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Mössbauer mineralogy of rock, soil, and dust at Gusev crater, Mars: Spirit's journey through weakly altered olivine basalt on the plains and pervasively altered basalt in the Columbia Hills

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TLDR
The Moessbauer spectrometer on Spirit measured the oxidation state of Fe, identified Fe-bearing phases, and measured relative abundances of Fe among those phases for surface materials on the plains and in the Columbia Hills of Gusev crater as discussed by the authors.
Abstract
The Moessbauer spectrometer on Spirit measured the oxidation state of Fe, identified Fe-bearing phases, and measured relative abundances of Fe among those phases for surface materials on the plains and in the Columbia Hills of Gusev crater. Eight Fe-bearing phases were identified: olivine, pyroxene, ilmenite, magnetite, nanophase ferric oxide (npOx), hematite, goethite, and a Fe(3+)-sulfate. Adirondack basaltic rocks on the plains are nearly unaltered (Fe(3+)/Fe(sub T) Px), and minor npOx and magnetite. Columbia Hills basaltic rocks are nearly unaltered (Peace and Backstay), moderately altered (WoolyPatch, Wishstone, and Keystone), and pervasively altered (e.g., Clovis, Uchben, Watchtower, Keel, and Paros with Fe(3+)/Fe(sub T) approx.0.6-0.9). Fe from pyroxene is greater than Fe from olivine (Ol sometimes absent), and Fe(2+) from Ol+Px is 40-49% and 9-24% for moderately and pervasively altered materials, respectively. Ilmenite (Fe from Ilm approx.3-6%) is present in Backstay, Wishstone, Keystone, and related rocks along with magnetite (Fe from Mt approx. 10-15%). Remaining Fe is present as npOx, hematite, and goethite in variable proportions. Clovis has the highest goethite content (Fe from Gt=40%). Goethite (alpha-FeOOH) is mineralogical evidence for aqueous processes because it has structural hydroxide and is formed under aqueous conditions. Relatively unaltered basaltic soils (Fe(3+)/Fe(sub T) approx. 0.3) occur throughout Gusev crater (approx. 60-80% Fe from Ol+Px, approx. 10-30% from npOx, and approx. 10% from Mt). PasoRobles soil in the Columbia Hills has a unique occurrence of high concentrations of Fe(3+)-sulfate (approx. 65% of Fe). Magnetite is identified as a strongly magnetic phase in Martian soil and dust.

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Journal ArticleDOI

A habitable fluvio-lacustrine environment at Yellowknife Bay, Gale crater, Mars.

John P. Grotzinger, +71 more
- 24 Jan 2014 - 
TL;DR: The Curiosity rover discovered fine-grained sedimentary rocks, which are inferred to represent an ancient lake and preserve evidence of an environment that would have been suited to support a martian biosphere founded on chemolithoautotrophy.
Journal ArticleDOI

Overview of the Spirit Mars Exploration Rover Mission to Gusev Crater: Landing site to Backstay Rock in the Columbia Hills

Raymond E. Arvidson, +62 more
TL;DR: In this paper, the authors show that the surface enrichment is the result of a minor amount of transport and deposition by aqueous processes on the surface of olivine-bearing basalts.
Journal ArticleDOI

Mineralogy of the Martian Surface

TL;DR: The past fifteen years of orbital infrared spectroscopy and in situ exploration of Mars have led to a new understanding of the composition and history of Mars, as well as its geology as discussed by the authors.
Journal ArticleDOI

Alpha Particle X-Ray Spectrometer (APXS): Results from Gusev crater and calibration report

TL;DR: The chemical composition of rocks and soils on Mars analyzed during the Mars Exploration Rover Spirit Mission was determined by X-ray analyses with the Alpha Particle X-Ray Spectrometer (APXS) as discussed by the authors.
References
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Journal Article

New York 1987

Gilbert Duclos
- 01 Jan 2000 - 
Book

Mossbauer Spectroscopy and Transition Metal Chemistry

TL;DR: In this article, the authors present an interpretation of Mo ssbauer Parameters of Iron Compounds and present a special application of active transition metals other than iron in special applications.
Journal ArticleDOI

Overview of the Spirit Mars Exploration Rover Mission to Gusev Crater: Landing site to Backstay Rock in the Columbia Hills

Raymond E. Arvidson, +62 more
TL;DR: In this paper, the authors show that the surface enrichment is the result of a minor amount of transport and deposition by aqueous processes on the surface of olivine-bearing basalts.
Journal ArticleDOI

Iron and Aluminum Hydroxysulfates from Acid Sulfate Waters

TL;DR: In this paper, the formation, properties, fate, and environmental implications of nano-to microphase hydroxy-sulfates of Fe and Al that are precipitated from acid sulfate waters are described.
Journal ArticleDOI

The Spirit Rover's Athena Science Investigation at Gusev Crater, Mars

Steven W. Squyres, +49 more
- 06 Aug 2004 - 
TL;DR: The Mars Exploration Rover Spirit and its Athena science payload have been used to investigate a landing site in Gusev crater, but no clear evidence for lacustrine sedimentation has been found to date as discussed by the authors.
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Overview of the Spirit Mars Exploration Rover Mission to Gusev Crater: Landing site to Backstay Rock in the Columbia Hills

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