Book ChapterDOI
The Coordination and Bioinorganic Chemistry of Molybdenum
Edward I. Stiefel
- pp 1-223
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The article was published on 2007-03-09. It has received 78 citations till now. The article focuses on the topics: Bioorganometallic chemistry & Bioinorganic chemistry.read more
Citations
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Journal ArticleDOI
Molybdenum in natural waters: A review of occurrence, distributions and controls
TL;DR: The 2011 WHO Guidelines for Drinking-Water Quality (fourth edition) advised a health-based value of 70μg/L for Mo but this is no longer promulgated as a formal guideline value as WHO consider such concentrations to be rarely found in drinking water as discussed by the authors.
Journal ArticleDOI
Structure and Function of Xanthine Oxidoreductase
TL;DR: An overview of the current state of our understanding of the molybdenum-containing enzyme xanthine oxidoreductase is presented, with an emphasis on work done in the past five years.
Journal ArticleDOI
Synthetic approaches to the molybdenum sulfide materials
TL;DR: In this article, synthetic aspects of molybdenum sulfide-based materials were reviewed, with emphasis on the catalytic materials, and a number of preparation methods were critically compared, including molecular precursor decomposition, hydrothermal, soft chemistry aqueous, surfactant-aided, intercalation-exfoliation, and solid gas reactions.
Journal ArticleDOI
Reduction of Carbon Dioxide by a Molybdenum-Containing Formate Dehydrogenase: A Kinetic and Mechanistic Study.
TL;DR: The ability of Desulfovibrio desulfuricans formate dehydrogenase (DdFDH) to reduce carbon dioxide was kinetically and mechanistically characterized and a kinetic model of a hysteretic enzyme is proposed to interpret and predict the progress curves of the Dd FDH-catalyzed reactions.
Journal ArticleDOI
Synthesis and characterization of molybdenum complexes with bidentate Schiff base ligands within nanoreactors of MCM-41 as epoxidation catalysts
TL;DR: The mesoporous molecular sieve MCM-41 was covalently grafted with 3-aminopropyl trimethoxysilane (AmpMCM41) in this article.
References
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Journal ArticleDOI
Arene–molybdenum chemistry: diprotonation of arenetris(tertiary phosphine)molybdenum compounds
TL;DR: In this paper, the properties of diprotonated cations (arene) Mo(PR3)3H2]2+ were described, where arene = benzene, R = Et, R3 = Ph2Me or PhMe2.
Journal ArticleDOI
Structures of monoadducts of tris(β-diketonato) lanthanoid shift reagents
TL;DR: In this article, the repulsion energies of bidentate β-diketonate ligands attached to a lanthanoid element were calculated using a normalized bite of 1·22.
Journal ArticleDOI
Tetrafluorobenzene 1,2-dithiolene complexes of the transition metals
Journal ArticleDOI
Resonance Raman spectrum of K4Mo2Cl8
TL;DR: In this article, a resonance-Raman spectrum of the complex K4Mo2Cl8 has been recorded with 488·0 and 514·5 nm excitation; five harmonics of ν1 (the “Mo-Mo stretching” fundamental) have been located accurately, and from these data it is deduced that ω1= 347·1 ± 0·5 cm-1 and X11= 0·50 ± 0.08 cm-
Journal ArticleDOI
Transition-metal derivatives of arenediazonium ions. Part VII. Fluorine-19 nuclear magnetic resonance and nitrogen-l5 infrared labelling studies on some benzene-, meta-fluorobenzene-, and para-fiuorobenzene-diazo-complexes of iron, molybdenum, platinum, and tungsten
TL;DR: In this paper, the 19F n.m. spectra of fifteen different classes of m- and p-fluorobenzenediazo-complexes containing iron, molybdenum, platinum, or tungsten have been measured.