (GO) using a simple water solution processing method is reported, and efficient load transfer is found between the nanofiller graphene and matrix PVA and the mechanical properties of the graphene-based nanocompositionite with molecule-level dispersion are significantly improved.Abstract:
Despite great recent progress with carbon nanotubes and other nanoscale fillers, the development of strong, durable, and cost-efficient multifunctional nanocomposite materials has yet to be achieved. The challenges are to achieve molecule-level dispersion and maximum interfacial interaction between the nanofiller and the matrix at low loading. Here, the preparation of poly(vinyl alcohol) (PVA) nanocomposites with graphene oxide (GO) using a simple water solution processing method is reported. Efficient load transfer is found between the nanofiller graphene and matrix PVA and the mechanical properties of the graphene-based nanocomposite with molecule-level dispersion are significantly improved. A 76% increase in tensile strength and a 62% improvement of Young's modulus are achieved by addition of only 0.7 wt% of GO. The experimentally determined Young's modulus is in excellent agreement with theoretical simulation.read more
Citations
More filters
Journal ArticleDOI
Graphene and Graphene Oxide: Synthesis, Properties, and Applications
TL;DR: An overview of the synthesis, properties, and applications of graphene and related materials (primarily, graphite oxide and its colloidal suspensions and materials made from them), from a materials science perspective.
Journal ArticleDOI
Graphene-based composites
TL;DR: A critical review of the synthesis methods for graphene and its derivatives as well as their properties and the advantages of graphene-based composites in applications such as the Li-ion batteries, supercapacitors, fuel cells, photovoltaic devices, photocatalysis, and Raman enhancement are described.
Journal ArticleDOI
Graphene based materials: Past, present and future
TL;DR: Graphene and its derivatives are being studied in nearly every field of science and engineering as mentioned in this paper, and recent progress has shown that the graphene-based materials can have a profound impact on electronic and optoelectronic devices, chemical sensors, nanocomposites and energy storage.
Journal ArticleDOI
Recent advances in graphene based polymer composites
TL;DR: In this paper, the structure, preparation and properties of polymer/graphene nanocomposites are discussed in general along with detailed examples drawn from the scientific literature, and the percolation threshold can be achieved at a very lower filler loading.
Journal ArticleDOI
Graphene/Polymer Nanocomposites
TL;DR: Graphene has emerged as a subject of enormous scientific interest due to its exceptional electron transport, mechanical properties, and high surface area, and when incorporated appropriately, these atomically thin carbon sheets can significantly improve physical properties of host polymers at extremely small loading.
References
More filters
Journal ArticleDOI
Structure of Graphite Oxide Revisited
TL;DR: In this paper, the authors used 13C and 1H NMR spectra of graphite oxide derivatives to confirm the assignment of the 70 ppm line to C−OH groups and allow them to propose a new structural model for graphite oxides.
Journal ArticleDOI
Evaluation of Solution-Processed Reduced Graphene Oxide Films as Transparent Conductors
TL;DR: These experiments demonstrate solution-processed GO films have potential as transparent electrodes and sheet resistance and optical transparency using different reduction treatments.
Journal ArticleDOI
The Halpin-Tsai Equations: A Review
TL;DR: The Halpin-Tsai equations are based upon the self-consistent micromechanics method developed by Hill as discussed by the authors. But they are not suitable for semi-crystalline polymers.
Journal ArticleDOI
Synthesis of water soluble graphene.
Yongchao Si,Edward T. Samulski +1 more
TL;DR: A facile and scalable preparation of aqueous solutions of isolated, sparingly sulfonated graphene is reported, and NMR and FTIR spectra indicate that the bulk of the oxygen-containing functional groups was removed from graphene oxide.
Journal ArticleDOI
Stable aqueous dispersions of graphitic nanoplatelets via the reduction of exfoliated graphite oxide in the presence of poly(sodium 4-styrenesulfonate)
TL;DR: In this article, stable aqueous dispersions of polymer-coated graphitic nanoplatelets can be prepared via an exfoliation/in-situ reduction of graphite oxide in the presence of poly(sodium 4-styrenesulfonate).