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Synthesis and catalytic properties of metal nanoparticles: Size, shape, support, composition, and oxidation state effects

Beatriz Roldan Cuenya
- 02 Apr 2010 - 
- Vol. 518, Iss: 12, pp 3127-3150
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TLDR
In this paper, the authors examine the role played by the particle structure and morphology (size and shape), its chemical composition and oxidation state, and the effect of the cluster support.
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This article is published in Thin Solid Films.The article was published on 2010-04-02. It has received 957 citations till now. The article focuses on the topics: Nanomaterial-based catalyst.

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Citations
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Particle Size Effects in the Catalytic Electroreduction of CO2 on Cu Nanoparticles

TL;DR: The presented activity-selectivity-size relations provide novel insights in the CO2 electroreduction reaction on nanoscale surfaces and lend themselves well to density functional theory (DFT) evaluation and reaction mechanism verification.
Journal ArticleDOI

Cellular Uptake, Intracellular Trafficking, and Cytotoxicity of Nanomaterials

TL;DR: This article focusses on the cellular uptake, location and translocation, and any biological consequences, such as cytotoxicity, of the most widely studied and used nanoparticles,such as carbon-based nanoparticle, metallic nanoparticles and quantum dots.
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Catalysis by Supported Single Metal Atoms

TL;DR: In this article, the authors discuss the most recent advances in preparing, characterizing, and catalytically testing SACs with a focus on correlating the structural perspective of the anchored single metal atoms to the observed catalytic performances.
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Synthesis, characterization, applications, and challenges of iron oxide nanoparticles

TL;DR: This review summarizes the methods for the preparation of iron oxide NPs, size and morphology control, and magnetic properties with recent bioengineering, commercial, and industrial applications.
References
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Journal ArticleDOI

Activity benchmarks and requirements for Pt, Pt-alloy, and non-Pt oxygen reduction catalysts for PEMFCs

TL;DR: In this article, the authors quantified the activities and voltage loss modes for state-of-the-art MEAs (membrane electrode assemblies), specifies performance goals needed for automotive application, and provides benchmark oxygen reduction activities for state of the art platinum electrocatalysts.
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Onset of Catalytic Activity of Gold Clusters on Titania with the Appearance of Nonmetallic Properties

TL;DR: Results suggest that supported clusters, in general, may have unusual catalytic properties as one dimension of the cluster becomes smaller than three atomic spacings.
Journal ArticleDOI

Size- and support-dependency in the catalysis of gold

TL;DR: In this article, the adsorption properties and reactivities of gold are summarized in terms of their size dependency from bulk to fine particles, clusters and atoms, and the catalytic performances of gold markedly depend on dispersion, supports, and preparation methods.
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